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Solvent Resistant Microporous/Nanoporous Polymeric Hollow Fiber And Flat Film Membranes And Their Applications, Praveen B. Kosaraju Jan 2007

Solvent Resistant Microporous/Nanoporous Polymeric Hollow Fiber And Flat Film Membranes And Their Applications, Praveen B. Kosaraju

Dissertations

The separation and purification of organic-solvent-based process streams may be carried out by membrane processes such as nanofiltration/ultrafiltration/microfiltration and membrane solvent extraction. Lack of solvent stability and chemical stability of most commercially available membranes is limiting the utilization of the above mentioned membrane technologies. This dissertation was primarily focused on developing solvent resistant hollow fiber and flat film membranes for separation and purification of organic-solvent-based process streams.

Available porous polymeric supports (Polypropylene (PP), Polyethersulfone (PES) and Nylon) suitable for the required solvent-stable applications were chosen first and then the supports were modified to satisfy the requirements for the applications. Membrane …


An Investigation Of Size Exclusion And Diffusion Controlled Membrane Fouling, Colin Michael Hobbs Jan 2007

An Investigation Of Size Exclusion And Diffusion Controlled Membrane Fouling, Colin Michael Hobbs

Electronic Theses and Dissertations

The reduction of membrane productivity (i.e. membrane fouling) during operation occurs in virtually all membrane applications. Membrane fouling originates from the method by which membranes operate: contaminants are rejected by the membrane and retained on the feed side of the membrane while treated water passes through the membrane. The accumulation of these contaminants on the feed side of the membrane results in increased operating pressures, increased backwashing frequencies, increased chemical cleaning frequencies, and increased membrane replacement frequencies. The most significant practical implication of membrane fouling is increased operating and maintenance costs. As such, membrane fouling must be properly managed to …