Engineering Commons^™

Strengthening Of Damaged Structural Members With External Frp, Krishna Tulasi Gadde

Graduate Theses, Dissertations, and Problem Reports

Fiber reinforced polymer (FRP) composites are excellent alternatives to traditional materials for civil infrastructure. Several researchers have worked on the application of FRP composites for construction, repair, and rehabilitation of structures. This research aims at evaluating the use of carbon, glass, basalt, and hybrid FRPs with epoxy and polyurethane resin systems for rehabilitation of damaged structural components. Following evaluations were carried out in this research: (i) tension testing of FRP coupons, (ii) compression testing of concrete cylinders with and without damaged sections/FRP reinforcements, (iii) flexural testing of external-FRP reinforced RC beams with and without damages, (iv) pull-off tests on FRP …

Unraveling The Effects Of Molecular Confinement On The Dynamics Of Polymeric Systems: I. Block Copolymer Architecture Ii. Silica Nanopores, Thomas P. Kinsey

Doctoral Dissertations

In this dissertation, broadband dielectric spectroscopy (BDS) is employed as an experimental tool to probe dipolar relaxations in polymeric systems under two types of molecular confinement. First a series of miktoarm star copolymers are used to explore how branching block copolymer architectures constrain polymer relaxations within self-assembled domains in relation to linear systems. Secondly, the effects of hard spatial confinement on the dynamics of polymer chains and of ions in polymerized ionic liquids (PILs) are studied after infiltration into silica nanochannels. Complementary techniques such as transmission electron microscopy, small angle x-ray scattering, and Raman spectroscopy are used to determine various …

The Effects Of Rigid Polyurethane Foam As A Confinement Material On Breaching Charge Detonations, Nathan Franz Paerschke-O'Brien

Masters Theses

"The effects of a rigid polyurethane foam used as a confinement material on four types of breaching explosives were tested, focusing on the changes in shockwave peak pressures, detonation load compression forces, and brisance cratering abilities. The Plate Dent testing procedure was modified to incorporate a load cell force sensor, and two air overpressure sensors were included adjacent to the blast to quantify each test result. The testing variables focused on the polyurethane foam cure times and thickness volumes around the breaching explosives to determine the breaching charges' optimal energy output capabilities when confined by the foam material. The rigid …

Compressive Behavior Of Masonry Columns Confined With Steel Reinforced Grout (Srg) Composite, Sarah Elizabeth Jemison

Masters Theses

"In this study, a new type of composite comprised of steel fiber cords embedded in a natural hydraulic lime mortar matrix, known as steel reinforced grout (SRG), is explored for the use in confinement of masonry columns. An experimental study was carried out to understand the behavior of solid clay brick masonry columns confined by SRG jackets. Twenty-four confined and seven unconfined columns with a square cross-section were tested to failure under a monotonic concentric compressive load. Test parameters considered were the column corner condition, number of fiber jacket layers, and number of fiber overlapping faces. SRG confinement improved the …

Tire-Derived Geo-Cylinders And Polymer Products For Enhancing The Properties Of Base/Sub Base Materials In Pavement Systems, Justin Scott Smith

Graduate Theses, Dissertations, and Problem Reports

As a critical part of the transportation network, pavements offer a safe means for vehicular traffic. Pavements are subjected to many forms of stress during their service life, and they are susceptible to environment related cracking and failures. Failures can be attributed to poor subgrade, freeze-thaw variations, and fatigue under repetitive axle loadings. Reinforcement products such as tire-derived geo-cylinders (TDGC) which make-up mechanical concrete and geo-polymers have been utilized in civil engineering practice, and this research aims to understand the potential life of tested pavement system components set at displacement limitations when reinforced with TDGCs and geo-polymers from exposure to …

The Impact Of Quantum Size Effects On Thermoelectric Performance In Semiconductor Nanostructures, Adithya Kommini

Masters Theses

An increasing need for effective thermal sensors, together with dwindling energy resources, have created renewed interests in thermoelectric (TE), or solid-state, energy conversion and refrigeration using semiconductor-based nanostructures. Effective control of electron and phonon transport due to confinement, interface, and quantum effects has made nanostructures a good way to achieve more efficient thermoelectric energy conversion. This thesis studies the two well-known approaches: confinement and energy filtering, and implements improvements to achieve higher thermoelectric performance. The effect of confinement is evaluated using a 2D material with a gate and utilizing the features in the density of states. In addition to that, …

Confinement Effects And Magnetic Interactions In Magnetic Nanostructures, Kristen Lee Stojak Repa

USF Tampa Graduate Theses and Dissertations

Multifunctional nanocomposites are promising for a variety of applications ranging from microwave devices to biomedicine. High demand exists for magnetically tunable nanocomposite materials. My thesis focuses on synthesis and characterization of novel nanomaterials such as polymer nanocomposites (PNCs) and multi-walled carbon nanotubes (MWCNTs) with magnetic nanoparticle (NP) fillers.

Magnetite (Fe₃O₄) and cobalt ferrite (CoFe2O4) NPs with controlled shape, size, and crystallinity were successfully synthesized and used as PNC fillers in a commercial polymer provided by the Rogers Corporation and poly(vinylidene fluoride). Magnetic and microwave experiments were conducted under frequencies of 1-6 GHz in the presence of …

Behavior Of Expansive Concrete-Filled Steel Tubular (Ecfst) Columns Under Axial Loadings, Abdulaziz Lazkani

Theses

Concrete-filled steel tubes (CFST) have been introduced in high-rise buildings in order to expedite construction and increase the confinement of concrete by the steel tube, and hence increase the capacity of the column cross-section. More recently, expansive additives (EAs) that counteract the shrinkage of concrete have been used in CFST to improve the bond between the concrete and steel tube. Although changing the confinement level exerted by the steel tube on concrete will have an impact on the behavior of CFSTs, little information is available regarding the influence of EAs on the mechanical characteristics of expansive concrete-filled steel tubular (ECFST) …

Circular Rc Columns Partially Confined With Frp, Sahar Y. Ghanem

Theses and Dissertations--Civil Engineering

Wrapping reinforced concrete (RC) columns with Fiber Reinforced Polymer (FRP) composites is effective in increasing their capacity. The current state of art concentrates primarily on fully wrapped RC columns and few studies dealt with partially wrapped columns. The majority of the studies did not account for the influence of the existing steel reinforcement on the column’s behavior. Other studies estimated the total confinement pressure as the sum of the confinement pressure due to the external FRP jacketing and due to the internal transverse steel reinforcement. Few models dealt with the coupled effect of the confinement from steel and partial FRP …

Ab Initio Studies Of Proton Transport In Proton Exchange Membranes, Jeffrey Keith Clark

Doctoral Dissertations

A molecular-level understanding of the factors that contribute to transport properties of proton exchange membranes (PEMs) for fuel cell applications is needed to aid in the development of superior membrane materials. Ab initio electronic structure calculations were undertaken on various PEM ionomer fragments to explore the effects of local hydration, side chain connectivity, protogenic group separation, and specific side chain chemistry on proton dissociation and transfer at low hydration. Cooperative interactions between both intra- and inter-molecular acidic groups and hydrogen bond connectivity were found to enhance proton dissociation at very low degrees of hydration. The energetics associated with proton transfer …

Effects Of Partial Confinement And Local Heating On Healing Efficiencies Of Self-Healing Particulate Composites, Jonah Champagne

LSU Master's Theses

Shape memory polymers are smart materials that can be trained to hold a temporary shape through programming and regain their original shape upon heating. Since there discovery in the 1960s, much research has been devoted to the study of these polymers. Of particular interest in recent years is the study of self-healing shape memory polymers. In a previous study, it has been shown that in order for efficient healing to take place in self-healing shape memory polymers, confinement during healing is essential. Moreover, a two-step close-then-heal (CTH) approach to healing was suggested. It was shown that use of this CTH …

Structural And Dynamical Properties Of Liquid And Solid Phases Of Ionic Liquids Confined Inside Nanoporous Materials, Ramesh Singh

LSU Doctoral Dissertations

The purpose of this research is to investigate the physical properties of ionic liquids (ILs) confined inside nanopores of different materials and morphologies. We are interested to study the effect of pore material, morphology and addition of organic solvents on the properties of confined ILs. Understanding the behavior of ILs inside nanopores is relevant to potential applications of these systems in electrochemical double layer capacitors (EDLCs) and dye sensitized solar cells (DSSCs). Such a fundamental understanding is also crucial to optimize the synthesis of hard-templated 1D nanostructures (nanorods, nanotubes, nanowires) based on organic salts, which may be imparted properties (e.g., …

Efficient Finite Element Modeling Of Reinforced Concrete Columns Confined With Fiber Reinforced Polymers, Dan Hu

LSU Master's Theses

Fiber reinforced polymer (FRP) composites have found extensive applications in the field of Civil Engineering due to their advantageous properties such as high strength-to-weight ratio and high corrosion resistance. This study presents a simple and efficient frame finite element (FE) able to accurately estimate the load-carrying capacity and ductility of reinforced concrete (RC) circular columns confined with externally bonded fiber reinforced polymer (FRP) plates and/or sheets. The proposed FE considers distributed plasticity with fiber-discretization of the cross-sections in the context of a force-based (FB) formulation. The element is able to model collapse due to concrete crushing, reinforcement steel yielding, and …

Fabrication Of Mwcnt Based Gas Sensor Using Site-Selective Growth Of Nanotubes On Gold Patterned Silicon Oxide Substrate, Srikanth Durgamahanty

University of Kentucky Master's Theses

Growth confinement techniques for multi walled carbon nanotubes on Au/SiO₂ surfaces was studied and incorporated into a gas sensor design. A device framework was conceived and a sensor was built to achieve this structure. The fabrication results were analyzed using scanning electron microscopy which confirmed the achievement of highly site-selective growth of carbon nanotubes, exclusively between the interdigitated electrodes. The sensor was then evaluated for its capacitance and conductance response when exposed to NO₂ gas. Variation in sensitivities with frequency and flow rate were analyzed. A mathematical model was derived for such a device structure and the predictions …

Molecular-Level Modeling Of Proton Transport In Aqueous Systems And Polymer Electrolyte Membranes: A Reactive Molecular Dynamics Study, Myvizhi Esai Selvan

Doctoral Dissertations

Proton exchange membrane (PEM) fuel cells are an eco-friendly power source that has great potential to reduce our oil dependence for our stationary and transportation applications. In order to make PEM fuel cells an economically viable option, further effort is needed to improve proton conduction under wide operating conditions and reduce the cost of production. Design and synthesis of novel membranes that have superior characteristics require a fundamental molecular-level understanding of the relationship between the polymer chemistry, water content and proton conduction. The performance of a fuel cell is influenced by the electrochemical and molecular/proton transport processes that occur at …

Performance Of Reinforced Concrete Columns Strengthened With Fiber Reinforced Polymers Under Various Loading Conditions, Mohamed Gamal Mohamed El Sayed

Theses

Strengthening of reinforced concrete (RC) structures with Carbon Fiber Reinforced Polymer (CFRP) composites has been a popular subject that attracted considerable attention from researchers for the last two decades. The high specific strength, stiffness, environmental resistance, and ease of application make CFRP composites highly desirable for strengthening and rehabilitation of RC structural components.

For concentrically loaded RC members with a circular cross-section, the lateral CFRP-confinement of concrete results in a substantial increase in load capacity and ductility. CFRP-confinement is less effective for RC compression members with square and rectangular cross-sections due to stress concentration at the corners and lack of …

Frp Confined Reinforced Concrete Circular Cross Section Seismic Applications, Jeffrey G. Lyon

Master's Theses

In recent earthquakes, structures have not performed as well as expected resulting in a need for better means of retrofitting and improvements in seismic design. Fiber Reinforced Polymers (FRP), as a material with potential to increase strength and ductility of columns in conjunction with capacity design methodology, has promise for seismic design. By investigating the displacement, ductility, and flexural strength properties of FRP confined reinforced concrete circular cross sections, this study analyzes the seismic applications of FRP confinement.

The study is performed by incorporating an FRP confined concrete stress-strain model into a developed Moment-Curvature and PM Interaction software. This software …