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Full-Text Articles in Engineering

Studies On The Preparation And Luminescence Properties Of Cadmium Selenide Quantum Dots, Their Immobilization, And Applications., Travis Justin Heath Dec 2010

Studies On The Preparation And Luminescence Properties Of Cadmium Selenide Quantum Dots, Their Immobilization, And Applications., Travis Justin Heath

Electronic Theses and Dissertations

Quantum dots are semiconductive particles whose properties are highly influenced by the presence of at least one electron. Cadmium selenide quantum dots were synthesized via colloidal synthesis. Contrary to previous preparations, more focus was placed on the temperature rather than the duration of time at which they form. A series of colored solutions were obtained because the excited quantum dots of various sizes emitted specific wavelengths of light. The emission spectra showed that the temperature-dependent quantum dots were successfully synthesized. The quantum dots were also immobilized on various surfaces, and the luminescence properties were examined. The quantum dots that were …


Providing A Theoretical Basis For Nanotoxicity Risk Analysis Departing From Traditional Physiologically-Based Pharmacokinetic (Pbpk) Modeling, Dirk P. Yamamoto Sep 2010

Providing A Theoretical Basis For Nanotoxicity Risk Analysis Departing From Traditional Physiologically-Based Pharmacokinetic (Pbpk) Modeling, Dirk P. Yamamoto

Theses and Dissertations

The same novel properties of engineered nanoparticles that make them attractive may also present unique exposure risks. But, the traditional physiologically-based pharmacokinetic (PBPK) modeling assumption of instantaneous equilibration likely does not apply to nanoparticles. This simulation-based research begins with development of a model that includes diffusion, active transport, and carrier mediated transport. An eigenvalue analysis methodology was developed to examine model behavior to focus future research. Simulations using the physicochemical properties of size, shape, surface coating, and surface charge were performed and an equation was determined which estimates area under the curve for arterial blood concentration, which is a surrogate …


Fabrication Of Fluorescent Nanoparticle-Polymer Composites For Photoactive-Based Materials, Brett Ellerbrock Aug 2010

Fabrication Of Fluorescent Nanoparticle-Polymer Composites For Photoactive-Based Materials, Brett Ellerbrock

All Theses

Nanocomposites of nanoparticles dispersed throughout a polymer matrix have been studied to great length to improve the overall polymer properties. These enhancements are observed in the thermal, physical, and/or optical characteristics. Being able to harness nanoparticles in such a way may help improve fiber technology into the 21st century.
This work was geared toward synthesizing rare earth doped lanthanum fluoride (LaF3) nanoparticles because good separation in the absorption and emission bands of the material and it fluoresces in the visible to near-infrared range. Terbium ions were added to a LaF3 crystal because of their distinct visible green …


Synthesis, Structure, And Catalytic Properties Of Size-Selected Platinum Nanoparticles, Simon Armando Covone Jan 2010

Synthesis, Structure, And Catalytic Properties Of Size-Selected Platinum Nanoparticles, Simon Armando Covone

Electronic Theses and Dissertations

The use of heterogeneous catalysis is well established in chemical synthesis, energy, and environmental engineering applications. Supported Pt nanoparticles have been widely reported to act as catalysts in a vast number of chemical reactions. In this report, the performance of Pt/ZrO2 nanocatalyst for the decomposition of methanol, ethanol, 2-propanol, and 2-butanol is investigated. The potential of each alcohol for the production of H2 and other relevant products in the presence of a catalyst is studied. All the alcohols studied show some decomposition activity below 200°C which increased with increasing temperature. In all cases, high selectivity towards H2 formation is observed. …


Plasmon Enhanced Near-Field Interactions In Surface Coupled Nanoparticle Arrays For Integrated Nanophotonic Devices, Amitabh Ghoshal Jan 2010

Plasmon Enhanced Near-Field Interactions In Surface Coupled Nanoparticle Arrays For Integrated Nanophotonic Devices, Amitabh Ghoshal

Electronic Theses and Dissertations

The current thrust towards developing silicon compatible integrated nanophotonic devices is driven by need to overcome critical challenges in electronic circuit technology related to information bandwidth and thermal management. Surface plasmon nanophotonics represents a hybrid technology at the interface of optics and electronics that could address several of the existing challenges. Surface plasmons are electronic charge density waves that can occur at a metal-dielectric interface at optical and infrared frequencies. Numerous plasmon based integrated optical devices such as waveguides, splitters, resonators and multimode interference devices have been developed, however no standard integrated device for coupling light into nanoscale optical circuits …


Antisense Silver Nanoparticles For Photo-Activated Gene Silencing, Paige Kathleen Brown Jan 2010

Antisense Silver Nanoparticles For Photo-Activated Gene Silencing, Paige Kathleen Brown

LSU Master's Theses

The unique properties of noble metal nanoparticles, which include tunable electronic and photonic characteristics, contribute to their potential as novel delivery vectors with enhanced drug stability, cell uptake, and photo-activated functionalities. Silver, as one of best surface-enhancing substrates available for bulk nanostructure synthesis, is a prime choice for investigations of metal nanohybrids as antisense therapy vehicles with special surface plasmon resonance (SPR) enabled functional attributes. The singular photonic properties of silver nanoparticles (SNPs) may contribute to ease of delivery confirmation and in situ photo-activation of protected cargo packed on particle surfaces. Here we show the synthesis and characterization of 40-80nm …


Itraconazole Loaded Poly (Lactic-Co-Glycolic) Acid Nanoparticles For Improved Antifungal Activity, Nipur Rajan Patel Jan 2010

Itraconazole Loaded Poly (Lactic-Co-Glycolic) Acid Nanoparticles For Improved Antifungal Activity, Nipur Rajan Patel

LSU Master's Theses

PLGA (polylactic-co-glycolic acid) nanoparticles containing the hydrophobic antifungal Itraconazole (ITZ) were developed to address the need for more efficient means of treating fungal infections. PLGA-ITZ nanoparticles were synthesized using an oil-in-water emulsion evaporation method. The nanoparticles morphology (TEM), size and size distribution, zeta potential (DLS), encapsulation efficiency (UV-VIS), release profile, and antifungal activity were characterized. The blank NPs and loaded PLGA-ITZ NPs were spherical with diameters of 201±5 nm, 232±1 nm and 223±36 nm at 0%, 12.5% and 25% loadings, respectively. All synthesized particles measured a negative zeta potential ranging from -28 to -33 mV. The maximum encapsulation efficiency of …