Engineering Commons^™

Spacecraft Fire Safety Research: Combustion Of Lithium-Ion Batteries To Predict Fire Scenarios, Elisabeth Meyer

Williams Honors College, Honors Research Projects

The purpose of this project was to research characteristics of a Lithium-ion battery fire to determine if trends exist in measured fire characteristics that can help predict different fire scenarios. These experiments will ultimately aid in developing an alarm threshold for a spacecraft smoke detector, specifically for Orion, a new, multi-purpose crew vehicle under development by NASA. Orion is the next-generation of spacecraft designed to replace the space shuttle and will play an important role in NASA’s journey to Mars.

In the experiments performed, Lithium-ion batteries were placed in a test chamber and ignited while smoke concentration was measured, simulating …

Sequence Effects On The Glass Transition Temperature, William Drayer

Williams Honors College, Honors Research Projects

Lithium ion batteries are widely used for the energy needs of portable electronic devices. Unfortunately, current liquid organic solvents used as the electrolytic portion of the battery have low thermal stability, resulting in batteries that may combust upon failure. This flammability can be attributed to the configurational strain in cyclic organic electrolytes. Due to the lack of configurational strain in a flexible polymer chain, designing polymer electrolytes for use in lithium ion batteries may result in a safer battery due to their lower flammability in comparison to traditional liquid organic electrolytes. From the perspective of an electrolytic polymer, lowering the …

The Influence Of Organic Pigments On Coating Properties, Sarah Medeiros

Williams Honors College, Honors Research Projects

Abstract

The purpose of this project was to identify the qualities of two synthesized organic pigments added to a coating. These high-performance pigments were benzodipyrrolidone and benzodifuranone, which are π-conjugated monomers. These pigments were each formulated into two different pigment concentrations and compared with a control that had no pigment. This project is limited by time constraints and the number of variables that can be tested in that time. Performance testing was conducted to evaluate the qualities of these coatings. The results demonstrated that the coatings were reproducible and most tests had results that were equal to or exceeded the …

Development Of Entubulation Strategies For Treating Central Nervous System Injuries, Ivy Brosch

Williams Honors College, Honors Research Projects

According to the McKnight Brain Institute, at least 10,000 people annually in the USA suffer from a central nervous system (CNS) injury. These injuries can cause serve disabilities including paralysis. Due to the complexity of the spinal cord, it is common that potential CNS treatments are first applied to an optic nerve crush (ONC) model in rats. Two proposed treatments were employed; one where nerve growth factor (NGF) was immobilized to a chitosan substrate to stimulate axonal regeneration, and the other using pentadecafluorooctanoyl chloride modified methacrylamide chitosan (MAC(Ali15)F) hydrogel to enhance local oxygenation. The two different treatments were formed into …

Vanadium Redox Flow Batteries: Design And Experimentation, Matthew George

Williams Honors College, Honors Research Projects

Vanadium flow batteries (VFB) are a type of battery that has potential as a grid-scale energy storage solution. An original design for a lab-scale VFB is presented herein, along with a procedure for electrolyte preparation from V₂O₅ using oxalic acid. The flow cell is constructed from Delrin, Teflon, Kynar, Santoprene, Nafion, graphite plate, and porous carbon. Two diaphragm pumps along with polyethylene, PVC, and Santoprene tubing are used. The active area is 58 cm². The battery was charged using a DC power supply at a constant current of 4 A with corresponding initial voltage of …

Galvanic And Pitting Corrosion Of A Fastener Assembly, Julie Shallman

Williams Honors College, Honors Research Projects

This research focuses on coupled galvanic/pitting corrosion of AA7075 when combined with stainless steel in a fastener assembly. A one-dimensional mathematical model of a well-mixed thin film electrolyte is developed to predict the damage profile of the AA7075 surface when its protective coating is damaged. The damage exposes the galvanic couple. A time dependent system of partial differential equations for potential, chloride concentration, aluminum ion concentration, and damage is developed and solved numerically. Two approaches to calculate the current density within aluminum pits are discussed. The first is a current balance between the cathodic, anodic and passive portions of the …

Ball Oscillating Bouncer, Eric Blok, Daniel Altemese, Ryan Nowacki, Maram Qurban

Williams Honors College, Honors Research Projects

The purpose of this report is to document the need, objectives, marketing and engineering requirements, as well as validate the design of an autonomous control device capable of continuously bouncing a table tennis ball on a paddle. This includes the design of a self correcting system using lightweight materials, and as few sensors and components as possible to achieve a compact, portable design. To accomplish this, the system is designed to react to a ball falling from as short a distance as 10 centimeters above the paddle, meaning all sensor processing, control processing, and motor drives should be able to …

Modeling Crevice Corrosion Of Nickel Alloy 625 In Seawater, Linsey Grzeschik

Williams Honors College, Honors Research Projects

In this work, COMSOL Multiphysics was used to model crevice corrosion of Nickel Alloy 625 in seawater. Initial model parameters included a bulk solution of 0.6M (Cl^-) ASTM D1141-98 artificial seawater, a crevice length of 12.7mm, and applied current of 0.44V_SHE. A crevice gap of 7μm and 10μm were compared using a 3.0m polarization curve of the simulated critical crevice solution for Alloy 625. A constant crevice gap of 10μm was used to compare varying polarization curves of 3.0m, 3.5m, and deaerated seawater. The model found a variation in free chloride concentration from the bulk to …

Administrative Cost Reimbursement Online, Luciano Mogorovic

Williams Honors College, Honors Research Projects

Administrative Cost Reimbursement (ACR) is a program funded by the state of Ohio that reimburses non-public elementary and high schools for having employees perform a series of mandated activities. ACR Consultants is a company that collects data from schools that contains the amount of time each teacher spent on any of the mandated activities. The president of ACR Consultants is a neighbor and longtime family friend. Currently, to collect the time data, the company goes to each school it services and gives each teacher a large paper spreadsheet for them to fill in with the amount of time they spend …

Garbage Disposal, Madison Popa, Tyler Miller, Mitchell Wheeler, Johnathon Klebe

Williams Honors College, Honors Research Projects

The purpose of this report is to outline a new design for a sink garbage disposal system. The goal of this design is to develop a garbage disposal that could be made for less money, which would turn into a cost savings for the consumer and would lead to an increase in the amount of garbage disposal systems being used throughout the world. This allows the garbage disposal system to be marketed to different parts of the world that currently can’t afford the systems available on the market.

The increased use of garbage disposals, help reduce the amount of organic …

Sweat Sensor Modelling, Katie Brumbaugh

Williams Honors College, Honors Research Projects

There are no in-situ electrolyte sodium sensors available in the marketplace, however there is a demand and use for them. An in-situ sodium sensor can be used to monitor bodily functioning in many applications like medical patient monitoring and athlete monitoring during workouts. Patients with cystic fibrosis attempt to monitor salt content in sweat to maintain homoeostatic body function, this sweat sensor would change the way those patients took care of themselves [1]. Sweat sensor samples were made using multiwalled carbon nanotubes (MWNT) and nylon 6. The MWNTs were functionalized on the nylon using cyclo-oligomeric calixarene [3]. In functionalizing the …

Residence Time Distribution Of Mixing Based On Mathematical Modeling, Michelle Ayers

Williams Honors College, Honors Research Projects

Two different mathematical models were investigated for their use in describing the residence time distribution (RTD) of an industrial mixer. The first model investigated was the tanks-in-series model, while the second model was a combination of two branches of tanks-in-series. The tanks-in-series model is capable of characterizing the mixing present in the flow, but cannot detect non-idealities in flow such as bypassing and dead space. The multi-branch model has mathematical complexity, but it uses the second branch of flow to detect the presence of this non-ideal flow, determine if it is dead space of bypassing, and characterize how well-mixed the …

Robotic Mining Digging Core, John Stefan, Ryan Weir

Williams Honors College, Honors Research Projects

The purpose of this design project is to design a digging core for a lunar robot that will collect large amounts of material buried beneath the surface of Mars so one day, astronauts can use those resources. This lunar robot will be competing in the NASA Robotic Mining Competition, where teams from universities around the country display and test their designs. This design must adhere to a newly implemented rule which states that the amount of gravel a robot collects will determine the team score. The layer of gravel is located underneath a layer of Regolith, which simulates the surface …

Basic Highway Workzone Safety, Collin Shamberger

Williams Honors College, Honors Research Projects

The purpose of this essay will be to examine, and provide information detailing work zone safety practices, and maximizing safety in construction zones. This report will examine the functionality of components of a work zone and how they work together, the use of standard construction drawings of work zones, personal protective equipment of workers, possible hazards of work zones, minimizing risks and ultimately work zone safety training. Also this report will provide a spreadsheet which can be used to calculate and layout a construction work zone based on a GPS location.

Evaluation Of Silane-Doped Epoxy Coatings For Resisting Aluminum Corrosion By Oxalic Acid, An A. Niger Metabolite, Alex Pica

Williams Honors College, Honors Research Projects

The goal of this study was to investigate whether silane-doped epoxy coatings are capable of preventing corrosion of aluminum alloy 2024-T3 by oxalic acid, one of the primary metabolites of the fungus Aspergillus Niger. Previous research suggested the success of these types of coatings at preventing AA 2024-T3 corrosion in saline solutions, and this study was meant to build on those findings by investigating the efficacy of the coating in an acidic environment.

Each coating was applied to an AA 2024-T3 coupon by dissolving the epoxy and varying amounts of 3-aminopropyltriethoxysilane in acetone and then dripping the solution onto …

Winter Maintenance Of Akron Roadways, Kayla Hillegass

Williams Honors College, Honors Research Projects

The city of Akron experiences several hundred crashes each winter season due to winter road and weather conditions. The winter maintenance practices of the city follow a guide by the Salt Institute that uses a combination of plowing and salting to clear the roads. This paper provides an understanding of winter maintenance from its beginnings to present day and will discuss how certain practices came to be. Looking at three other cities across the United States with similar characteristics in size or snowfall amount show many similarities with a few new concepts that Akron can consider (e.g., better communication via …

Investigation Of Scanning Kelvin Probe Techniques, Nicholas D'Angelo Jr., Hongbo Cong

Williams Honors College, Honors Research Projects

The original scope of this work was to advance the understanding of corrosion properties of additively manufactured (AM) materials by correlating microstructural defects in AM materials to the material conventional counterparts utilizing a scanning kelvin probe [Ametek VeraSCAN Electrochemical System]. However, upon the initiation of project research, it was observed that the system was not operational due to unknown hardware and software problems. The evolved scope of this work was to reconcile the operational issues and develop a repair and mitigation plan. After extensive troubleshooting, it was determined that the software was not properly configured, and the electrometer had permanently …

Reaction Kinetics Of The Hydrogenation Of Phenol In A Tubular Reactor, Michael Selzer

Williams Honors College, Honors Research Projects

The reaction kinetic parameters for the hydrogenation of phenol to cyclohexanone are determined for the liquid phase reaction with the palladium catalyst supported on an electrospun PVDF membrane. Runs of the reactor were completed at catalyst loadings of 40, 50, and 60 g/m², and tube diameters of 0.187 in and 0.25 in with a runtime of ten hours. One-dimensional and two-dimensional models of the experimental setup were developed. Fitting data to the one-dimensional model found that the pre-exponential factor was 2.50 x 10⁴, the activation energy was 7.69 kJ/mol, and the order with respect to phenol …

Polyhexamethylene Biguanide Release By Chitosan-Heparin Nanoparticles, Jacob Ress

Williams Honors College, Honors Research Projects

Chitosan and heparin were used to synthesize nanoparticles using polyelectrolyte complexation. The optimal mixing ratio was determined to be 1:4 by studying the particle characteristics of zeta potential and dynamic light scattering of the ratios 1:2, 1:3, 1:4, 1:5 and 1:6 (chitosan: heparin). The particles were loaded with the antibiotic polyhexamethylene biguanide (PHMB) and the release was measured over 335 hours using the dialysis membrane incubation method and detected via ultraviolet-visible (UV-Vis) spectroscopy. Around 80% of the encapsulated PHMB was released over the measured period. The goal of this part of the study was to determine the drug release behavior …

Swagelok Adjustable Check Valve Setting Device, Brandon Sours, Paul Olson, David Race, Nick Rimpf

Williams Honors College, Honors Research Projects

Check valves are used to control the amount of flow through a valve and only open when a certain pressure is reached. The path of the fluid is strictly in one direction, which allows the valve to prevent any back flow within a system. They are also one of few self-automated piping system components that do not require assistance to open or close. Some check valves use a combination spring-and-nut compression assembly to set an opening pressure. As the nut is used to set the spring compression, and by extension the opening pressure, problems tend to arise when adjusting the …

Environmentally Friendly Alternates To Chemlok 233 Adhesive Cement, Madeline M. Busch

Williams Honors College, Honors Research Projects

The purpose of this project was to determine and qualify suitable, environmentally friendly replacement(s) for the current Chemlok 233 adhesive cement used by UTC Aerospace. Chemlok 233 was discontinued by the manufacturer based on the availability of a hazardous solvent (Trichloroethylene – TCE). The Chemlok 233 Control and four Experimental alternates with similar properties were lab tested for adhesion strength in various UTC proprietary cement specifications. The specifications modeled Chemlok’s uses in the construction of pneumatic de-icers. Chemlok 2332 was selected for use in Cement A, and Chemlok 402 was chosen for use in Cement B based on their highest …

Battery Test Chamber, Olivia Cole, Noah Purdy, Jacob Happ

Williams Honors College, Honors Research Projects

A battery test chamber was designed for temperature-controlled experiments on batteries. The apparatus is a standalone desktop unit capable of testing a battery of maximum size 2.25” x 2.25” x 2”. There are two separate chambers divided by a rotating, 90° door. The chamber halves are used for heating and cooling the battery, respectively. An adjustable mount for the battery allows for variation in sample size and securely holds the battery throughout the experiment. The operator can twist a knob on top of the box to spin the battery between the hot and cold chambers. The hot side is equipped …

Guardian Condor, Jake Stefanick, Matt Wallace, Dan Bologna, Kevin Bayonnet

Williams Honors College, Honors Research Projects

The group was tasked with designing a 3D printed glider. The scope of this assignment is to someday use the developed glider design and equip it with electronics and controls to deliver medical materials to remote areas in drone-like fashion. The glider was to be designed so that it could be printed using a lower-end, compact, and relatively portable 3D printer for optimal field efficiency. For this reason, the makerbot 3D printer was selected. The compact base plate of the makerbot printer left the team with strict size limitations, so the glider was printed in a series of nine parts …

Modification Of Bacterial Cellulose Using Organosilanes To Enhance Cell Adhesion And Growth, Kristi Ferrato

Williams Honors College, Honors Research Projects

In this project, drying bacterial cellulose (BC) to maintain its structural integrity, and treating BC with organosilanes 3-aminopropyltriethoxysilane (APTES) and (3-Mercaptopropyl)trimethoxysilane (MPTMS) as well as with various concentration of gelatin to increase the cells per area was studied. Drying BC with hexamethyldisilazane (HMDS) by soaking the BC in ascending concentrations of ethanol and HMDS did not protect the structural integrity of the BC grown in lab but did for the BC grown in Dr. Siriporn Taokaew’s lab. Freeze drying also did not fully protect the structural integrity as the BC was placed in a freezer for several hours at -20oC …

Correlation Of Electrospun Polyvinylpyrrolidone Fiber Mat Thickness With Basis Weight, Fiber Diameter, Pore Size Distribution, And Air Permeability, Leah Mcpherson

Williams Honors College, Honors Research Projects

This project developed correlations between electrospun polyvinylpyrrolidone fiber mat thickness, basis weight, fiber diameter, pore size, and air permeability. The hypotheses were thinner fibers produce thicker mats, pore size decreases with fiber diameter, pore size and permeability decrease as basis weight increases. Project results could be used for modeling or quality control purposes.

Fiber diameter distributions were analyzed using a Scanning Electron Microscope and FibraQuant 1.3 software. Four conditions were chosen for further study: 0.284 ± 0.104 µm, 0.379 ± 0.128 µm, 0.520 ± 0.138 µm, and 0.733 ± 0.177 µm. Lower PVP concentrations produced thinner fibers.

Sample thickness (nm) …

Molded Features In Pdms For Fabricating Bacterial Cellulose For Various Geometries, Mitchell Habegger

Williams Honors College, Honors Research Projects

The purpose of producing features on bacterial cellulose (BC) is to facilitate the elongation and alignment for cells, in this case Normal Human Dermal Fibroblast (NHDF) cells. The elongated cells have applications in wound healing, tissue engineering, disease diagnostics, and many other fields. Experiments were run to test the effectiveness of transferring features to BC sheets from features induced by fracturing on polydimethylsiloxane (PDMS) and those duplicated from molds with existing features. The features were duplicated to BC sheets by either air drying or Guided Assembly-Based Biolithography (GAB). The research results showed that fracture inducing on PDMS produced very small …

Autonomous Uav Battery Swapping, Reed Jacobsen, Nikolai Ruhe, Nathan Dornback

Williams Honors College, Honors Research Projects

One of the main hindrances of unmanned aerial vehicle (UAV) technology are power constraints. One way to alleviate some power constraints would be for two UAVs to exchange batteries while both are in flight. Autonomous mid-air battery swapping will expand the scope of UAV technology by allowing for indefinite flight times and longer missions. A single board computer will control each UAV’s flight software to respond to inputs to align with each other mid-flight. When the two UAVs have joined, mechanical components will exchange a depleted battery on the worker UAV for a freshly charged battery that belongs to the …

Indicator-Supporting Fixture Based On A Time And Motion Study, James Anthony

Williams Honors College, Honors Research Projects

The design goal of this project was proposed by the sponsor company, Jay-Em Aerospace in Cuyahoga Falls, Ohio. I was tasked with observing a process carried out in the Assembly department by multiple people and charged with coming up with a fixture to improve safety, speed, and accuracy of this task. To determine how to make the process safer, interviews were conducted with the people who would usually be carrying out this process and determined their top concerns and issues with how it is carried out currently. To improve the speed and accuracy of the process, a "time and motion …

Human Powered Vehicle Design Team: Speed Variable Steering Stabilizer, Eric Miller, Matt Kraml

Williams Honors College, Honors Research Projects

The Human Powered Vehicle Competition (HPVC) is held annually by ASME at a few locations. The University of Akron has competed in the ASME-East and ASME-West competitions over the past handful of years against universities from all over the world. Objectives of each team for the competition are three-fold: vehicle design, racing performance, and innovation. Our senior design project involved working on the innovation concept for ASME-East 2018 held at Penn State University during the weekend of 4/13. Speed variable steering was decided upon by the entire HPVC team early in the design process as the innovation choice for this …

Impedance Tube Alternative Via The Transfer Function Method, Nathan Palella, Griffin J. Binkley

Williams Honors College, Honors Research Projects

Typical industry-ready impedance tube systems for measuring sound absorption cost between $20,000 and $60,000. The scope of this project was to explore an industrial impedance tube and its functions as well as iteratively reduce the cost of each component of the system to its lowest possible conclusion without severely sacrificing quality of data acquisition. Replacement of the hardware and software with “off-the-shelf” alternatives and custom-made components can reduce the overall cost by as much as two orders of magnitude in order to be used in the education sector, mainly high schools. We find that the designed tube and driver replacements …