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Full-Text Articles in Engineering
Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham
Graduate Theses and Dissertations
NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …
Comparison Of The Resistance Of Belitic Calcium Sulfoaluminate Cement And Portland Cement To Sulfate Attack And Sulfuric Acid, Rilye Dillard
Comparison Of The Resistance Of Belitic Calcium Sulfoaluminate Cement And Portland Cement To Sulfate Attack And Sulfuric Acid, Rilye Dillard
Graduate Theses and Dissertations
Microbially induced corrosion (MIC) is a fairly common concrete deterioration mechanism with many negative effects. MIC is a complex chemical and biological process that occurs in sewage systems and is nearly impossible to replicate in a laboratory setting. For this study, sulfate and sulfuric acid attack on concrete were studied to mimic two stages of the MIC process. The ASTM C1012, Standard Test Method for Length Change of Hydraulic-Cement Mortars Exposed to a Sulfate Solution and a modified ASTM C1012 accelerated method were used to compare the sulfate resistance of belitic calcium sulfoaluminate (BCSA) cement, portland cement (PC), and PC-fly …