Engineering Commons^™

Glass Microspheres, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

A radioactive microsphere for radiation therapy of a mammal comprising a biologically compatible glass material containing a beta or gamma emitting radioisotope distributed substantially uniformly throughout the glass. Advantageously, the radioisotope is produced by irradiation of the microsphere.

Anomalous Temperature Dependence Of The Electric Field Gradient At The Y Site In In₀.₁Y₀.₉Ba₂Cu₃O9- Δ, Gary L. Catchen, Michael Blaszkiewicz, Anthony Baratta, Wayne Huebner

Materials Science and Engineering Faculty Research & Creative Works

Perturbed angular correlation (PAC) spectroscopy has been used to measure a well-defined static electric quadrupole interaction in a superconducting ceramic, In_0.1Y_0.9Ba₂Cu₃O_9-δ. Perturbation functions, Fourier transforms, and the derived PAC parameters are given for data taken at temperatures ranging from 77 to 1070 K. Indirect evidence is presented for the occupation of the Y site by the ¹¹¹In-¹¹¹Cd PAC probe. The derived electric field gradients were found to increase linearly with temperature. This result suggests the presence of soft, anisotropic vibrations in the structure. Additional evidence is presented …

Premartensitic Anelasticity In Indium-Thallium Alloys., Manfred Wuttig, C. Y. Lei, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

The linear and nonlinear low frequency internal friction of In-24 at. pct Tl displays a Curie-Weiss type behavior in the temperature range above the transformation temperature. The critical temperature equals the martensite start temperature. It is proposed that the origin of the observed internal friction is the diffusion-controlled interaction of substitutional atoms with the premartensitic strain modulation, tweed.

Structural Characterization Of A High-Temperature, Ionic Conducting Ceramic Using Perturbed Angular Correlation Spectroscopy, Gary L. Catchen, Michael Blaszkiewicz, Khalid Jamil, Dinesh K. Agrawal, Wayne Huebner, Herbert A. Mckinstry, Lorenz H. Menke Jr.

Materials Science and Engineering Faculty Research & Creative Works

Perturbed angular correlation (PAC) spectroscopy has been used to characterize several structural aspects of a high-temperature, ionic conducting ceramic, CaZr3.95Hf0.05P6O24. Hafnium was introduced into the material to provide the PAC probe nuclei, 181Hf/181Ta, which were located primarily at Zr sites. PAC measurements were made over a range of temperatures from 77 to 1180 K, and they have been analyzed and interpreted using several simple models. The distorted octahedral crystal field at the Zr site produced a (low-frequency) static electric quadrupole interaction which can be accurately described by the point-charge model. But, the temperature dependence of the associated electric field gradient …

South East Missouri Lead Belt - A Review 1987, Johh L. Watson

Materials Science and Engineering Faculty Research & Creative Works

The south-east Missouri Lead Belt is, and has been for many years, a major world producer of lead concentrate. This paper reviews the current mill operations in the area and presents detailed information on equipment, operating parameters and metallurgical performance. © 1988.

Glass Formation And Properties In The Sm₂O₃·Al₂O₃·Sio₂ System, Erik M. Erbe

Masters Theses

"The purpose of this investigation was to develop a samarium containing aluminosilicate glass with properties suitable for use in the treatment of rheumatoid arthritis. Microspheres made from these compositions would be neutron activated to produce radioactive Sm-153 which has beta-particle energies suitable for treating rheumatoid arthritis as well as appropriate gamma-ray emission for nuclear imaging. The properties of Sm₂O₃ · AI₂O₃ · SiO₂ glasses containing 10 to 25 mole% Sm₂O₃ were evaluated as a function of composition. The density, refractive index, thermal expansion coefficient, and microhardness increased with increasing Sm …

Sealing Glasses For Titanium And Titanium Alloys, Richard K. Brow, R. D. Watkins

Materials Science and Engineering Faculty Research & Creative Works

Glass compositions containing calcium oxide, alumina, boric oxide, strontium oxide and barium oxide in various mole % combinations were studied. These compositions are capable of forming stable glass to metal seals with titanium and titanium alloys for use as seals for battery headers.

Comments On A Paper By No, Esnouf, San Juan, And Fontozzi, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Effect Of Excess Pbo On The Sintering Characteristics And Dielectric Properties Of Pb(Mg1/3nb2/3)O3–Pbtio3‐Based Ceramics, Jyoti P. Guha, Dyllan J. Hong, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

Additions of excess PbO to the perovskite Pb[(Mg_1/3Nb_2/3)_0.92Ti_0.08]O₃ solid solution enhanced the formation of a liquid phase at 840°C, which served as a densification aid for the ceramics. The liquid phase allowed elimination of pores and promoted grain growth during sintering. With additions of 1 to 2 wt% excess PbO, densities in excess of 97% of theoretical were obtained at a sintering temperature of 950°C. The peak dielectric constants of the resulting ceramics were over 18 000 at 30°C and dissipation factors less than 1%. Additions of PbO in excess of …

The Effect Of Phosphate Additives On Alumina, Alumina-Calcia, Alumina-Silica Refractory Castable Systems, Sukendro Widjaja

Masters Theses

The effects of the addition of phosphate chemicals to Al₂O₃, Al₂O₃-CaO, and Al₂O₃-SiO₂ systems have been studied concentrating on selected dry and fired properties. The various refractories evaluated were formulated from all alumina aggregate systems based on 1) a mix of tabular and calcined fine aluminas, 2) a combination of calcium aluminate cement bonded-tabular and calcined fine aluminas, and 3) an alumina aggregate-silica fume mixture. Specimens were vibration-cast, dried at 110°C and fired at 1450°C. It was found that each system has different property responses to different …

Processing And Characterization Of Ceramic Fiber Reinforced Porous Matrix Composites, Wen-Chiang Tu

Masters Theses

"The development of ceramic fiber reinforced ceramic matrix composites has been shown to be a promising approach for high toughness ceramic materials. The purpose of this work was to develop a new ceramic matrix composite(CMC) system based on a porous mullitic matrix reinforced with ceramic fibers. Unidirectional alligned fiber reinforced mullitic matrix composites were fabricated by a filament winding process. Prepregs were laminated and thermal processed in air. SEM fractographs of the composites were characterized and related to the observed load-deflection behaviors under 3-point flexure. The fracture surface expositions changed from extensive fiber tear-out to limited fiber pull-out as the …

Reductive Stripping Of Iron(Iii) From Di(2-Ethylhexyl) Phosphoric Acid, Byron G. Belew

Masters Theses

"Unwanted impurities, present in raw materials, are often coextracted along with desired constituents during leaching. If left unchecked, impurity levels may increase in hydrometallurgical process streams until their presence has deleterious effects upon subsequent unit processes. Due to its abundance and ease of extraction, the presence of ferric iron in solvent extraction circuits has always been a problem. The technique proposed herein constitutes a novel approach to remove iron from zinc hydrometallurgical circuits; but the principles employed may find a variety of applications.

This research investigated the reduction and stripping of ferric iron from di(2-ethylhexyl) phosphoric acid into a …

Microstructural Analysis In Processing Of The High‐Tc Superconductor Ba2ycu3o7‐X In Air, Jyoti P. Guha

Materials Science and Engineering Faculty Research & Creative Works

In the synthesis of the superconducting compound Ba₂YCu₃O_7‐x from a stoichiometric mixture containing BaCO₃, Y₂O₃, and CuO In air, a low‐melting liquid phase is formed at about 890°C. The liquid phase was identified as a ternary eutectic located within the compatibility triangle Ba₂YCu₃O_7‐x–BaCuO₂–CuO. The implication of this finding for the processing of Ba₂YCu₃O_7‐x is discussed. Copyright © 1988, Wiley Blackwell. All rights reserved.

Sessile Drop Studies Of Aluminum On Sapphire, Ke Wen K. Li

Masters Theses

A sessile drop technique employing a drop placement method has been used to investigate the wetting behavior and interfacial phenomena between aluminum and single crystal α-alumina. Measurements were made under a flowing mixture of H₂ and He atomsphere from 1200°C to 1600°C. Acute contact angles decreased continuously in all cases during the 8-hour experimental time. Neither the oxygen partial pressure of the flowing gas nor the orientation of the single crystal alumina substrate affected the contact angles, but the shapes of crystals grown at the substrate-metal interfaces were dependent on the orientation of the substrate surface to some extent. …

Fabrication And Mechanical Property Analysis Of A Transparent, Glass Fiber Reinforced Polymer Matrix Composite, James R. Olson

Masters Theses

"A "transparent” composite was produced by reinforcing poly(methyl methacrylate) (PMMA) with unidirectional borosilicate glass fibers. Composites with 40 volume percent fiber had a modulus of rupture of 600 MPa which is six times greater than that of pure PMMA. Young's modulus for the same composite was 18 MPA which is nine times greater than the 2 MPa measured for pure PMMA. Work of fracture was 110 kJ/m² or more than double the 45 kJ/m² required to fracture pure PMMA. The optical transmission of the composite with 30 volume percent fiber was approximately 40 percent through a 10 mm …

The Effect Of Additives On Properties Of Pfn-Pfw Dielectric Materials, Weih-Min Liao

Masters Theses

"The purpose of this study was to investigate the effect of processing and additives on the properties of the Pb(Fe_1/2Nb_1/2)O₃-PB(Fe_2/3W_1/3)O₃ solid solutions. The basic composition was 70 m% Pb(Fe_1/2Nb_1/2)O₃ and 30 m% Pb(Fe_2/3W_1/3)O₃. The additives used were MnO, PbO and ZnNbO₆. Pressed compacts were sintered over the temperature range 900'C to 1050°C for 1 to 5 hours.

The influence of processing and composition on the properties was determined by measurement of density, shrinkage, dielectric constant, dissipation factor and …

Effects Of 0.5 Weight Percent Boron On Cobalt Aluminide, Kevin Thomas Slattery

Masters Theses

"A study was made on the effects of adding 0.5 weight percent boron to the ordered intermetallic Cobalt Aluninide. Thirty gram (30g) specimens were induction melted in an pure argon atmosphere and cast into a copper alloy bar mold. The addition of boron raised the modulus of rupture from 30.1 to 44.3 ksi; increased the Knoop microhardness from 543 to 693; reduced the average grain size from 190 to 70 microns; and gave a more equiaxed grain structure. X-ray diffraction detected the presence of a second phase, AlB , 12 in the material containing boron. Scanning electron micro-scopy revealed that …

Influence Of Prior Deformation On Structure And Properties Of Heat Treated Aluminum Casting Alloy, Chungwei Hsia

Masters Theses

"A1 356 alloy is extensively used for a wide variety of casting applications. The structure is composed of primary dendrites and eutectic silicon formed during the eutectic reaction. It has long been recognized that the shape of the eutectic silicon significantly affects the ductility of the alloy. Traditionally, the morphology of the silicon is changed by certain chemical and/or thermal processes to improve the ductility. Mechanically deforming the castings to "modify" the shape of silicon has been shown by this research to be an effective alternative method to improve the spheroidization rate of eutectic silicon during heat treatment. The best …