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Development Of Catalytic Processes For Aromatic Amides And Carboxylic Acids, Yujun Song
Development Of Catalytic Processes For Aromatic Amides And Carboxylic Acids, Yujun Song
LSU Master's Theses
New catalysts were prepared and studied for: (1) a model amidation with a hindered amine, diethylamine (DEA), to N,N¡¯-diethyltoluamide (DEET); (2) the oxidation of m-xylene (MX) to DEET¡¯s alkylaromatic precursor, m-toluic acid (MTA). In both cases the goal was to reduce waste associated with current processes. Thermodynamic analyses showed that the amidation to produce DEET from MTA and DEA was an equilibrium limited reaction with equilibrium constants (Ke) less than 41 at temperatures below 320¡ÆC. The kinetics on silica-supported titanium (¥³) (triethanolaminato)-isopropoxide (Tyzor TE), calcium hydroxyapatites and silica supported tungsten heteropolyacids were studied using a continuous reactor. Both porous hydroxyapatites …