Engineering Commons^™

Synthesis And Characterization Of Multi-Component Enrichment Polymer Layers For Chemical Sensor Applications, James Giammarco

All Dissertations

This dissertation presents the building and study of a "universal" enrichment polymer layer system (EPLS). Thin polymer films have been utilized as enrichment layers for evanescent waveguide chemical sensors. The chemical nature of the polymer provides affinity which promotes the analyte to be absorbed. Having one highly sensitive polymer layer is suitable for a single target volatile organic compound (VOC). Here, the development of multi-layered and multi-component thin polymer films has been done to allow for more diverse affinity. Several parameters were identified to make the EPLSs suitable as enrichment layers for chemical sensor devices. The evanescent sensor devices used …

Pyrene Oligomers: Their Isolation, Molecular Characterization, And Phase Behavior, David Esguerra Taborda

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Carbonaceous pitches can serve as attractive precursors for advanced carbon materials such as high thermal conductivity fibers or carbon-carbon composites. Yet the effects of composition and molecular structure on the bulk properties (e.g., mesophase content and melting point) of these precursors remain only partly known, mainly because of the difficulties associated with the isolation, identification, and quantification of the large (i.e., molecular weight (mol wt) > 350-400 Da) polycyclic aromatic hydrocarbon (PAH) oligomers comprising these pitches. In this study, oligomeric fractions were isolated via supercritical extraction (SCE) from two representative pitches: a petroleum pitch (M-50) produced by the thermal polymerization of …

Synthesis And Characterization Of Polymer Layers For Control Of Fluid Transport, Fehime Vatansever

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The level of wetting of fiber surface with liquids is an important characteristic of fibrous materials. It is related to fiber surface energy and the structure of the material. Surface energy can be changed by surface modification via the grafting methodologies that have been reported for introducing new and stable functionality to fibrous substrates without changing bulk properties.

Present work is dedicated to synthesis and characterization of macromolecular layers grafted to fiber surface in order to achieve directional liquid transport for the modified fabric. Modification technique used here is based on formation of stable polymer layer on fabric surface using …

Predictive Maturity Of Inexact And Uncertain Strongly Coupled Numerical Models, Ismail Farajpour

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The Computer simulations are commonly used to predict the response of complex systems in many branches of engineering and science. These computer simulations involve the theoretical foundation, numerical modeling and supporting experimental data, all of which contain their associated errors. Furthermore, real-world problems are generally complex in nature, in which each phenomenon is described by the respective constituent models representing different physics and/or scales. The interactions between such constituents are typically complex in nature, such that the outputs of a particular constituent may be the inputs for one or more constituents. Thus, the natural question then arises concerning the validity …

Study On Electromagnetic Scattering Of Cylinders Buried In A Half Space With Random Rough Surfaces Of Finite/Infinite Length, Yueyang Dai

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Analysis of electromagnetic scattering of buried objects is a subject of great interest due to its practical importance in both military and civil applications, such as subsurface investigation and target detection. In reality, the earth is of layered structure of random rough interfaces, which leads to a greatly increased complexity of the analysis. However, it is necessary to incorporate the nature of random rough surface and the layered structure because they both have substantial impact on the scattered signature and hence affect the study of inverse scattering and detection of buried objects. In this dissertation, a Monte-Carlo multidomain pseudospectral time …

Biological Scaffolds For Peripheral Vascular Surgery, George Fercana

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The gold standards for small diameter peripheral vascular graft replacement are autologous arteries or veins; however, one-third of patients lack such vessels due to previous vessel harvesting or advanced vascular disease. A promising approach for patients in this category is tissue engineering with off-the-shelf biological vascular grafts. Three small diameter acellular scaffolds were developed and evaluated as vascular grafts. Porcine renal arteries (2-3 mm diameter, 20 mm length) were decellularized by immersion and stabilized with penta-galloyl glucose (PGG) with and without subsequent heparinization via carbodiimide chemistry. Bovine mammary (4-6 mm ID, 250 mm length) and femoral arteries (6-8 mm ID, …

Engineering Beta-Cell Spheroids For Type 1 Diabetes Treatment, Xiaoyan Liu

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Diabetes mellitus, the third most common disease in the world, is a chronic metabolic disorder caused by a failure of insulin production and/or an inability to respond to insulin. Specifically, type 1 diabetes is a disorder characterized by targeted autoimmune-directed destruction of a patient's beta-cell population within the pancreatic islets of Langerhans. The current primary treatment for type 1 diabetes is daily multiple insulin injections. However, this treatment cannot provide sustained physiological release, and the insulin amount is not finely tuned to glycemia. Pancreatic transplants or islet transplants would be the preferred treatment method but the lack of donor tissue …

Effect Of Graphitic Carbon Nanomodifiers On The Electromagnetic Shielding Effectiveness Of Linear Low Density Polyethylene Nanocomposites, Byron Villacorta Hernandez

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Conductive polymer composites have become alternative materials for providing electromagnetic and electrostatic shielding where metals are not suitable. In this study, the effect of crystallinity, morphology, concentration and orientation of carbon nanomodifiers on shielding provided by their polyethylene-based composites has been investigated relative to their transport properties.

First, the electrical properties and EM SE of composites consisting of heat-treated carbon nanofibers (Pyrograf^® -III PR-19 CNF) in a linear low density polyethylene (LLDPE) matrix were assessed. Heat treatment (HT) of CNF at 2500°C significantly improved their graphitic crystallinity and intrinsic transport properties, thereby increasing the EM SE of the nanocomposites. …

Large Scale 3d Mapping Of Indoor Environments Using A Handheld Rgbd Camera, Brian Peasley

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The goal of this research is to investigate the problem of reconstructing a 3D representation of an environment, of arbitrary size, using a handheld color and depth (RGBD) sensor. The focus of this dissertation is to examine four of the underlying subproblems to this system: camera tracking, loop closure, data storage, and integration. First, a system for 3D reconstruction of large indoor planar environments with data captured from an RGBD sensor mounted on a mobile robotic platform is presented. An algorithm for constructing nearly drift-free 3D occupancy grids of large indoor environments in an online manner is also presented. This …

Understanding The Role Of Requirements In Engineering Design By Novices, Shraddha Joshi

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Requirements play a critical role in the design process. The broader impact of this research is to develop a systematic understanding of the current use of requirements with an ultimate goal to develop guidelines and recommendations for more effective use of requirements throughout the design process. Thus, this research begins to answer the question about what is the role of requirements in design process and, specifically, its role in idea generation? The answer to this question is explored in three phases. The first phase is to understand how requirements are currently taught to students. To that end, two surveys were …

Seismic Site Coefficient Model And Improved Design Response Spectra Based On Conditions In South Carolina, Shimelies Aboye

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A new seismic site coefficient model is developed from the results of over 60,000 total stress, one-dimensional equivalent ground response simulations assuming conditions in South Carolina. Computed site coefficients ( F ) are plotted versus average shear wave velocity in the top 30 m (V_S30 ) and grouped by location, spectral acceleration (S_outcrop ) and spectral period. Locations considered in the Coastal Plain include Aiken, Charleston, Columbia, Florence, Lake Marion, Myrtle Beach, and the South Carolina side of Savannah. Locations considered in the Piedmont include Columbia, Greenville, Greenwood, and Rock Hill. In all the plots of …

Uv-Assisted Stabilization Of Polyacrylonitrile-Based Carbon Fiber Precursors, Marlon Salvador Morales Sandoval

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Due to their high strength and stiffness coupled with low density, carbon fibers are the preferred reinforcing fibers used in high-performance polymer matrix composites. Consequently, the demand for carbon fibers is expected to grow from 40,000 metric tons to about 150,000 metric tons over the next decade. A large fraction of the increase is anticipated in the industrial sector that is cost-sensitive. Therefore, there is a need for the development of novel processes and precursors to reduce the carbon fiber production cost and expand the use of carbon fibers. This research focuses on the development of an alternative, rapid stabilization …

Primary Resonance Behavior Of Expanded Polymer Cushion Material Under Low-Intensity Harmonic Excitations, Gregory Batt

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The demand to lower costs and reduce the amount of packaging materials utilized in a packaged-product system has placed increased importance on the development of tools to model the behavior of packaging systems. In this dissertation, the free and forced vibration response of a nonlinear, distributed-parameter model of a viscoelastic rod with an applied tip-mass is used to investigate the response of expanded polymer cushion materials to low-intensity harmonic excitations. The rod and tip-mass represent an idealized packaged product system. A nonlinear model is developed from constitutive relations. A classical Maxwell-Weichert model, represented via a Prony series, is used to …

Knowledge Base Representation With Axiomatic Design Rules For Concept Level Up Implement In Ontological Framework, Zhuochen Shi

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Axiomatic Design has been applied and developed as a tool, offering a scientific basis for design and improving design activities. Axiomatic Design has been used in various fields such as software system design, structure design, and product design. However, several challenges and limitations exist in Axiomatic Design including: the inconsistency in identifying design parameters, existence of coupled design, and multiple groups of functional requirements and design parameters. Aimed at using Axiomatic Design to generate conceptual solutions in engineering design while overcoming its limitations, a formal ontology is developed. The ontology defines functional requirements, design parameters, concepts, components and variables and …

Speech Enhancement By Exploiting The Baseband Phase Structure Of Voiced Speech For Effective Non-Stationary Noise Estimation, Sanjay Patil

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Speech enhancement is one of the most important and challenging issues in the speech communication and signal processing field. It aims to minimize the effect of additive noise on the quality and intelligibility of the speech signal. Speech quality is the measure of noise remaining after the processing on the speech signal and of how pleasant the resulting speech sounds, while intelligibility refers to the accuracy of understanding speech. Speech enhancement algorithms are designed to remove the additive noise with minimum speech distortion.The task of speech enhancement is challenging due to lack of knowledge about the corrupting noise. Hence, the …

Development And Testing Of An Impact Plate Yield Monitor For Peanuts, Jacob Fravel

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Advancements in precision agriculture technologies such as yield monitors have allowed for improved management capabilities and reduced input costs for a number of crops. Most commercialized developments in yield monitoring systems and technologies to date have been directed for use with the major grain crops such as corn, soybeans and cereal grains. This research focuses on development and testing of an impact plate yield monitor system for the peanut harvest. Using a four row peanut combine in virginia type peanuts, 4.8 ha (12 ac) of simultaneous yield data were recorded from an Ag Leader® grain (impact plate) yield monitor and …

An Exploratory Study On The Effects Of Goal Alignment, Interventions, And Motivational Factors On Innovative Engineering Design Projects, Blake Linnerud

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Innovation has become an important facet of engineering design, both in industry and the academy. Many senior-level engineering design courses encourage students to develop innovative solutions to open design projects from industry sponsors. Like industry, these academic problems are tackled by teams of students. Student teams that function at the highest level are more likely to reach the innovative solutions for which they are searching. The research presented in this work focuses on two main areas: (1) understanding what motivates engineers when working on innovative design projects and (2) determining the effects of goal alignment interventions on design teams working …

The Effects Of Different Size Gold Nanoparticles On Mechanical Properties Of Vascular Smooth Muscle Cells Under Mechanical Stretching, Tri Kieu

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The field of nanotechnology research has seen a large growth in the past few decades due to the great potential of novel nano-size material for useful applications such as drug delivery and medical imaging. Also, they are a promising platform for the detection of terrible diseases such as cancer and atherosclerosis. Although these materials hold great promise, there is very limited understanding about the biological effects of these nanoparticles on normal healthy cells, such as vascular smooth muscle cells (VSMCs). The VSMCs are unique cells due to the two distinct phenotype characteristics it can express: a contractile and a synthetic …

Knowledge Extraction From Work Instructions Through Text Processing And Analysis, Abhiram Koneru

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The objective of this thesis is to design, develop and implement an automated approach to support processing of historical assembly data to extract useful knowledge about assembly instructions and time studies to facilitate the development of decision support systems, for a large automotive original equipment manufacturer (OEM). At a conceptual level, this research establishes a framework for sustainable and scalable approach to extract knowledge from big data using techniques from Natural Language Processing (NLP) and Machine Learning (ML). Process sheets are text documents that contain detailed instructions to assemble a portion of the vehicle, specification of parts and tools to …

Optimal Retrofit Strategy Design For Highway Bridges Under Seismic Hazards: A Case Study Of Charleston, Sc, Shawn Parmelee

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A significant number of US highway bridges are inadequate for seismic loads and could be seriously damaged or collapse during a relatively small earthquake. On the most recent infrastructure report card from the American Society of Civil Engineers (ASCE), one-third of the bridges in the United States are deemed to be structurally deficient. To improve this situation, at-risk bridges must be identified, evaluated, and effective retrofitting programs implemented to reduce their seismic vulnerabilities. In practice, the Federal Highway Administration uses the expected damage method and indices method to assess the condition of bridges. These methods compare the severity of expected …

Effects Of Iteration On Concept Development, Shivraj Ranganathan

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Iteration in the conceptual design stage is defined as repetition of design tasks to incorporate new information. A more concise definition of iteration relevant to this research would be the progression of design through different abstraction levels or design stages, defining and refining design solutions while progressing from initial concepts to a more detailed design. Although it is believed that iteration has a positive effect on the quality of ideas in the design process, this experimental study presents an opportunity to determine the effects of iteration on quality of concepts and the factors that lead to increased quality of concepts. …

Sociallink: A Social Network Based Trust System For P2p File Sharing Systems, Fang Qi

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In peer-to-peer (P2P) file sharing systems, many autonomous peers without preexisting trust relationships share files with each other. Due to their open environment and distributed structure, these systems are vulnerable to the significant impact from selfish and misbehaving nodes. Free-riding, whitewash, collusion and Sybil attacks are common and serious threats, which severely harm non-malicious users and degrade the system performance. Many trust systems were proposed for P2P file sharing systems to encourage cooperative behaviors and punish non-cooperative behaviors. However, querying reputation values usually generates latency and overhead for every user. To address this problem, a social network based trust system …

Cost And Embodied Energy Optimization Of Rectangular Reinforced Concrete Beams, Alexander Kosloski

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Concrete has a large environmental footprint so it is desirable to find ways to efficiently design structural members. Engineers can exercise their abilities early on in the design phase of construction projects to reduce the environmental footprint by minimizing the amount of materials required. One way to achieve these results is to optimize the design of structural concrete. In this study, simple-span rectangular reinforced concrete (RC) beams with a range of different bending moments were analyzed. The primary goal was to combine life cycle analysis (LCA), numerical optimization, and reinforced concrete mechanics to create a framework for designing efficient RC …

Twelve Mile Creek Channel Morphology, Substrate Composition, And The Macroinvertebrate Community Changes Resulting From Multiple Dam Removals, Patricia Whitener

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Dam removal is gaining global attention as a potential restoration tool for impacted rivers. As the practice of dam removal increases, physical, chemical and biological monitoring before and after dam removal is essential to our understanding of the ecological consequences of this type of disturbance. Under the Lake Hartwell Restoration and Compensation Determination Plan, two dams (>9 m height) were removed from the Twelve Mile Creek watershed (170 km2) in Pickens county, South Carolina. To assess the short term impacts of dam removal on the Twelve Mile Creek ecosystem we conducted biomonitoring of macroinvertebrate species and surveys of river …

Scratch Damage Evolution On Metals In Total Joint Replacements, Caleb Eljach

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The goal of total joint replacement (TJR) is to replace nonfunctioning joint components and relieve pain, improve quality of life, and to improve joint function. Although TJR is a successful procedure, more than 54,000 knee revisions occur each year due to factors, such as wear, loosening, infection, fracture, instability, and patient related factors (Ranawat, 2010). TJRs consist of components typically composed of polyethylene and a metallic counterface (Navarro, 2008). The sliding contact that occurs between the metal and polyethylene components has been well studied and is shown to produce both surface damage and wear of the implant components (Barbour, 1997; …

Dissolved Carbon Dioxide For Scale Removal In Reverse Osmosis, Erin Partlan

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Membrane fouling is a major operational issue in reverse osmosis (RO) desalination plants. In particular, plants treating brackish groundwater can encounter troublesome inorganic scales, including carbonates, sulfates, and silicates. A novel cleaning method is proposed to remove inorganic scales from fouled RO membranes usinag dissolved CO ₂ . As CO₂ molecules encounter membrane foulants, the surfaces serve as nucleation sites for small bubbles to form and shear off foulants. Dissolved CO₂ solutions were prepared by bubbling CO₂ gas into water held in a pressure vessel. Gas dissolution was confirmed by enhanced exit velocities for water containing CO …

Development And Verification Of A Test System To Quantify Strain Of An Optical Displacement Indicator And The Design Of A Strain Indicating Prototype, Josh Lake

All Theses

The organic-rich Middle Devonian Marcellus Shale of the Appalachian basin is a rapidly developing natural gas play. Stratigraphic boundaries of the Marcellus Shale in Westmoreland County, Pennsylvania were identified using geophysical logs from 10 vertical gas-producing wells in a 23 sq. km area. Gamma-ray, bulk density, and resistivity well logs were examined to assess hydrocarbon potential. Values of porosity, total organic carbon (TOC), and water saturation (SW) were derived and mapped by incorporating well-log data into Marcellus-specific formulas. Gamma-ray, penetration (minutes per foot drilled), and mud-logging gas (total gas) from 12 horizontal wells from within the study area were also …

Design Of An Optical Position Sensor For Microfiber Actuators, Luxi Cheng

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This thesis introduces a new type of sensor that detects the position information of a paramagnetic microfiber and transforms it to computational electrical signal. The original purpose of the sensor is to solve the problem of feedback signal detection of the microfiber control system, which is the problem of detecting the position information for the microfiber. The microfiber will be presented as the experimental object of this sensor to test its capability. A novel optical based approach is used to transfer the position signal to a computer scrutable signal for further analysis.

The purpose of the sensor design comes from …

Adaptive Transmission For Ofdm, Michael Juang

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To respond to dynamic channel conditions caused by fading, shadowing, and other time-varying disturbances, orthogonal frequency division multiplexing (OFDM) packet radio systems should adapt transmission parameters on a packet-by-packet basis to maintain or improve performance over the channel. For this to be possible, there are three key ideas that must be addressed: first, how to determine the subchannel conditions; second, which transmission parameters should be adapted; and third, how to adapt those parameters intelligently. In this thesis, we propose a procedure for determining relative subchannel quality without using any traditional channel measurements. Instead, statistics derived solely from subcarrier error counts …

Phonon Transport Analysis Of Semiconductor Nanocomposites Using Monte Carlo Simulations, Mayank Malladi

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Nanocomposites are composite materials which incorporate nanosized particles, platelets or fibers. The addition of nanosized phases into the bulk matrix can lead to significantly different material properties compared to their macrocomposite counterparts. For nanocomposites, thermal conductivity is one of the most important physical properties. Manipulation and control of thermal conductivity in nanocomposites have impacted a variety of applications. In particular, it has been shown that the phonon thermal conductivity can be reduced significantly in nanocomposites due to the increase in phonon interface scattering while the electrical conductivity can be maintained. This extraordinary property of nanocomposites has been used to enhance …