Engineering Commons^™

Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang

McKelvey School of Engineering Theses & Dissertations

Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …

Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang

McKelvey School of Engineering Theses & Dissertations

Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …

Novel Design And Synthesis Of Composite Nanomaterials For Lithium And Multivalent Ion Batteries, Wangwang Xu

LSU Doctoral Dissertations

Nowadays, the fast-increasing energy demand for efficient, sustainable and environmentally-friendly energy storage devices remains a significant and challenging issue. Lithium ion batteries (LIBs) have been widely used as commercial energy devices in portable electronics and also shown great promise in upcoming large-scale applications due to their advantages of environmental safety, efficiency in energy delivering and light weight. However, due to their limited capacity, energy densities and cycle ability, LIBs still need further improvement to expand their applications to a larger field, especially electric vehicle (EVs) and hybrid electric vehicles (HEVs), in which energy storage devices with large capacity and high …

Synthesis Of Crumpled Graphene And Titanium Dioxide Based–Nanomaterials And The Application To Carbon Dioxide Photoreduction, Yao Nie

McKelvey School of Engineering Theses & Dissertations

With the rapid development of the economy, increasing combustion of fossils fuels has caused an increase in the atmospheric carbon dioxide (CO2) level, and has led to global climate change. As a mitigation approach, CO2 capture and conversion (CCC) can not only capture CO2, but also convert it to useable products, such as hydrocarbon fuels. Photocatalytic reduction is an attractive CCC option that directly harnesses inexpensive and abundant solar energy. Titanium dioxide (TiO2) is a widely used semiconductor for photocatalysis, and graphene nanosheets are a promising material for use in fabricating graphene-TiO2 hybridized photocatalysts. To realize the application of these …

Opto-Thermal Characterization Of Plasmon And Coupled Lattice Resonances In 2-D Metamaterial Arrays, Vinith Bejugam

Graduate Theses and Dissertations

Growing population and climate change inevitably requires longstanding dependency on sustainable sources of energy that are conducive to ecological balance, economies of scale and reduction of waste heat. Plasmonic-photonic systems are at the forefront of offering a promising path towards efficient light harvesting for enhanced optoelectronics, sensing, and chemical separations. Two-dimensional (2-D) metamaterial arrays of plasmonic nanoparticles arranged in polymer lattices developed herein support thermoplasmonic heating at off-resonances (near infrared, NIR) in addition to regular plasmonic resonances (visible), which extends their applicability compared to random dispersions. Especially, thermal responses of 2-D arrays at coupled lattice resonance (CLR) wavelengths were comparable …

Development Of Nanostructures By Atomic And Molecular Layer Deposition, Andrew P. Lushington

Electronic Thesis and Dissertation Repository

Atomic layer deposition (ALD) is a thin film deposition technique that has a rich history of being an enabling technique. This vapor phase deposition process can produce a variety of thin films and nanostructures. ALD is based on sequential, self-limiting reactions and provides angstrom level control over film growth. Furthermore, ALD allows for conformal deposition on high-aspect ratio structures and can provide tunable film composition. As nanotechnology marches forward, the development of nanomaterials has significantly advanced. Additional functionality can be imparted to nanomaterials by using surface modification techniques. Given the advantages of ALD, this technique has become a powerful tool …

Combustion Of Nanocomposite Thermite Powders, Ian Monk

Dissertations

This work investigates combustion of nanocomposite thermite powders prepared by arrested reactive milling (ARM). The focus is on how ARM as a top-down approach to nano-thermite building generating fully-dense nanocomposite particles with dimensions of 1-100 µm affects the rates and mechanism of their combustion. A variety of thermites are milled using both aluminum and zirconium as fuels combined with several oxidizers (WoO₃, MoO₃, CuO, Fe₂O₃, and Bi₂O₃). The powders are ignited using both an electrostatic discharge (ESD) and a CO₂ laser beam.

A range of parameters vary …

Nonlinear Coupled Effects In Nanomaterials, Sia Bhowmick

Theses and Dissertations (Comprehensive)

Materials at the nanoscale have different chemical, structural, and optoelectrical properties compared to their bulk counterparts. As a result, such materials, called nanomaterials, exhibit observable differences in certain physical phenomena. One such resulting phenomenon called the piezoelectric effect has played a crucial role in miniature self-powering electronic devices called nanogenerators which are fabricated by using nanostructures, such as nanowires, nanorods, and nanofilms. These devices are capable of harvesting electrical energy by inducing mechanical strain on the individual nanostructures. Electrical energy created in this manner does not have environmental limitations. In this thesis, important coupled effects, such as the nonlinear piezoelectric …