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Theses/Dissertations

2007

Missouri University of Science and Technology

<p>Catalysts -- Analysis<br />Fuel cells -- Design<br />Methanol as fuel<br />Nanotechnology</p>

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Full-Text Articles in Engineering

Synthesis And Characterization Of Platinum-Based Multi-Component Catalysts For Direct Methanol Fuel Cells, Li Ren Jan 2007

Synthesis And Characterization Of Platinum-Based Multi-Component Catalysts For Direct Methanol Fuel Cells, Li Ren

Masters Theses

"In the thesis work, Pt-based binary, ternary, quaternary alloy anode catalysts supported on sonochemically treated multi-walled carbon nanotubes (CNTs) were synthesized with ethylene glycol reduction of corresponding metal chloride salts. Inductively coupled plasma-mass spectroscopy (ICP-MS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) were used for catalyst characterization. Cyclic voltammetry for methanol oxidation and CO stripping were used to evaluate the performance of the catalysts.

PtRu nanoparticles supported on CNTs (PtRu/CNT) were prepared under a series of pHs. It was found that the PtRu particle size, composition, and catalytic activity were all sensitive to the deposition …