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Rational Design Of Hydrogen-Free Catalytic Active Sites, Andrei Ioan Loas

Dissertations

Materials that are organic-based and exhibit oxidative catalytic activity, including free-radical pathways, while being refractory to the activated oxygen species are not known. The synthesis of several classes of such materials, their electronic and structural characterizations as well as catalytic properties are reported. Their rational molecular design and biologically inspired reactivity are based on enzymatic active sites, which are reengineered into robust metal-organic fluoroalkylated scaffolds that, for the first time, exhibit structural asymmetry and tunable π-π interactions both in solution and solid state. In these complexes, labile C-H bonds are replaced with chemically and thermally resistant C-F bonds to create …