Engineering Commons^™

Characterization Techniques And Electrolyte Separator Performance Investigation For All Vanadium Redox Flow Battery, Zhijiang Tang

Doctoral Dissertations

The all-vanadium redox flow battery (VRFB) is an excellent prospect for large scale energy storage in an electricity grid level application. High battery performance has lately been achieved by using a novel cell configuration with advanced materials. However, more work is still required to better understand the reaction kinetics and transport behaviors in the battery to guide battery system optimization and new battery material development. The first part of my work is the characterization of the battery systems with flow-through or flow-by cell configurations. The configuration difference between two cell structures exhibit significantly different polarization behavior. The battery output can …

Micro Solar Thermal Energy Development And Use For Mems Power Applications, Emmanuel Ogbonnaya

Doctoral Dissertations

Increasing focus on alternative energy sources has produced significant progress across a wide variety of research areas. One particular area of interest has been solar energy. The sun represents sustainable and renewable energy source capable of meeting present energy needs without compromising the ability of future generations to meet theirs. Energy from the sun can be utilized in multiple ways. Direct rise in modern power generation typically involves either photovoltaic systems or large-scale solar thermal energy installations. While large-scale solar thermal energy generation is well advanced, there has been comparatively little research on smaller scale thermal energy collection and application. …

Fully Coupled Fluid And Electrodynamic Modeling Of Plasmas: A Two-Fluid Isomorphism And A Strong Conservative Flux-Coupled Finite Volume Framework, Richard Joel Thompson

Doctoral Dissertations

Ideal and resistive magnetohydrodynamics (MHD) have long served as the incumbent framework for modeling plasmas of engineering interest. However, new applications, such as hypersonic flight and propulsion, plasma propulsion, plasma instability in engineering devices, charge separation effects and electromagnetic wave interaction effects may demand a higher-fidelity physical model. For these cases, the two-fluid plasma model or its limiting case of a single bulk fluid, which results in a single-fluid coupled system of the Navier-Stokes and Maxwell equations, is necessary and permits a deeper physical study than the MHD framework. At present, major challenges are imposed on solving these physical models …

Toward Direct Biosynthesis Of Drop-In Ready Biofuels In Plants: Rapid Screening And Functional Genomic Characterization Of Plant-Derived Advanced Biofuels And Implications For Coproduction In Lignocellulosic Feedstocks, Blake Lee Joyce

Doctoral Dissertations

Advanced biofuels that are “drop-in” ready, completely fungible with petroleum fuels, and require minimal infrastructure to process a finished fuel could provide transportation fuels in rural or developing areas. Five oils extracted from Pittosporum resiniferum, Copaifera reticulata, and surrogate oils for Cymbopogon flexuosus, C. martinii, and Dictamnus albus in B20 blends were sent for ASTM International biodiesel testing and run in homogenous charge combustion ignition engines to determine combustion properties and emissions. All oils tested lowered cloud point. Oils derived from Copaifera reticulata also lowered indicated specific fuel consumption and had emissions similar to the ultra-low sulfur diesel control. Characterization …

Essentially Analytical Theory Closure For Space Filtered Thermal-Incompressible Navier-Stokes Partial Differential Equation System On Bounded Domains, Mikhail Alexandrovich Sekachev

Doctoral Dissertations

Numerical simulation of turbulent flows is identified as one of the grand challenges in high-performance computing. The straight forward approach of solving the Navier-Stokes (NS) equations is termed Direct Numerical Simulation (DNS). In DNS the majority of computational effort is spent on resolving the smallest scales of turbulence, which makes this approach impractical for most industrial applications even on present-day supercomputers. A more feasible approach termed Large Eddy Simulation (LES) has evolved over the last five decades to facilitate turbulent flow predictions for reasonable Reynolds (Re) numbers and domain sizes. LES theory uses the concept of convolution with a spatial …

Plasmonics Resonance Enhanced Active Photothermal Effects In Aluminum Nanoenergetics For Propulsion Applications, Jacques Abboud

Doctoral Dissertations

In this dissertation, aluminum nanoparticles (Al NPs) are shown capable to on-demand enhance and control the local photothermal energy deposition, both spatially and temporally, via active photothermal effects initiated by the localized surface plasmon resonance (LSPR) phenomenon, and amplified by the Al exothermal oxidation reactions. Experiments in dry and wet environments along with computational modeling of the photothermal process are very desirable for gaining fundamental understanding, ignition optimization and parameter exploration.

Combined phenomena of motion and ignition of Al NPs are explored first in this study. Both resulting from exposing a pile of the nanoenergetics in hand to a single …

Multidimensional Compressible Framework For Modeling Biglobal Stability In Rocket Motors, Michel Henry Akiki

Doctoral Dissertations

Rocket motor stability analysis has historically been focused on two fundamental theories: the acoustic and the hydrodynamic. While the acoustic part examines the system at resonant states, the hydrodynamic component focuses on the fluid-wall interactions and the vortex shedding mechanisms which are responsible for exciting the system. Traditionally, the two concepts are studied independently and their results are then superposed for a more complete solution. In this study, we analyze the problem from a hydrodynamic standpoint and extend it to include compressibility. This is realized by reducing the linearized Navier-Stokes and energy equations to their biglobal form assuming a two-dimensional …

Experimental And Theoretical Investigations Of Lube Oil Performance And Engine Friction, William Fredrick Rohr

Doctoral Dissertations

The feasibility of using a motored small, single-cylinder 517 cc Hatz 1D50 diesel engine to evaluate lube oil performance and engine friction at conditions typical for a fired engine is investigated in the present study. In addition a commercial engine modeling software, AVL Excite Power Unit, is used to predict the effects of lube oil formulations on the engine friction of the same engine. The motored engine can be operated with and without compression and with and without the engine oil pump. Lube oil performance is evaluated for 19 different lube oils by using either instantaneous motoring torque (motoring torque …

Vibration Based Damage Identification Of Time-Varying Dynamical Systems, Jie Zhao

Doctoral Dissertations

This thesis develops and explores two new kinds of vibration-based damage identification methodologies suitable for dynamical systems with periodically time-varying coefficients; 1) a Floquet based method (Methodology I) and, 2) a Sideband Frequency Response Function (FRF) method (Methodology II). One important class of dynamical systems where periodic time-varying parametric terms naturally arise is rotordynamic systems. For the case of a flexible shaft-rotor system with multiple open cracks, this thesis explores a new Least Squares damage identification approach based on Floquet theory with iterative eigenvector estimate updating. It is found that this method is able to detect the location and severity …

Approximate Dynamic Programming Based Solutions For Fixed-Final-Time Optimal Control And Optimal Switching, Ali Heydari

Doctoral Dissertations

"Optimal solutions with neural networks (NN) based on an approximate dynamic programming (ADP) framework for new classes of engineering and non-engineering problems and associated difficulties and challenges are investigated in this dissertation. In the enclosed eight papers, the ADP framework is utilized for solving fixed-final-time problems (also called terminal control problems) and problems with switching nature. An ADP based algorithm is proposed in Paper 1 for solving fixed-final-time problems with soft terminal constraint, in which, a single neural network with a single set of weights is utilized. Paper 2 investigates fixed-final-time problems with hard terminal constraints. The optimality analysis of …

Numerical Modeling Of Heat Transfer And Fluid Flow In Laser Metal Deposition By Powder Injection, Zhiqiang Fan

Doctoral Dissertations

"Laser metal deposition is an additive manufacturing technique which allows quick fabrication of fully-dense metallic components directly from Computer Aided Design (CAD) solid models. A self-consistent three-dimensional model was developed for the laser metal deposition process by powder injection, which simulates heat transfer, phase changes, and fluid flow in the melt pool, The governing equations for solid, liquid and gas phases in the calculation domain have been formulated using the continuum model. The free surface in the melt pool has been tracked by the Volume of Fluid (VOF) method, while the VOF transport equation was solved using the Piecewise Linear …

Bio-Inspired Design, Fabrication And Testing Of Bipolar Plates For Pem Fuel Cells, Nannan Guo

Doctoral Dissertations

"The flow field of a bipolar plate distributes reactants for polymer electrolyte membrane (PEM) fuel cells and removes the produced water from the fuel cells. It greatly influences the performance of fuel cells, especially the concentration losses. Two approaches were developed to improve flow field designs in this dissertation. One is inspired by the biological circulatory structures and called bio-inspired designs, which have great potential to transport reactant efficiently and hence improve fuel cell performance. Another way is using a network-based optimization model to optimize the conventional flow field configurations, i.e., pin-type, parallel and serpentine designs, to improve flow distributions …