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Full-Text Articles in Engineering
Dropwise Condensation Dynamics In Humid Air, Julian Eduardo Castillo Chaco
Dropwise Condensation Dynamics In Humid Air, Julian Eduardo Castillo Chaco
Open Access Theses
Dropwise condensation of atmospheric water vapor is important in multiple practical engineering applications. The roles of environmental factors and surface morphology/chemistry on the condensation dynamics need to be better understood to enable efficient water-harvesting, dehumidication, and other psychrometric processes. Systems and surfaces that promote faster condensation rates and self-shedding of condensate droplets could lead to improved mass transfer rates and higher water yields in harvesting applications. The thesis presents the design and construction of an experimental facility that allows visualization of the condensation process as a function of relative humidity. Dropwise condensation experiments are performed on a vertically oriented, hydrophobic …
Application Of Bayesian Networks In Consumer Service Industry, Yuan Gao
Application Of Bayesian Networks In Consumer Service Industry, Yuan Gao
Open Access Theses
Gao, Yuan. M.S.I.E., Purdue University. December 2014. Application of Bayesian Networks in Consumer Service Industry. Major professor: Vincent G. Duffy The purpose of the present study is to explore the application of Bayesian networks in the consumer service industry to model causal relationships within complex risk factor structures using aggregate data. An analysis of the Hawaii tourism market was conducted to find out how visitor characteristics affect their behavior and experience as consumers during the trips, and influence the tourism market outcomes represented by measurable factors. Two hypotheses were proposed regarding the use of aggregate data and the influence of …
High-Purity Gallium Analysis By Inductively Coupled Plasma Mass Spectrometry, Kyungjean Min
High-Purity Gallium Analysis By Inductively Coupled Plasma Mass Spectrometry, Kyungjean Min
Open Access Theses
The mobility of Two-dimensional Electron Gas in AlGaAs/GaAs heterostructures that are grown in the Molecular Beam Epitaxy (MBE) can be increased by purification of the gallium used to grow the films. To attain 200 million cm2/Vs mobility, the impurity concentration of gallium should be reduced to below 1 ppb. The commercial 7N (99.99999%) gallium with 100 ppb total impurity is currently used in the MBE at Purdue University and is being purified by zone refining. To evaluate the commercial 7N gallium and establish the methodology for the impurity measurement after zone refining, germanium, iron, and zinc in 6N and 7N …
Identifying Conditions To Optimize Lactic Acid Production From Food Waste, Raymond M. Redcorn
Identifying Conditions To Optimize Lactic Acid Production From Food Waste, Raymond M. Redcorn
Open Access Theses
There is an increased demand for lactic acid for the production of biopolymers and to aid nutrient removal in wastewater treatment. Food waste offers a source of soluble sugars to produce lactic acid, which does not increase land demand, but digestion conditions have yet to be optimized when co-digested with primary sludge. Food waste was collected from cafeteria waste bins, homogenized and seeded with primary sludge. A Box Behnken Response surface design was used to optimize lactic acid production based on pH, temperature, loading rate, and retention time. Subsequent experiments verified and refined those conditions to optimize for both yield …
Impact Of Nanostructure On Polymer-Based Nonvolatile Memory Devices, Seung Hyun Sung
Impact Of Nanostructure On Polymer-Based Nonvolatile Memory Devices, Seung Hyun Sung
Open Access Theses
Memory functionality is essential for many high-end electronic applications (e.g. , smart phones, personal computers). Particularly, organic nonvolatile memory devices based on polymer ferroelectric materials are a promising approach toward the development of low-cost memory due to the ease of processing and flexibility associated with the device. Here, we will focus on a memory device with a two-component active layer and a diode structure. This ferroelectric diode (FeD) has a nanostructured active layer, composed of ferroelectric and semiconducting polymers, and it can provide easy access to high-performance polymer-based memory devices. In order to create these nanostructured active layers, we …
Correlating Molecular Architecture Of A Radical Polymer Based Copolymer With Its Electrical Transport Properties, Holly Chan
Open Access Theses
The design and synthesis of electrically-conductive macromolecules can lead to significant improvements in the performance of polymer-based energy conversion devices (e.g., thermoelectric devices). For these organic electronic devices, conjugated polymers have dominated the area of conductive polymers; however, these materials are usually synthesized using conditions that lead to poorly-defined polymers. Furthermore, in these increasingly-standard polymers, the charge transport ability of the polymer thin films is largely affected by the degree of crystallinity, which is a difficult property to control in a reproducible fashion. Therefore, we seek to explore a new class of amorphous, non-conjugated polymers containing a stable radical …
Optical Position Sensing In Free Space Optical Communication, Muhammad Salman Bashir
Optical Position Sensing In Free Space Optical Communication, Muhammad Salman Bashir
Open Access Theses
In this thesis the performance of three estimators, (center of gravity, template matching and maximum likelihood (MLE)) to estimate the center of the beam on a photoemissive receiver array in a Free Space Optics (FSO) system, is compared in terms of mean square error. Simulations have been conducted in Matlab by generating a two dimensional nonhomogeneous Poisson process, and, mean square error is computed for three estimators. The cases of continuous and discrete arrays are also considered for various levels of signal-to-noise (SNR) ratio. Simulations have shown that the MLE gives the least mean squared error and especially performs significantly …
Feasibility Analysis Of Large Length-Scale Thermocapillary Flow Experiment For The International Space Station, Samantha Jean Alberts
Feasibility Analysis Of Large Length-Scale Thermocapillary Flow Experiment For The International Space Station, Samantha Jean Alberts
Open Access Theses
The investigation of microgravity fluid dynamics emerged out of necessity with the advent of space exploration. In particular, capillary research took a leap forward in the 1960s with regards to liquid settling and interfacial dynamics. Due to inherent temperature variations in large spacecraft liquid systems, such as fuel tanks, forces develop on gas-liquid interfaces which induce thermocapillary flows. To date, thermocapillary flows have been studied in small, idealized research geometries usually under terrestrial conditions. The 1 to 3m lengths in current and future large tanks and hardware are designed based on hardware rather than research, which leaves spaceflight systems designers …
Drift-Flux Correlation Development For Two-Phase Flow In Rod Bundles, Collin M. Clark
Drift-Flux Correlation Development For Two-Phase Flow In Rod Bundles, Collin M. Clark
Open Access Theses
A rod bundle drift-flux correlation is developed with intended application across a wide range of two-phase flow conditions. Special consideration is made for fluid flow mechanisms at low liquid velocity and low pressure conditions. In these instances, gravitational forces from the density difference of the associated fluid phases are more significant. Secondary flow patterns may develop as a result and a drift-flux correlation would need to make appropriate adjustments. Earlier correlations may have increased error at these conditions if they have been formulated with respect to relatively higher pressures or flow rates. In the present work, area-average void fraction data …
The Development Of 6.7% Efficient Copper Zinc Indium Selenide Devices From Copper Zinc Indium Sulfide Nanocrystal Inks, Brian Kemp Graeser
The Development Of 6.7% Efficient Copper Zinc Indium Selenide Devices From Copper Zinc Indium Sulfide Nanocrystal Inks, Brian Kemp Graeser
Open Access Theses
As solar cell absorber materials, alloys of CuIn(S,Se)2 and Zn(S,Se) provide an opportunity to reduce the usage of indium along with the ability to tune the band gap. Here we report successful synthesis of alloyed (CuInS2 )0.5(ZnS)0.5 nanocrystals by a method that solely uses oleylamine as the liquid medium for synthesis. The reactive sintering of a thin film of these nanocrystals via selenization at 500 °C results in a uniform composition alloy (CuIn(S,Se)2 )0.5 (Zn(S,Se)) 0.5 layer with micron size grains. Due to the large amount of zinc in the film, the sintered grains exhibit the zinc blende structure instead …
Effect Of Multivalent Ions On The Swelling And Mechanical Behavior Of Superabsorbent Polymers (Saps) For Mitigation Of Mortar Autogenous Shrinkage, Qian Zhu
Open Access Theses
The chemical and physical structure-property relationships of model superabsorbent polymer (SAP) hydrogels were characterized with respect to swelling behavior and mechanical properties in different ionic solutions (Na+ , Ca2+ , and Al3+ ). The model hydrogels were composed of poly(sodium acrylate-acrylamide) (PANa-PAM) copolymer with varying concentrations of PANa (0, 17, 33, 67, and 83 wt.%) and covalent crosslinking densities of 1, 1.5, and 2 wt.%. By synthesizing the hydrogels in-house, systems with independently tunable amounts of covalent crosslinking and anionic functional groups were created, allowing for the relative effects of covalent and ionic crosslinking on the properties of the hydrogels …