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Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek
Local Structure And Dynamic Studies Of Mixed Ch4-Co2 Gas Hydrates Via Computational Simulation And Neutron Scattering, Bernadette Rita Cladek
Doctoral Dissertations
Permeated throughout the ocean floor and arctic permafrost, natural gas hydrates contain an estimated 3000 trillion cubic meters, over three times that of traditional shale deposits, of CH4 that is accessible for extraction. Gas hydrates are a crystal structure in which water molecules form a cage network, the host, through hydrogen bonds while trapping a guest molecule such as CH4 in the cavities. These compounds form naturally where the appropriate low temperature and high pressure conditions occur. A promising and tested method of methane recovery is through exchange with CO2, which energetically takes place of the …
Structural And Kinetic Studies Of Structure I Gas Hydrates Via Low Temperature X-Ray Diffraction And High Resolution Neutron Diffraction, Susan Michelle Everett
Structural And Kinetic Studies Of Structure I Gas Hydrates Via Low Temperature X-Ray Diffraction And High Resolution Neutron Diffraction, Susan Michelle Everett
Doctoral Dissertations
Gas hydrates are materials of interest as sources for clean energy, carbon sequestration, greenhouse gas mitigation, and gas storage. This body of work presents two projects that each separately explore one aspect of the potential found in gas hydrates. Chapter 1 tackles the structural changes found to occur over the CO2 [carbon dioxide] - CH4 [methane] hydrate solid solution. The application here pertains to the sequestration of CO2 in natural gas hydrates found in permafrost regions and ocean floors. As CO2 is injected into the hydrate reservoir, CH4 is released and recovered for energy use. …