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Full-Text Articles in Engineering

The Effects Of Solution Condition On Virus Filtration Performance, Fnu Namila Dec 2020

The Effects Of Solution Condition On Virus Filtration Performance, Fnu Namila

Graduate Theses and Dissertations

Virus filtration is an integral part of the downstream purification of mammalian cell culture-derived biotherapeutics to assure the viral safety of the products. Virus filtration membranes remove viruses based on a size-exclusion mechanism. Commercial parvovirus filers possess unique membrane structure and are designed to remove smaller non-enveloped parvoviruses with size 18-26 nm. However, some filters face issues, such as pre-mature fouling, the decline of filtrate flux, and reduction in virus retention. This doctoral dissertation focused on identifying the factors that influence the filtrate flux and the virus retention capability of commercial virus filters. The effects of solution pH and ionic …


Optimization And Longevity Of Functionalized Multi-Walled Carbon Nanotube-Enabled Membranes For Water Treatment, Madeleine Michael Isabella White Jun 2020

Optimization And Longevity Of Functionalized Multi-Walled Carbon Nanotube-Enabled Membranes For Water Treatment, Madeleine Michael Isabella White

Master's Theses

Water scarcity is a growing concern at the global scale. Large scale water reuse is growing both in necessity and popularity. Before water reuse can be performed efficiently on a large scale or be used for potable supply, even indirectly, contaminants of emerging concern (CECs) will need to be treated at the full scale. Advanced oxidation processes (AOPs) are a form of advanced water treatment capable of treating a wide range of CECs. This study contributes to the growing field of AOPs and more specifically AOPs using ozone combined with functionalized multi-walled carbon nanotubes (MWCNTs). Ozonation of MWCNTs has been …


Scale-Up Of Polyaniline Cellulose Membranes, Isaac Bodemann May 2020

Scale-Up Of Polyaniline Cellulose Membranes, Isaac Bodemann

Chemical Engineering Undergraduate Honors Theses

Polyaniline coated cellulose membranes show impressive conductive properties that may be used to innovate traditional charged separation techniques, such as electrodeionization. However, these membranes are not sold to consumers, so they cannot be easily integrated into such systems. This research focuses on the scale-up and development of positively charged anion exchange membranes to be used in EDI cells. Novel cellulose membranes were made using lab-specific cellulose. These membranes were then coated using a polyaniline technique adopted from a paper titled, “Flexible Electrically Conductive Nanocomposite Membrane Based on Bacterial Cellulose and Polyaniline." This paper details the methods used to add the …


Ab Initio Investigation On The Surface Chemistry Of Functionalized Titania Membranes, Evan Hyde Jan 2020

Ab Initio Investigation On The Surface Chemistry Of Functionalized Titania Membranes, Evan Hyde

Theses and Dissertations--Chemical and Materials Engineering

Titania (titanium dioxide) is a metal oxide which has recently been investigated as a photocatalyst, most commonly for use in hydrolysis, which absorbs mostly in the UV range. However, the range of absorption can be shifted to fall within the visible light range either by doping or by functionalizing the surface with atomic or molecular adsorbates. Over the course of this research, a series of Density Functional Theory (DFT) calculations are performed to ascertain the effects of these different methods on the photocatalytic performance of titania. While the effects of nitrogen doping and oxygen vacancies are well known, more recent …


Methods For Film Coating Electrospun Fibers, Kristopher Dejean Jan 2020

Methods For Film Coating Electrospun Fibers, Kristopher Dejean

Williams Honors College, Honors Research Projects

Electrospinning uses high voltages to form polymer nanofiber membranes. These membranes have potential for use in filtration, tissue engineering, drug delivery, and catalysis. The nonwoven fiber mat is malleable but has a low tensile strength compared to a solid film of the same polymer. Joining the fibers with a thin film is desired to balance the strength and flexibility. Three methods of producing a film on fiber membrane were tested. The techniques are spraying then melting, spin coating, and dip coating. Electrospinning setup conditions, solvent ratios, damage to fibers, and spin coating speeds were determined. Research was abruptly stopped and …