Engineering Commons^™

Free-Radical Retrograde Precipitation-Polymerization Process, Gerard T. Caneba

Michigan Tech Patents

A free-radical retrograde polymerization process for forming a polymer. An admixture of reactants including predetermined amounts of a monomer, a solvent, and a free-radical-initiator is reacted. A precipitation polymerization reaction occurs such that a polymer-rich phase is at a temperature generally above the lower critical solution temperature (LCST) of the admixture.

Royal Institute Of Technology: Department Of Polymer Technology, Otto Vogl, Ann Christine Albertsson

Emeritus Faculty Author Gallery

No abstract provided.

70. Obituary, Herman F. Mark, Otto Vogl

Emeritus Faculty Author Gallery

No abstract provided.

70. Obituary, Herman F. Mark, Otto Vogl

Otto Vogl

No abstract provided.

Royal Institute Of Technology: Department Of Polymer Technology, Otto Vogl, Ann Christine Albertsson

Otto Vogl

No abstract provided.

High-Level Expression Of A Heterologous Protein In The Milk Of Transgenic Swine Using The Cdna Encoding Human Protein C, William H. Velander, John L. Johnson, Raymond L. Page, Chritopher G. Russell, Anuradha Subramanian, Tracy D. Wilkins, Francis C. Gwazdauskas, Christoph Pittus, William N. Drohan

Papers in Biotechnology

Transgenic pigs were generated that produced human protein C in their milk at up to 1 g/liter. The gene construct was a fusion gene consisting of the cDNA for human protein C inserted into the first exon of the mouse whey acidic protein gene. These results demonstrate that the mouse whey acidic protein gene contains regulatory elements that can direct cDNA expression at high levels in the pig mammary gland. Recombinant human protein C that was produced at about 380 pg/ml per hr in transgenic pig milk possessed anticoagulant activity that was equivalent to that of protein C derived from …

A Study Of The Effects Of Polyacrylates On Water Retention And Binder Migration Tendencies Of Coatings, Wichan Charoenkitsupat

Masters Theses

Five commercial polyacrylate samples were used to study their effects on viscosity, water holding, and binder migration under non-pressure conditions. The polyacrylates used were different in acid level, degree of crosslinking, and type of polymer (copolymer and terpolymer). A series of coatings was prepared using a number two clay and three styrene-butadiene latexes of similar particle size and T⋁g but different degrees of carboxylation, then the polyacrylates were added at several levels. The coatings were evaluated for rheological properties, water loss rate and binder migration. The results show that with increasing amounts of polyacrylates, the viscosity increased and the water …

A Computer Simulation Of The Rotary Vacuum Filter Brown Stock Washing System Using Distribution Sampling, Edison G. Yiu

Masters Theses

A probabilistic model was utilized to simulate the brown stock washing system's error due to process variability and measurement noise. Mass balances of the washing system were performed using distribution sampling. This model relies on a nonlinear relationship between displacement and dilution, which permitted the generation of displacement ratio based upon wash liquor ratio. Experimental trials were performed on a pilotscale rotary vacuum single-stage washer. Nonlinear first-order relationship appears to characterize a pilotscale washer adequately. Differences were observed between the means and standard deviations of the measured results compared to the simulation output. Future work is needed to identify the …

A Study Of The Effects Of Pigment Size And Shape On Binder Migration, Hee Jong Yang

Masters Theses

The effects of pigment size and shape on coating structure and binder migration has been investigated. Clays and ground calcium carbonates of different particle size distributions were used in coatings with 15 pph SB latex.

Coatings were applied to Mylar and a special Tyvek using a wire wound rod. The coatings were dried slowly under ambient conditions, and using hot air immediately or after having been allowed to reach immobilization through penetration into the Tyvek. The dried coatings were evaluated for water holding, relative pore size and migration using the UV technique to measure the increase in SB latex at …

Polymer Science In Finland, Otto Vogl, Johan J. Lindberg, Franciska Sundholm

Emeritus Faculty Author Gallery

No abstract provided.

71. Otto Vogl, David A. Tirrell

Emeritus Faculty Author Gallery

No abstract provided.

Polymer Science In Finland, Otto Vogl, Johan J. Lindberg, Franciska Sundholm

Otto Vogl

No abstract provided.

71. Otto Vogl, David A. Tirrell

Otto Vogl

No abstract provided.

A Study On Radical Scavenging And Magnetic Resonance Imaging Characteristics Of Stable Radical Nitroxides, Shiey-Shiun Horng

Dissertations

Several nitroxides have been prepared for study of their image enhancement capability. These nitroxides contain different nitroxyl moieties within one molecule. On MRI examination for the nitroxides prepared, TEMPO and HPTPO are better due to their better water solubility, even though some of the others have more nitroxyl centers available. The intensity response is linear with respect to concentration in the range studied in most of the cases except for HPTPO, whose intensity finally reaches maximum when its concentration is higher than 10 mM.

Three sources of biomass, namely, liver microsomes, whole-cell yeast and a bacterial activated sludge consortium, have …

Removal Of Volatile Organic Compounds (Voc's) Acetone And Ethyl Alcohol Emitted In The Manufacture Of A Multi-Base Propellant, Yih-Leu Liu

Theses

The Production Base Modernization Activity located at Picatinny Arsenal, initiated this study for the removal of the low concentrations of VOC's, acetone and ethyl alcohol emitted from the mixer operation and the forced air dry unit in the manufacture of a multi -base propellant. Air pollution requirements necessitate 85 % removal of the VOC's prior to discharge of the vent gases into the atmosphere. Because of the availability of sulfuric acid, it is proposed to use 70 percent or stronger acid as the absorbing agent in a recirculating acid absorption tower.

Vapor - Liquid Equilibrium ( VLE ) data were …

Mineralization Of 2-Chlorophenol Using A Hollow Fiber Ultrafiltration System In Combination With A Reactor Containing An Immobilized White Rot Fungus, Sheau-Ming Tung

Theses

Phanerochaete chrysosporium, a white rot fungus was immobilized on a packed-bed reactor, and was used to mineralize an aqueous stream contaminated with 50 ppm of 2-chlorophenol. Hollow fiber ultrafiltration membranes (for 5,000 daltons and 10,000 daltons molecular weight cut-oft) were utilized to retain the extracellular enzyme resulting from the immobilized fungus in a recirculation loop outside of the reactor.

It was found here that the concentration of proteins (roughly proportional to the extracellular enzyme releasd by the fungus) does not correlate with the rate of degradation of 2-chlorophenol in the system. The protein was concentrated 1.5 fold in the recycle …

Iupac Conference On “New Polymers”, Kyoto, Japan, Otto Vogl, Yoshiki Chujo

Emeritus Faculty Author Gallery

No abstract provided.

Iupac Conference On “New Polymers”, Kyoto, Japan, Otto Vogl, Yoshiki Chujo

Otto Vogl

No abstract provided.

Diffraction In The Binary Encounter Electron Peak Observed In Collisions Of 0.6 Mev Amu⁻¹ I7+, I23+ And Au11+ Projectiles With He And Ar, W. Wolff, J. L. Shinpaugh, H. E. Wolff, Ronald E. Olson, Jee-Ching Wang, S. Lencinas, D. Piscevic, R. Herrmann, H. Schmidt-Böcking

Physics Faculty Research & Creative Works

Relative double differential cross sections for electron emission from collisions of 0.6 MeV amu^-1I⁷⁺and I²³⁺ projectiles with Ar and Au¹¹⁺projectiles with He were measured for electron energies from 100 eV to 2000 eV and for angles from 0° to 50°. Experimentally observed sudden shifts of the position of the binary encounter peak were interpreted as resulting from quantum interference in the scattering of target electrons from the partially stripped projectile ion. To this end calculations for the elastic scattering of free electrons initially at rest in the laboratory reference frame from the screened …

Second Pacific Polymer Conference In Otsu, Shiga, Japan, Otto Vogl, Tatsuki Kitayama, Koichi Hatada

Emeritus Faculty Author Gallery

No abstract provided.

Second Pacific Polymer Conference In Otsu, Shiga, Japan, Otto Vogl, Tatsuki Kitayama, Koichi Hatada

Otto Vogl

No abstract provided.

Product Distributions In The Co2-Nh3-H2o System From Liquid Conductivity Measurements, James E. Pelkie, P. John Concannon, David B. Manley, Bruce E. Poling

Chemical and Biochemical Engineering Faculty Research & Creative Works

The objective of this work was to illustrate how liquid conductivity measurements could be used to provide information about the extent of ionization and the amounts of the various ionic products that are formed in the liquid phase in the CO₂-NH₃-H₂O system. To accomplish this, pressures and liquid-phase conductivities for the CO₂-NH₃-H₂O system were measured at 25 °C and over a range of pressures and concentrations. In order to acquire the desired information from bulk conductivity measurements, calibration curves were established from measurements with several potassium salts. These …

The 33rd Iupac Congress, Budapest, August 17-22, 1991, Otto Vogl, Koichi Hatada

Emeritus Faculty Author Gallery

No abstract provided.

The 33rd Iupac Congress, Budapest, August 17-22, 1991, Otto Vogl, Koichi Hatada

Otto Vogl

No abstract provided.

Modeling Of A-Si : H Deposition In A Dc Glow Discharge Reactor, Dariusz Orlicki, Vladimir Hlavacek, Hendrik J. Viljoen

Papers in Reaction Kinetics

PECVD reactors are increasingly used for the manufacturing of electronic components. This paper presents a reactor model for the deposition of amorphous hydrogenated silicon in a dc glow discharge of Ar-SiH₄ The parallel-plate configuration is used in this study. Electron and positive ion densities have been calculated in a self-consistent way. A macroscopic description that is based on the Boltzmann equation with forwardscattering is used to calculate the ionization rate. The dissociation rate constant of SiH₄ requires knowledge about the electron energy distribution function. Maxwell and Druyvesteyn distributions are compared and the numerical results show that the deposition …

Tenth International Symposium On Cationic Polymerization And Related Processes, Otto Vogl, Gyorgy Deak

Emeritus Faculty Author Gallery

No abstract provided.

Tenth International Symposium On Cationic Polymerization And Related Processes, Otto Vogl, Gyorgy Deak

Otto Vogl

No abstract provided.

In Vitro Development Of Zygotes From Prepubertal Gilts After Microinjection Of Dna, B. L. Williams, J. L. Johnson, A. E.T. Sparks, R. S. Canseco, J. W. Knight, William H. Velander, R. L. Page, W. N. Drohan, J. M. Young, R. E. Pearson, T. D. Wilkins, F. C. Gwazdauskas

Papers in Biotechnology

The effect of pronuclear microinjection of DNA and culture in excised mouse oviducts on the development of porcine zygotes was assessed in this study. Precocious ovulation was induced in prepubertal gilts with pregnant mare's serum gonadotrophin and hCG. Zygotes received either pronuclear microinjection of buffer alone, buffer containing a DNA construct, or no microinjection. Zygotes were cultured in vitro in either modified Krebs-Ringer bicarbonate medium (KRBI for 144 h or in mouse oviduct (MO) explant culture with KRB for 48, 72, 96, or 120 h. Pronuclear microinjection of DNA resulted in a lower (P < .05) cleavage index (CII than did buffer or no microinjection (CI 2.16 k .10 vs 2.80 f .13 and 2.93 f .lo). The CI loss was greatest for DNA-injected zygotes at the two-cell stage of development. Coculture of zygotes in MO resulted in a higher CI (P < .01) than did culture in KRB. Culture in MO for 72 h was the most beneficial system compared with MO for 48, 96, or 120 h (P < .05; CI 3.25 k .12 vs 2.66 k .18, 2.79 f .14, and 2.40 .14, respectively). Microinjection of DNA, not merely the mechanical procedure, was detrimental to early zygote development and may be the cause of low pregnancy rates.

The Fokker–Planck Closure For Turbulent Molecular Mixing: Passive Scalars, Rodney O. Fox

Rodney O. Fox

A turbulent-molecular-mixing closure for passive scalar mixing is derived based on the theory of diffusion in layerlike lamellar structures. The closure is formulated in terms of the Fokker- Planck (FP) equation (or an equivalent stochastic differential equation), and is to be employed in conjunction with the probability density function (pdf) balance equation appearing in the pdf methods for modeling turbulent reactive flows. Like the mapping closure, the FP closure predicts a limiting Gaussian pdf for the passive scalar concentration in isotropic turbulence. In addition, the FP closure models the joint pdf of the scalar concentration and the scalar gradient and …

Prediction Of Paper Color: A Process Simulation Approach, Mayank Chaturvedi

Masters Theses

A simulation model was developed for a dye mixing process and for the prediction of the optical properties of the paper. The model was integrated with the MAPPS (Modular Analysis of Pulp and Paper Systems) simulation software package. The model was validated using dyed handsheets made in a laboratory and dyed paper made on a pilot papermachine. Validation comprised of prediction of the optical properties of the handsheets and the machine-made paper which contained various combinations of three non-fluorescent dyes. Sheet reflectances were predicted at 20 nanometer intervals for discrete light wavelength range of 400 to 700 nanometers and verified …