Engineering Commons^™

Friction And Wear Of Polytetrafluoroethylene/Graphene Oxide Composite Thin Films, Justin Kyle Carter

Graduate Theses and Dissertations

Polytetrafluoroethylene (PTFE) is a commonly used solid lubricant due to its low coefficient of friction and chemical inertness. As a polymer, PTFE suffers from high wear and low adhesion to substrates limiting its use as a thin film. Thin PTFE films are ideal candidates for solid lubrication in micro-machines and bearing applications. The main goal of this work is to enhance the durability of thin PTFE films through the addition of few layered graphene oxide (GO) as filler. In order to address adhesion issues, the addition of an adhesive layer of polydopamine (PDA) between stainless steel substrates and thin PTFE …

Crack Growth Behavior Under Creep-Fatigue Conditions Using Compact And Double Edge Notch Tension-Compression Specimens, Santosh B. Narasimha Chary

Graduate Theses and Dissertations

The American Society for Testing and Materials (ASTM) has recently developed a new standard for creep-fatigue crack growth testing, E 2760-10, that supports testing compact specimens, C(T), under load controlled conditions. C(T) specimens are commonly used for fatigue and creep-fatigue crack growth testing under constant-load-amplitude conditions. The use of these specimens is limited to positive load ratios. They are also limited in the amount of crack growth data that can be developed at high stress intensity values due to accumulation of plastic and/or creep strains leading to ratcheting in the specimen. Testing under displacement control can potentially address these shortcomings …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

An Experimental And Computational Evaluation Of The Importance Of Molecular Diffusion In Gas Gravity Currents, Jeremy Jac Herman

Graduate Theses and Dissertations

The accidental release of hazardous, denser-than-air gases during their transport or manufacture is a vital area of study for process safety researchers. This project examines the importance of molecular diffusion on the developing concentration field of a gas gravity current released into a calm environment. Questions which arose from the unexpectedly severe explosion in 2005 at Buncefield, England were of particular interest. The accidental overfilling of a large tank with gasoline on a completely calm morning led to a massive open air explosion. Forensic evidence showed that at the time of ignition, a vapor cloud, most of which now appears …

Tin Sensitization For Electroless Plating, Xingfei Wei

Graduate Theses and Dissertations

The tin sensitization process has been used in electroless plating since 1940s Brenner and Riddell developed the electroless plating for surface metallization method. It was found to be an interesting topic to study tin sensitization for chemically controlling metal deposition on different substrates, because the tin sensitization process had critical effects on the electroless plated metal thin films. Nowadays electroless plating metal deposition is still an important method for depositing metals. It has a few advantages over the vapor deposition and electrodeposition method, such as work in an ambient condition, on nonconductive substrates, and without extra power input. Applying electroless …

A Reconfigurable Digital-To-Analog Converter With Supply Invariant Linearity, Nicholas J. Chiolino

Graduate Theses and Dissertations

A novel reconfigurable digital-to-analog converter (DAC) with supply independent linearity is presented. The process agnostic converter achieves wide supply range operation and re-configurability by being charge based. This converter consists of a 7-bit parallel digital input control core and an analog "summing" core utilizing charging capacitors with an operational transconductance amplifier in a voltage-follower configuration. This topology is highly configurable to allow for optimization across process voltages, step sizes and low power operation. The specification of the DAC is (1) supply independence (2) low power operation (3) operation up to 200 kHz and (4) conversion control through a DAC enable …

A Wide Bandgap Silicon Carbide (Sic) Gate Driver For High Temperature, High Voltage, And High Frequency Applications, Ranjan Raj Lamichhane

Graduate Theses and Dissertations

The potential of silicon carbide (SiC) for modern power electronics applications is revolutionary because of its superior material properties including substantially better breakdown voltage, power density, device leakage, thermal conductivity, and switching speed. Integration of gate driver circuitry on the same chip, or in the same package, as the power device would significantly reduce the parasitic inductance, require far less thermal management paraphernalia, reduce cost and size of the system, and result in more efficient and reliable electrical and thermal performance of the system.

The design of a gate driver circuit with good performance parameters in this completely new under-development …

Microfluidics Guided By Redox-Magnetohydrodynamics (Mhd) For Lab-On-A-Chip Applications, Vishal Sahore

Graduate Theses and Dissertations

Unique microfluidic control actuated by simply turning off and on microfabricated electrodes in a small-volume system was investigated for lab-on-a-chip applications. This was accomplished using a relatively new pumping technique of redox-magnetohydrodynamics (MHD), which as shown in this dissertation generated the important microfluidic features of flat flow profile and fluid circulation. MHD is driven by the body force, FB = j × B, which is the magnetic part of the Lorentz force equation, and its direction is given by the right hand rule. The ionic current density, j, was generated in an equimolar solution of potassium ferri/ferro cyanide by applying …

The Development Of A Traumatic Brain Injury Bioreactor, Zachery Heller

Graduate Theses and Dissertations

Approximately 1.7 million Americans experience a traumatic brain injury (TBI) each year. Concussive injuries are a subset of TBI in which blows to the head cause the brain to collide against the interior of the skull. Damage to the neurons, supporting cells, and surrounding extra cellular matrix resulting from these collisions can lead to permanent physical, cognitive, and psychological impairment. We believe the prevalence and clinical significance of concussive injures warrants research investment. To study brain injury following TBI, in vivo models have been the gold standard for TBI experiments. Although a valuable research alternative, animals are expensive, raise ethical …

Identifying Emerging Researchers Using Social Network Analysis, Syed Masum Billah

Graduate Theses and Dissertations

Finding rising stars in academia early in their careers has many implications when hiring new faculty, applying for promotion, and/or requesting grants. Typically, the impact and productivity of a researcher are assessed by a popular measurement called the h-index that grows linearly with the academic age of a researcher. Therefore, h-indices of researchers in the early stages of their careers are almost uniformly low, making it difficult to identify those who will, in future, emerge as influential leaders in their field. To overcome this problem, we make use of Social network analysis to identify young researchers most likely to become …

Development And Evaluation Of Chitosan Particle Based Antigen Delivery Systems For Enhanced Antigen Specific Immune Response, Bhanuprasanth Koppolu

Graduate Theses and Dissertations

Particle-based vaccine delivery systems are under exploration to enhance antigen-specific immunity against safe but poorly immunogenic polypeptide antigens. Chitosan is a promising biomaterial for antigen encapsulation and delivery due to its ability to form nano- and microparticles in mild aqueous conditions thus preserving the antigenicity of loaded polypeptides. The objective of this work is to develop a chitosan particle based antigen delivery system for enhanced vaccine response. Chitosan particle sizes, which ranged from 300 nm to 3 ìm, were influenced by chitosan concentration, chitosan molecular weight and addition rate of precipitant salt. The composition of precipitant salt played a significant …

An Open Source, Line Rate Datagram Protocol Facilitating Message Resiliency Over An Imperfect Channel, Christina Marie Smith

Graduate Theses and Dissertations

Remote Direct Memory Access (RDMA) is the transfer of data into buffers between two compute nodes that does not require the involvement of a CPU or Operating System (OS). The idea is borrowed from Direct Memory Access (DMA) which allows memory within a compute node to be transferred without transiting through the CPU. RDMA is termed a zero-copy protocol as it eliminates the need to copy data between buffers within the protocol stack. Because of this and other features, RDMA promotes reliable, high throughput and low latency transfer for packet-switched networking. While the benefits of RMDA are well known and …

One-Dimensional Compressibility Of Intermediate Non-Plastic Soil Mixtures, Sean E. Salazar

Civil Engineering Undergraduate Honors Theses

The results of high stress, one-dimensional compression testing on intermediate soils are presented. Nevada Sand and silica silt mixtures were subjected to very high vertical stresses (140 MPa) in one-dimensional, monotonic compression. Each soil mixture was tested in a nominally loose condition. A specially designed mold with an integrated sensor array was fabricated to contain the soil during pre-consolidation and loading. The 1-D compression curve was plotted for each mixture in the double-logarithmic void ratio (e), and vertical effective stress (σ’v) space and characteristics of the Limiting Compression Curve (LCC) were identified. Initial and post test grain size distribution curves …

Analysis Of Social Networks In A Virtual World, Gregory Thomas Stafford

Graduate Theses and Dissertations

As three-dimensional virtual environments become both more prevalent and more fragmented, studying how users are connected via their avatars and how they benefit from the virtual world community has become a significant area of research. An in-depth analysis of virtual world Social networks is needed to evaluate how users interact in virtual worlds, to better understand the impact of avatar Social networks on the virtual worlds, and to improve future online Social networks.

Our current efforts are focused on building and exploring the Social network aspects of virtual worlds. In this thesis, we build a Social network of avatars based …

Developing Process Control Experiments For Undergraduate Chemical Engineering Laboratories, Chase M. Swaffar

Graduate Theses and Dissertations

It is the intent of this work to develop a process control apparatus and series of experiments that will help students visualize the PID (Proportional-Integral-Derivative) control of a process and enhance their understanding of the subject. The apparatus is a computer-controlled PID mixing system that responds quickly to set point changes and process disturbances which are directly observable. The system can easily be simulated with a transfer function model in Matlab's Simulink, so that the controller can be optimized for the desired system response. Four experiments can be conducted with this system including: exploration of system modeling and controller optimization …

Attitudes And Behaviors In Online Communities: Empirical Studies Of The Effects Of Social, Community, And Individual Characteristics, Richard Kumi

Graduate Theses and Dissertations

Online communities and communities of practice bring people together to promote and support shared goals and exchange information. Personal interactions are important to many of these communities and one of the important outcomes of personal interactions in online communities and communities of practice is user-generated content. The three essays in the current study examines behavior motivation in online communities and communities of practice to understand how Social and personal psychological factors, and user-generated influence attitudes, intentions and behaviors in online communities.

The first essay addresses two research questions. First, how does Social capital influence exchange and combination behaviors in online …

A Solar-Powered And Multi-Tiered Mesh Node For A Portable In Situ Emergency Response System, Adam Matthews

Graduate Theses and Dissertations

The aftermath of a natural disaster is typically characterized by lack of a reliable medium for dissemination of information to survivors. Current state-of-the-art emergency response systems rely on satellite radio-enabled devices, but survivors, unlike first responders, do not have access to such devices. To mitigate this problem, we present PERPETUU a solar-powered portable GIS microserver. The microserver node can be deployed in a disaster scene, and can serve maps to survivors viewable on browsers of off-the-shelf mobile systems. A key innovation in the design of the PERPETUU node is a multi-tiered hardware architecture-the system combines a low-power micro-controller, a medium-power …

Design, Fabrication And Characterization Of Plasmonic Fishnet Structures For The Enhancement Of Absorption In Thin Film Solar Cells, Sayan Seal

Graduate Theses and Dissertations

Incorporating plasmonic structures into the back spacer layer of thin film solar cells (TFSCs) is an efficient way to improve their performance. The fishnet structure; which is a tunable, plasmonic light scatterer is used to enhance light absorption. Unlike other plasmonic particles that have been previously suggested, the fishnet is an electrically connected wire mesh and does not result in electric field localization, hence it results in greater absorption in the intrinsic Si layer. Unlike other designs, the fishnet structure is placed in the back spacer layer of the TFSC, so it does not block any incident light. There is …

Monodentate, Bidentate And Photocrosslinkable Thiol Ligands For Improving Aqueous Biocompatible Quantum Dots, Hiroko Takeuchi

Graduate Theses and Dissertations

Water-soluble Quantum Dots (QDs) are highly sensitive fluorescent probes that are often used to study biological species. One of the most common ways to render QDs water-soluble for such applications is to apply hydrophilic thiolated ligands to the QD surface. However, these ligands are labile and can be easily exchanged on the QD surface, which can severely limit their application. As one way to overcome this limitation while maintaining a small colloidal size of QDs, we developed a method to stabilize hydrophilic thiolated ligands on the surface of QDs through the formation of a crosslinked shell using a photocrosslinking approach. …

Distortion-Tolerant Communications With Correlated Information, Ning Sun

Graduate Theses and Dissertations

This dissertation is devoted to the development of distortion-tolerant communication techniques by exploiting the spatial and/or temporal correlation in a broad range of wireless communication systems under various system configurations. Signals observed in wireless communication systems are often correlated in the spatial and/or temporal domains, and the correlation can be used to facilitate system designs and to improve system performance. First, the optimum

node density, i.e., the optimum number of nodes in a unit area, is identified by utilizing the spatial data correlation in the one- and two-dimensional wireless sensor networks (WSNs), under the

constraint of fixed power per unit …

Zinc Oxide Nanorod Based Ultraviolet Detectors With Wheatstone Bridge Design, Arun Vasudevan

Graduate Theses and Dissertations

This research work, for the first time, investigated metal semiconductor-metal (MSM) zine oxide (ZnO) nanorod based ultra-violet (UV) detectors having a Wheatstone bridge design with a high

responsivity at room temperature and above, as well as a responsivity that was largely independent of the change in ambient conditions. The ZnO nanorods which acted as the sensing element of the detector were grown by a chemical growth technique. Studies were conducted to determine the effects on ZnO nanorod properties by varying the concentration of the chemicals used for the rod growth. These studies showed how the rod diameter and the deposition …

Investigation Of The Effects Of Rapid Thermal Annealing On Mbe Grown Gaasbi/Gaas Heterostructures For Optoelectronic Devices, Perry C. Grant

Graduate Theses and Dissertations

High efficiency optoelectronic devices rely on high quality materials making up the device structure. The scope of this thesis investigates the effectiveness of rapid thermal annealing (RTA) at improving the material quality of GaAsBi/GaAs heterostructures. During the fabrication of a device, the contacts of the device had the rapid thermal annealing process accomplished to produce ohmic contacts and this research explored if this annealing treatment degraded the quantum wells that made up the active region of a device. To investigate these effects, a system to measure the photoluminescence of the material system was constructed utilizing Fourier Transform Infrared Spectroscopy. The …

Effect Of Lightweight Aggregate Moisture Content On Internally Cured Concrete, Casey Jones

Graduate Theses and Dissertations

Putting an end to the rapid deterioration of concrete structures in the United States will only occur through the introduction of better materials and construction methods. The American Society of Civil Engineers (ASCE) reports the overall condition of concrete bridges in the United States to be a "C+". Though better than other areas of the infrastructure, there is still room for improvement in concrete bridges. One major area that may be improved is that of the concrete bridge deck. The bridge deck is comprised of the actual driving surface. It is subject to many deterioration mechanisms including freeze/thaw cycles, de-icing …

Electrical Design Considerations And Packaging Of Power Electronic Modules, Shijie Wang

Graduate Theses and Dissertations

A modern power electronic module can save significant energy usage in the power electronic systems by improving their switching efficiencies. One way to improve the efficiency of the power electronic module is to reduce its parasitic circuit elements. The purpose of this thesis is to investigate the mitigation of parasitic circuit elements in power electronic modules. General methods of mitigating parasitic inductances were analyzed by the Q3D Extractor and verified by the time-domain reflectometry (TDR) measurements. In most cases, the TDR measurement results closely matched those predicted by the Q3D Extractor. These methods were applied to design and analyze a …

Parameterizing Analytical Models To Support An Empirically Based Warehouse Design Methodology, Lisa Thomas

Graduate Theses and Dissertations

Research in the area of warehouse design is characterized by a myriad of analytical models that address one, typically small and isolated, area of the warehouse. These models, although important in gaining insight into one question of warehouse design, are of limited value when one considers the larger question of overall warehouse design. Thus, research in the area of overall warehouse design typically consists of procedure-driven processes based on qualitative factors and not the quantifiable results of analytical models.

In contrast, practitioners have significant empirical data related to how a design alternative performs in an industry, a company, or a …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

The Legitimation Of Novel Technologies: The Case Of Nanotechnology, Anastasia E. Thyroff

Graduate Theses and Dissertations

Nanotechnology is the control, manipulation, and application of matter on an atomic and molecular level. The technology is complex and confusing to consumers, and its long-term safety and effect on the human body, as well as the environment, are unknown. However, for the past decade, nanotechnology has been used to develop consumer products and food with novel and attractive attributes.

Since nanotechnology is still not well known, it is not legitimized; that is, it has not been deemed safe and accepted by society. However, the market for nanotechnology is in the legitimation process. It will take an entire network of …

Structural Properties Of Ferroelectric Lead (Zirconium0.5,Titanium0.5)Oxygen3 Nanotube Array And Electronic Structure Of Lao Delta-Doped Strontium Titanate, Rajendra Prasad Adhikari

Graduate Theses and Dissertations

In this Dissertation we begin with two introductions on: 1) ferroelectricity and related phenomena, and 2) novel properties of Oxide electronics and the generation of two dimensional electron gas. We then give theoretical background of density functional theory (including LDA+U) and pseudopotentials. The first part of research work is about structural, polarization, and dielectric properties of ferroelectric Lead Zirconate Titanate (PZT) solid solution in the form of a nanotube array, embedded in a matrix medium of different ferroelectric strengths. We use the effective Hamiltonian derived from first-principles and finite-temperature Monte Carlo methods to determine the various properties. We revealed different …

Analysis Of Parameter Tuning On Energy Efficiency In Asynchronous Circuits, Justin Thomas Roark

Graduate Theses and Dissertations

Power and energy consumption are the primary concern of the digital integrated circuit (IC) industry. Asynchronous logic, in the past several years, has increased in popularity due to its low power nature. This thesis analyzes a collection of array multipliers with different parameters to compare two asynchronous design paradigms, NULL Convention Logic (NCL) and Multi-Threshold NULL Convention Logic (MTNCL). Several commercially available pieces of software and custom scripts are used to analyze the asynchronous circuits and their components to provide the energy consumption estimation on various parts of each circuit. The analysis of the software results revealed that MTNCL circuits …