Engineering Commons^™

The Synthesis And Characterization Of Mesoporous Uranium Oxide Catalysts For Oxidative Destructions Of Volatile Organic Compounds And Clean Air Protection, Cyrus Khezr Riahi-Nezhad

Masters Theses

The overall goal of this research was to investigate a new class of mesoporous uranium oxide catalyst used to destroy a range of volatile organic compounds (VOCs), including aromatics and chlorinated organic compounds under conditions which are applicable for U.S. Department of Energy (DOE) facilities and U.S. industries.

Uranium oxides are known to have high efficiency and long-term stability when used to destroy volatile organic compounds (VOCs) when compared with some of the commercial catalysts, such as precious metals, TiO₂, and Co₃O₄ catalysts. Two key factors limiting catalytic activities of uranium oxides prepared by conventional …

Modeling Contaminant Transport And Fate And Subsequent Impacts On Ecosystems, Ming Fan

Dissertations

Assessing risks associated with the release of metals into the environment and managing remedial activities requires simulation tools that depict speciation and risk with accurate mechanistic models and well-defined transport parameters. Such tools need to address the following processes: (1) aqueous speciation, (2) distribution mechanisms, (3) transport, and (4) ecological risk. The primary objective of this research is to develop a simulation tool that accounts for these processes. Speciation in the aqueous phase can be assessed with geochemical equilibrium models, such as MINEQL+. Furthermore, metal distribution can be addressed mechanistically. Studies with Pb sorption to amorphous aluminum (HAG), iron (HFO), …

Air Toxic Emissions Distribution And Performance Analysis Of The Cmaq Air Toxic Model - A Case Study Of Houston Area, Texas, Ramesh Ramachandran Gopal

Masters Theses

Air quality models have been used in the past to predict the ambient air toxic concentration but CMAQ air toxics model, used in this thesis, is the first air quality model, which accounts the toxic chemical reactions in the ambient atmosphere. The main objective of this thesis was to analyze the distribution of air toxics emission in the Houston region, Texas using an emission processing tool and to determine the performance of the advanced air toxics model (CMAQ) used. Each year large amount of air toxics are emitted in the state of Texas, particularly in the Houston region. A study …

Performance Of Self-Compacting Concrete, Mohamed Samir Rushdy

Archived Theses and Dissertations

Concrete compaction is one of the indispensable fundamentals of concrete manufacturing. However, thorough compaction cannot always be insured. This can be wholly or partially encountered in congested sections, out-of reach deep foundations and narrow or irregular precast components. On the other hand, typical vibrators were considered as contributor to health hazards to workers. Self-compacting concrete (SCC) is an emerging concrete where the cohesive yet flowable consistency of the concrete itself secures adequate placement with high level of homogeneity and little or no segregation. Such concrete is primarily achieved by incorporating admixtures that is referred to as viscosity modifying (VM) admixtures …

Making The Business Case For Sustainable Design In The Department Of Defense, David M. Warnke

Theses and Dissertations

Buildings are one of the largest consumers of natural resources, a major source of ecological pollution, and occasionally toxic to human health. Sustainable design is the common term associated with buildings which, during their construction, use, and eventual disposal, seek to minimize their negative impact on the environment and human health. The U.S. Green Building Council's Leadership in Energy and Environmental Design (LEED) rating system helps to assess a building's sustainability level. In the Federal Government's push to set the example for the rest of the nation, nearly every Federal Agency has chosen to adopt the LEED assessment tool. Each …

Modeling A Field Application Of In Situ Bioremediation Of Perchlorate-Contaminated Groundwater Using Horizontal Flow Treatment Wells (Hftws), Peter G. Chosa

Theses and Dissertations

Perchlorate contaminated groundwater is rapidly becoming a significant environmental remediation issue for the Department of Defense. In this study, an existing numerical model that simulates the operation of a Horizontal Flow Treatment Well (HFTW) system to effect the in situ biodegradation of perchlorate through the addition of an electron donor is modified to include a submodel that describes bioclogging. Bioclogging restricts flow out of the HFTW due to the accumulation of biomass directly adjacent to the well. The modified model is then applied to an existing perchlorate contaminated site that will be used for an evaluation of the HFTW technology. …

Characterization Of Microbial Processes That Degrade Chlorinated Solvents In A Constructed Wetland Using Organic Acid And Inorganic Anion Concentration Profiles, Chad B. Bondurant

Theses and Dissertations

Chlorinated solvents have been used in industrial cleaning and degreasing processes in the United States since the early 1900s, and their induction into the environment increased significantly with the growth of industrial processes over the past century. PCE, TCE and their daughter products have been associated with a number of human health concerns and are currently the most common contaminants found in groundwater in the United States. Wetlands possess characteristics necessary for the complete degradation of chlorinated ethenes by microorganisms via anaerobic and aerobic regions that foster the necessary oxidation-reduction conditions. Organic acid and inorganic anion concentrations were evaluated in …

Application Of Horizontal Flow Treatment Wells For In Situ Treatment Of Mtbe-Contaminated Groundwater, Preston F. Rufe

Theses and Dissertations

This study utilized a three-dimensional numerical model to evaluate the potential application of HFTWs to manage MTBE-contaminated groundwater. HFTWs consist of two dual-screened treatment wells. One well operates in an upflow mode, with MTBE-contaminated water extracted from an aquifer through a screen in the deep portion of an aquifer and injected into the aquifer through a shallow well screen, while the adjacent well operates in a downflow mode, extracting water from the shallow zone of the aquifer and injecting it into the deep zone. As the MTBE-contaminated water flows through the wells, an electron acceptor and/or another electron donor is …

Recycled Concrete Properties And Feasibility, Mourad Nabil Shenouda

Archived Theses and Dissertations

As conventional good quality aggregates are becoming scarce in some zones in Egypt and many areas worldwide, and as environmental concerns are raised on dumping old and fresh concrete in landfills, recycled concrete has been receiving increased interest worldwide for its potential environmental, economic and technical merits. In fact, many countries have adopted such concrete in their codes and the majority of their old concrete is being recycled. An attempt is being made to trigger factors and means that enhance the economic feasibility of recycled concrete. The overall goal of this work is to pinpoint strength and deficiencies in this …

The Use Of A Water Quality Model To Evaluate The Impacts Of Combined Sewer Overflows On The Lower Hudson River, Wen-Pin Shu

Dissertations

CSO discharges have long been recognized as a significant source of water pollution. While many sources of water pollution have been controlled over the past 20 years, CSOs continue to be a main environmental concern in several areas, especially in old cities. In the past, most CSO research focused on the CSO control processes, including floatables and suspended solids removal. Few studies have been conducted in the area of the impacts of CSO discharge on the receiving water quality. To achieve this purpose, a powerful water-modeling tool, WASP 6.1, is utilized in this study. The Lower Hudson River is selected …

Dewatering Of Biosolids By Sodium Ferrate, Andrea Rios

Electronic Theses and Dissertations

This study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge after conditioning were used. For centrifugation the volume reduction and the turbidity of the supernatant after centrifugation were evaluated. For filtration, the Capillary Suction Time test was used. The optimum …

Hydrogen Sulfide Flux Measurements And Dispersion Modeling From Constr, Sangho Eun

Electronic Theses and Dissertations

Odor problems are a common complaint from residents living near landfills. Many compounds can cause malodorous conditions. However, hydrogen sulfide (h2s) has been identified as a principal odorous component from construction and demolition (c&d)debris landfills. Although several studies have reported the ambient concentrations of h2s near c&d landfills, few studies have quantified emission rates of h2s. The most widely used and proven technique for measuring gas emission rates from landfills is the flux chamber method. Typically the flux chamber is a cylindrical enclosure device with a spherical top which limits the gas emission area. Pure zero grade air is introduced …

Degradation Of Halogenated Aliphatic Compounds In Sequential Anaerobic, Scott Hoxworth

Electronic Theses and Dissertations

The objective of this study was to utilize an alternating anaerobic/aerobic sequence to biologically transform perchloroethylene to non-hazardous end products such as ethylene, CO2 and H2 using a single microbial consortia in a methanogenic and/or a homoacetogenic environment followed by a aerobic methanotrophic environment. Reductive dechlorination of PCE and TCE to cDCE and VC in an anaerobic environment is typically carried out by methanogens, sulfidogens, or homoacetogens but often (e.g. in-situ) leads to an accumulation of daughter compounds (cDCE, VC) which are more toxic than their parent compounds (PCE, TCE). Furthermore, PCE is resistant to degradation in aerobic environments while …

Predicting Air Quality Near Roadway Intersections Through The Applicat, Brian Kim

Electronic Theses and Dissertations

With substantial health and economic impacts attached to many highway-related projects, it has become imperative that the models used to assess air quality be as accurate as possible. The United States (US) Environmental Protection Agency (EPA) currently promulgates the use of CAL3QHC to model concentrations of carbon monoxide (CO) near roadway intersections. This model uses steady-state and macroscopic methods to model the physical phenomena (e.g., emission rates, atmospheric dispersion, etc.) occurring at intersections. These methods are not straightforward and unintuitive for the users. Therefore, this project investigated the possibility of developing a model that is theoretically more realistic and flexible …

Hydrologic Variations Within Created And Natural Wetlands In Southeastern Virginia, Aaron Dyer Despres

OES Theses and Dissertations

The hydrology of wetlands, particularly how wetland soils collect, store, and redistribute water strongly affects how wetland systems function. In created wetlands, construction processes and materials influence the hydrology and consequently, the potential for successful reestablishment of target vegetation communities. During 2002–2004, the Virginia Department of Transportation constructed large mitigation wetlands on two different Quaternary aged surfaces with very similar hydrogeomorphic conditions. The Sandy Bottom Nature Park site (SBNP) located in Hampton, VA and rests on the sandy loam Tabb Formation while the Charles City Wetland site (CCW) lies on the older and clay-rich Shirley Formation. This study documents and …

Evaluating Restored Oyster Reefs In Chesapeake Bay: How Habitat Structure Influences Ecological Function, Janet A. Nestlerode

Dissertations, Theses, and Masters Projects

A shortage of shell resources for restoring reefs of the Eastern oyster, Crassostrea virginica, has led to widespread use of substitute materials. The effectiveness of such alternative substrates as habitat for reef-associated fauna other than oysters is largely unresolved. I investigated the habitat value of oyster shell, surf clam (Spisula solidissima) shell, and pelletized coal ash reefs for benthic and nektonic communities. Oyster recruitment, survival, and growth were monitored on reefs of oyster and surf clam shell near the mouth of Chesapeake Bay and York River, USA. Oyster shell supported greater oyster growth and survival and offered the highest degree …