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Full-Text Articles in Engineering
Synchrotron X-Ray Diffraction And Piezospectroscopy Used For The Investigation Of Individual Mechanical Effects From Environmental Contaminants And Oxide Layer Undulations In Thermal Barrier Coatings, Sanna Siddiqui
Electronic Theses and Dissertations
The durability of Thermal Barrier Coatings (TBCs) used on the turbine blades of aircraft and power generation engines has been known to be affected by sand particle ingression comprised of Calcium-Magnesium-Alumina-Silicate (CMAS). Previous studies have shown that these effects present themselves through variations in the thermomechanical and thermochemical properties of the coating. This study investigated the impact of CMAS ingression on the Yttria Stabilized Zirconia Topcoat (YSZ) and Thermally Grown Oxide (TGO) strain in sprayed Thermal Barrier Coating (TBC) samples of varying porosity with and without CMAS ingression. In-Situ Synchrotron X-ray Diffraction measurements were taken on the sample under thermal …
Nanocomposite Coating Mechanics Via Piezospectroscopy, Gregory Freihofer
Nanocomposite Coating Mechanics Via Piezospectroscopy, Gregory Freihofer
Electronic Theses and Dissertations
Coatings utilizing the piezospectroscopic (PS) effect of alpha alumina could enable on the fly stress sensing for structural health monitoring applications. While the PS effect has been historically utilized in several applications, here by distributing the photo-luminescent material in nanoparticle form within a matrix, a stress sensing coating is created. Parallel to developing PS coatings for stress sensing, the multi-scale mechanics associated with the observed PS response of nanocomposites and their coatings has been applied to give material property measurements, providing an understanding of particle reinforced composite behavior. Understanding the nanoparticle-coating-substrate mechanics is essential to interpreting the spectral shifts for …
Piezospectroscopic Calibration Of Alumina-Nanocomposites For The Development Of Stress-Sensing Structures, Daniela Fugon-Dessources
Piezospectroscopic Calibration Of Alumina-Nanocomposites For The Development Of Stress-Sensing Structures, Daniela Fugon-Dessources
Electronic Theses and Dissertations
Alpha-alumina is known to exhibit photo-luminescent (PL) properties, mainly characteristic R-lines that shift according to applied stress. In addition to showing excellent PL properties, polymers with embedded alumina nanoparticles have been shown to improve the overall composite mechanical properties. While the use of the PL properties to develop stress-sensing materials using an alumina-epoxy material has been success- fully shown in compression, the properties have not been developed for tension. In this study, the PL response of variable volume fraction alumina-epoxy composites will be determined under tensile conditions. It is expected that increasing the volume fraction of alumina nanoparticles will increase …
Load Transfer In An Isolated Particle Embedded Within An Epoxy Matrix, Erik Durnberg
Load Transfer In An Isolated Particle Embedded Within An Epoxy Matrix, Erik Durnberg
Electronic Theses and Dissertations
Particulate composites are widely used in many aerospace applications such as protective coatings, adhesives, or structural members of a body and their mechanical properties and behavior have gained increasing significance. The addition of modifiers such as alumina generally leads to improved mechanical properties. This addition also enables the non-invasive study of the load transfer between the particle and the matrix. Understanding the load transfer between the particulate and the matrix material is the first step to understanding the behavior and mechanical properties of the composite as a whole. In this work, samples with an isolated alumina particle embedded in an …