Engineering Commons^™

Fabrication Of Two-Dimensional Material-Based Nano-Capacitors Using Bismuth Selenite (Bi2seo5) To Study Its Dielectric Properties, Major Kc

McKelvey School of Engineering Theses & Dissertations

In recent years, the demand for high-performance micro and nanodevices has surged, necessitating the exploration of novel dielectric materials to replace conventional silicon dioxide. Following the continuation of the Moorse law, as device dimensions reduce to nanoscale levels, the properties of silicon dioxide can degrade, leading to issues such as increased leakage current and reduced gate control. Materials with superior electrical properties, such as higher dielectric constant, lower leakage current, and better thermal stability allowing for the development of faster, more efficient, and more reliable devices are in higher demand than ever. Two-dimensional layered semiconductor nanomaterials represented by compounds such …

Pulsed Dielectric Breakdown And Permittivity Characterization Of Composite Solid Insulators In Pulsed Power Systems, Shawn T. Scoggin

Electrical Engineering Dissertations

In high voltage pulsed power systems, liquids and gases are often used as insulating materials because they offer high breakdown strengths, conform around complex geometries, and are self-healing, but they can introduce significant engineering challenges and restrictions when it comes to implementing them. Solid dielectrics can be desirable for improving the maintenance requirements, shelf life, and power/energy density metrics associated with insulating high voltage pulsed power systems, however they possess design challenges of their own. Solid dielectrics are not self-healing and can be difficult to manufacture, especially around complex geometries. Epoxy dielectrics are of high interest because of their naturally …

Low Temperature Dielectric Strength Of Polyimide-Silica Nanocomposites For Applications In High-Temperature Superconducting Cables, Michael John Mccaffrey

Theses and Dissertations

Gaseous helium is often considered as an alternative to liquid nitrogen to cool modern high-temperature superconducting cables in support of increased power capacity and/or reduction of required cable size. However, the small size of helium molecules and relatively poor dielectric strength of helium gas create challenges which limit the usefulness of modern cable dielectrics. Continuous dielectric coatings have been considered as an alternative to traditional lapped tape dielectrics to support gaseous helium refrigerants, but unmatched thermal contraction between the coating and cable components would induce failures due to mechanical stress. Composite materials have been considered as a means of matching …

Material Characterization For Microwave Absorbing And Shielding Applications, Muhammed Shafeeque Kallumottakkal

Theses

The rapid advancement and widespread of microwave and RF-communication systems have contributed to an abundant rise in electromagnetic energy radiation in our living environment. Such an increase in microwave sources is due to the development and advancement in communication techniques (mobile phones, laptops, and antennas for aeronautics or automobile) and electronic warfare in the military field (radar and satellite). To address these concerns, EM absorbing materials are used to ensure public safety and the safety of military operations. Various types of EM absorbing materials made up of composite materials have been produced and studied. This thesis discusses the microwave properties …

Development Of Synthetic Coal Char Simulant For Microwave Conversion Studies: A Computationally-Driven Approach, Kevin A. Hager

Graduate Theses, Dissertations, and Problem Reports

Recent experimental demonstration of new reaction windows for coal char/methane reactions that are less energy-intensive, provides innovation for modular reactors. However, the correlation of the exact mechanism for the enhancement of these reaction windows is not certain. This study investigates the simplification of these experimental studies by developing a well-characterized coal char simulant. The approach involves using a computational approach to screen macroscopic composition to replicate the dielectric and compositional response of actual char. This study is focused on PRB coal char. A discrete element method (DEM) technique was used to simulate the packing of coal chars to give the …

Bulk Properties Correlated To The Hydrogen Bond Organization In Dendrimers, Hyperbranched Polymers, And Linear Polymers, Beibei Chen

Dissertations

Although a lot of research was conducted on dendritic polymers, our understanding of their structure-property is still limited. Our previous study, which focused on a family of dendritic polymers based on 2,2-bis(hydroxymethyl) propionic acid (bis-MPA) as a monomer, discovered unique hydrogen bond organizations contributed by their dendritic structures. However, the influence of the H-bond organization on bulk properties has yet to be understood. The goal of this dissertation is to elucidate the correlation between the H-bond organization with the dielectric and volumetric properties of bis-MPA based dendritic polymers, with an emphasis on developing a fundamental understanding of to what extent …

Free-Space Measurements Of Dielectrics And Three-Dimensional Periodic Metamaterials, Clifford E. Kintner

Graduate Theses and Dissertations

This thesis presents the free-space measurements of a periodic metamaterial structure. The metamaterial unit cell consists of two dielectric sheets intersecting at 90 degrees. The dielectric is a polyetherimide-based material 0.001” thick. Each sheet has a copper capacitively-loaded loop (CLL) structure on the front and a cut-wire structure on the back. Foam material is used to support the unit cells. The unit cell repeats 40 times in the x-direction, 58 times in the y-direction and 5 times in the z-direction. The sample measures 12” × 12” × 1” in total. We use a free-space broadband system comprised of a pair …

Nonlinear Optical Studies Of Defects And Domain Structures In Perovskite-Type Dielectric Ceramics, David J. Ascienzo

Dissertations, Theses, and Capstone Projects

In order to improve future generations of dielectric capacitors a deeper understanding of voltage-induced dielectric breakdown and electrical energy storage limitations is required. This dissertation presents the use of far-field optical second harmonic generation (SHG) polarimetry for probing structural defects and polar domains in linear and nonlinear perovskite dielectric ceramics. We investigated the formation of electric field-induced structural distortions at pristine Fe-doped SrTiO₃ (Fe:STO) electrode interfaces, structural defect and strain formation due to oxygen vacancy migration in electrodegraded Fe:STO single crystals, and mixed tetragonal and rhombohedral phase domains in ferroelectric Zr-doped BaTiO₃ (BZT) films exhibiting excellent …

Dielectric Characterization Of Mylar And The Effects Of Doping Processes, Cami B. Belcher

Chemical and Biological Engineering ETDs

Mylar® polymer is a bi-axially oriented polyethylene terephthalate (PET) polymer film used widely as a dielectric, specifically in capacitors. The dielectric characteristics of Mylar have been well studied and documented over the years; however, many of the mechanisms responsible for dielectric breakdown and failure are not understood for modified versions of the material. Previous studies on Mylar confirm that factors such as temperature, humidity, and voltage ramp rates can also have a significant effect on the dielectric properties and measurement of the dielectric properties. This study seeks to determine how dielectric properties, including permittivity, dielectric loss, and breakdown strength, are …

Substrate Effects And Dielectric Integration In 2d Electronics, Bhim Prasad Chamlagain

Wayne State University Dissertations

The ultra-thin body of monolayer (and few-layer) two dimensional (2D) semiconducting materials such as transitional metal dichalconiges (TMDs), black phosphorous (BP) has demonstrated tremendous beneficial physical, transport, and optical properties for a wide range of applications. Because of their ultrathin bodies, the properties of 2D materials are highly sensitive to environmental effects. Particularly, the performance of 2D semiconductor electronic devices is strongly dependent on the substrate/dielectric properties, extrinsic impurities and absorbates. In this work, we systematically studied the transport properties of mechanically exfoliated few layer TMD field-effect transistors (FETs) consistently fabricated on various substrates including SiO2,Parylene –C, Al2O3, SiO2 modified …

Dielectric Prism Antenna, Jose Antonio Avila

Open Access Theses & Dissertations

3D printing is revolutionizing the development and manufacturing of devices. Currently multi-material 3D printing, like metals plus dielectrics, is in the early stages and not very accessible. This work set out to develop an all-dielectric antenna that could be 3D printed with current widely accessible 3D printing technologies. The antenna developed is an all-dielectric ultra-thin antenna with a simple geometry. The antenna radiates by using total internal reflection and a circulating mode operating as a leaky whispering gallery mode. We are calling the antenna the dielectric prism antenna because it acts like an optical prism. The dielectric prism antenna was …

Incorporation Of High-K Hfo2 Thin Films In A-Igzo Thin Film Transistor Devices, Aaron Hamilton Bales

Masters Theses

In this study, HfO2 [hafnium oxide] thin films are investigated extensively as part of indium gallium zinc oxide (IGZO) thin film transistor (TFT) devices. They are incorporated into the TFTs, both as a gate insulator and a passivation layer. First, the HfO2 [hafnium oxide] films themselves are investigated through an annealing study and through I-V and C-V measurements. Then, HfO2 [hafnium oxide] is suggested as a replacement for commonly used SiO2 [silicon dioxide] gate insulator, as it has a dielectric constant that is 4 – 6 times higher. This higher dielectric constant allows for comparable TFT performance at a lower …

Verifying Molecular Dynamics Using Dielectric Spectroscopy, Joshua Dee Smith

Theses and Dissertations

The electrical properties of proteins in solution are important for their structure and function. Computational biophysics studies of proteins need accurate parameters to ensure that numerical simulations match physical reality. Past work in this eld has compared the electrical properties of proteins obtained from dielectric spectroscopy to numerical simulations of proteins in water with adjustment of pKa values to try to capture the inevitable changes in electrical conformation that will occur in a complex structure such as a folded protein. However, fundamental veri cation of the charge parameters of the amino acid building blocks in common molecular dynamics software packages …

Property Enhancements Of Dielectric Nanoparticles Via Surface Functionalization, Andrew Byro

Dissertations, Theses, and Capstone Projects

This thesis describes the surface modification of barium strontium titanate nanoparticles for use in polymer/ceramic composite thin film capacitors with resultant improved dielectric and film-making properties. Phosphonic acid-type ligands proved to be most effective for surface conjugation to the surface of the barium strontium titanate nanoparticles. Amine-terminated ligands proved to be effective at removing surface adsorbed water before being almost entirely removed during the sample washing stage. Carboxylic acid terminated ligands proved to adhere less well to the nanoparticle than the phosphonic acid, but resulted in thin films with a higher dielectric constant, which was more stable in the measured …

Investigating The Possible Sources Of Error Using The Method Of Moments To Solve A Dielectric Scattering Problem, Phillip D. Bishop

Master's Theses (2009 -)

In an electromagnetic scattering problem, an incoming electromagnetic wave interacts with an object. The object is typically located in some medium, such as free space. When this electromagnetic wave becomes incident upon the object, the wave scatters. The goal of this work is to analyze the scattered fields for three different incoming wave types: a plane wave, a monopole line source, and a multipole line source. Each source is incident on an infinitely long circular cylinder of lossless dielectric material. Each source has a unique scattering characteristic.

The volume equivalence principle is used to replace the object geometry with mathematically …

Dielectric And Complex Impedance Properties Of Tetravalent Hafnium (Hf 4+) Integrated Cobalt Ferrite, Luis Javier Sanchez

Open Access Theses & Dissertations

The work presented in this thesis was carried out to understand the effects of tetravalent hafnium (Hf4+) ion on the crystal structure and phase, surface morphology, electrical, dielectric and complex impedance properties of cobalt ferrite (CoFe2O4; CFO). Hafnium incorporated cobalt ferrite, CoFe2-xHfxO4, with x = 0.00, 0.05, 0.075, 0.10, 0.15 and 0.20 were prepared by the standard solid state ceramic synthesis method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterizations were performed to determine the structural properties. Most important aspect of this study is to explore the dielectric and complex impedance properties as a function of variable temperature (T=300-1000 …

Enhanced Mechanical Performance Of Low Dielectric Constant Thin Films Synthesized In Supercritical Co2, And Sans Studies Of Microemulsions Induced Or Destabilized By Compressed Co2, Alvin Horatio Romang

Open Access Dissertations

Block copolymer (BCP) phase segregation and self-assembly into two or more distinct domains are primarily dictated by two parameters: the block volume fraction, f, and the product of the segment-segment interaction parameter and the length of polymer chain, XN. The volume fraction determines a block copolymer's phase segregated morphology, whereas XN dictates its overall segregation strength, or phase stability. In order to achieve smaller domain sizes, the interaction parameter must be increased to compensate for the decrease in chain length. In the melt, PEO-b-PPO-b-PEO (Pluronic) triblock copolymer surfactants do not phase segregate primarily due to their low molecular weights …

Development Of Advanced Polymer Nanocomposite Capacitors, Miguel Mendoza

Open Access Theses & Dissertations

The current development of modern electronics has driven the need for new series of energy storage devices with higher energy density and faster charge/discharge rate. Batteries and capacitors are two of the most widely used energy storage devices. Compared with batteries, capacitors have higher power density and significant higher charge/discharge rate. Therefore, high energy density capacitors play a significant role in modern electronic devices, power applications, space flight technologies, hybrid electric vehicles, portable defibrillators, and pulse power applications. Dielectric film capacitors represent an exceptional alternative for developing high energy density capacitors due to their high dielectric constants, outstanding breakdown voltages, …

Design And Analysis Of A Cylindrical Dielectric Resonator Antenna Array And Its Feed Network, John Ashmore

Electronic Theses and Dissertations

There is an ever increasing need for smaller, lighter, more efficient antennas for commercial and military applications. One such antenna that meets these requirements is the dielectric resonator antenna (DRA). In recent years there has been an abundance of research on the utilization of the DRA as a radiating element. However, its practical application - especially pertaining to DRA arrays - is still considered to be at its infancy. The purpose of this work is to present a systematic process to be used in the design, simulation, optimization, fabrication, and testing of a cylindrical DRA array including its associated feed …

A Framework For Determining The Reliability Of Nanoscale Metallic Oxide Semiconductor (Mos) Devices, Wilkistar Otieno

USF Tampa Graduate Theses and Dissertations

An increase in worldwide investments during the past several decades has pro-pelled scienti c breakthroughs in nanoscience and technology research to new and exciting levels. To ensure that these discoveries lead to commercially viable prod-ucts, it is important to address some of the fundamental engineering and scientific challenges related to nanodevices. Due to the centrality of reliability to product integrity, nanoreliability requires critical analysis and understanding to ensure long-term sustainability of nanodevices and systems. In this study, we construct a relia-bility framework for nanoscale dielectric lms used in Metallic Oxide Semiconductor (MOS) devices. The successful fabrication and incorporation of metallic …

Development Of A Plasma Arc Manufacturing Process And Machine To Create Metal Oxide Particles In Water From Wire Feedstock, Jonathan Alan George

Theses and Dissertations

A plasma arc erosion process can be used to create metal and metal oxide particles in the ultra-fine size range (<70 µm). An electric arc is struck between two metallic electrodes, submerged in water, melting the surface of the electrodes. When the arc collapses a high energy pressure wave strikes the molten surface of the electrode. When the pressure wave strikes the molten metal, small metallic particles are created from the molten metal and are immediately cooled in the water. Previous research developed a process that used a constant current power supply and electrode motion to create ultra-fine particles. This research improves upon previous research by using a pulsed power supply similar to those used in Electrical Discharge Machining (EDM). The pulsed power supply eliminates the need for electrode motion and improves the rate of particle production, provides control over size of the particles created, and reduces the amount of energy needed to produce the particles. The new process improves the maximum particle production rate from 3.6 g/hr to 14 g/hr, provides a method to control the mean diameter of the particles produced, and reduces the amount of energy needed from 200 kWh/kg(previous constant current process) to 10.6 kWh/kg(using the pulsed power supply).

Growth, Characterization And Applications Of Multifunctional Ferroelectric Thin Films, Bo Xiao

Theses and Dissertations

Ferroelectric materials have been extensively studied theoretically and experimentally for many decades. Their ferroelectric, piezoelectric, pyroelectric, dielectric and electro-optical properties offer great promise in various applications such as non-volatile random access memory devices, non linear optics, motion and thermal sensors, and tunable microwave devices. Advanced applications for high dielectric constant insulators and nonvolatile memories in semiconductor industry have led to a meteoric rise of interest in the ferroelectrics recently. As most studied and technically important ferroelectric materials, lead zirconate titanate (PZT) and barium strontium titanate (BST) are widely investigated to understand their properties for potential device applications. Using radio frequency …

Effects Of Deposition Temperature And Post Deposition Annealing On The Electrical Properties Of Barium Strontium Titanate Thin Film For Embedded Capacitor Applications, Ranganathan, Ravip Peelamedu

Electronic Theses and Dissertations

A higher degree of system level integration can be achieved by integrating the passive components into semiconductor devices, which seem to be an enabling technology for portable communication and modern electronic devices. Greater functionality, higher performance and increase in reliability can be achieved by miniaturizing and reducing the number of components in integrated circuits. The functional potential of small electronic devices can be enormously increased by implementing the embedded capacitors, resistors and inductors. This would free up surface real estate allowing either a smaller footprint or more silicon devices to be placed on the same sized substrate. This thesis focuses …

A Dielectric Study Of Sodium Carboxymethyl Cellulose, Mohamed Mounir Shalaby

Archived Theses and Dissertations

No abstract provided.