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Biological Transformation And Detoxification Of 7,12-Dimethylbenzanthracene In Soil, K. Park, Ronald C. Sims, W. J. Doucette, J. E. Matthews
Biological Transformation And Detoxification Of 7,12-Dimethylbenzanthracene In Soil, K. Park, Ronald C. Sims, W. J. Doucette, J. E. Matthews
Biological Engineering Faculty Publications
Biological transformation and detoxification of 7,12-dimethylbenz(a)anathracene (DMBA) were studied in a nonacclimated sandy loam soil. Parent 14C DMBA biodegraded extensively (62% to 20%), accompanying an increase of metabolite 14C fraction (4% to 53%). Incorporation of DMBA into non extractable soil residue ,4C increased from 12 to 17%, but the increase was not statistically significant. DMBA was transformed into several metabolic products in the soil system, including 4-hydroxy-, 5-hydroxy-, and 10-hydroxy-DMBA and 7,12-dihydro 12-methyl-7-methylene-benz(a)anthracene-12-ol. High polarity transformation products of DMBA demonstrated a negative mu tagenic response with the Ames mutagenicity assay, strain TA 100, for both low and neutral pH soils. …