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Development And Evaluation Of A Calibration Free Exhaustive Coulometric Detection System For Remote Sensing., Thomas James Roussel
Development And Evaluation Of A Calibration Free Exhaustive Coulometric Detection System For Remote Sensing., Thomas James Roussel
Electronic Theses and Dissertations
Most quantitative analytical measurement techniques require calibration to correlate signal with the quantity of analyte. The purpose of this study was to employ exhaustive coulometry, an implementation of coulometric analysis in a stopped-flow, fixed-volume, thin-layer cell, to attain calibration-free measurements that would directly benefit intervention-free analysis systems designed for remote deployment. This technique capitalizes on the short diffusion lengths (< 100 µm) to dramatically reduce the time for analysis (< 30 sec). For this work, a thin-layer fluidic cell was designed in software, fabricated via CNC machining, and evaluated using Ferri/Ferrocyanide {Fe(CN)63-/4-} as a model analyte. The 2 µL fixed volume incorporated an oval, 8mm by 4 mm, thin-film gold electrode sensor with an integrated Ag|AgCl pseudo-reference electrode. The flow cell area matched the shape of the sensor, with a volume set by the thickness of a laser-cut silicone rubber gasket (~80 µm). A semi-permeable membrane isolated the working electrode and counter electrode chambers to prevent analyte diffusion. A miniaturized custom potentiostat was designed and built to measure reaction currents ranging from 10 mA to 0.1 nA. Software was developed to perform step voltammetry as well as cyclic voltammetry analysis for verifying electrode condition and optimal redox potential levels. Experimentally determined oxidation/reduction potentials of -100 mV and 400 mV, respectively, were applied to the working electrode for sample concentrations ranging from 50 µM to 10,000 µM. The current generated during the reactions was recorded and the total charge captured at each concentration was obtained by integrating the amperograms. When compared to the expected charge for a 2 µL sample, the total charge vs. concentration plots displayed a near perfect linearity over the full concentration range, and the expected charge (100 % converted) was reached within 20 seconds. The reaction currents ideally should have decayed to background levels, but exhibited constant offset values slightly larger than the background signal, a phenomenon assumed to be lingering residual flow from sample injection. After adding rigid tubing and external valves, the thin-layer cell was shown to remain within 6% of the theoretical charge after 200 seconds. Continued development of this system will offer the possibility of remote, calibration-free determinations of real-world analytes such mercury and lead.
Integrated Remote Sensing And Forecasting Of Regional Terrestrial Precipitation With Global Nonlinear And Nonstationary Teleconnection Signals Using Wavelet Analysis, Lee Mullon
Electronic Theses and Dissertations
Global sea surface temperature (SST) anomalies have a demonstrable effect on terrestrial climate dynamics throughout the continental U.S. SST variations have been correlated with greenness (vegetation densities) and precipitation via ocean-atmospheric interactions known as climate teleconnections. Prior research has demonstrated that teleconnections can be used for climate prediction across a wide region at sub-continental scales. Yet these studies tend to have large uncertainties in estimates by utilizing simple linear analyses to examine chaotic teleconnection relationships. Still, non-stationary signals exist, making teleconnection identification difficult at the local scale. Part 1 of this research establishes short-term (10-year), linear and non-stationary teleconnection signals …
Remote Sensing With Computational Intelligence Modelling For Monitoring The Ecosystem State And Hydraulic Pattern In A Constructed Wetland, Golam Mohiuddin
Remote Sensing With Computational Intelligence Modelling For Monitoring The Ecosystem State And Hydraulic Pattern In A Constructed Wetland, Golam Mohiuddin
Electronic Theses and Dissertations
Monitoring the heterogeneous aquatic environment such as the Stormwater Treatment Areas (STAs) located at the northeast of the Everglades is extremely important in understanding the land processes of the constructed wetland in its capacity to remove nutrient. Direct monitoring and measurements of ecosystem evolution and changing velocities at every single part of the STA are not always feasible. Integrated remote sensing, monitoring, and modeling technique can be a state-of-the-art tool to estimate the spatial and temporal distributions of flow velocity regimes and ecological functioning in such dynamic aquatic environments. In this presentation, comparison between four computational intelligence models including Extreme …