Engineering Commons^™

Characterizing Emissions From Open Burning Of Military Food Waste And Packaging From Forward Operating Bases, Thomas Dominguez

Theses and Dissertations

Emissions were characterized and compared from the open burning of four compositions of Meals, Ready-To-Eat (MRE) and four types of MRE fiberboard packaging in response to inhalation concerns at military forward operating bases. Measurements of particulate matter (PM2.5, PM10) showed that MREs account for 70-90 percent of PM emissions when burned in unison with the current fiberboard container and liner and that PM2.5 constitutes a vast majority of the particulates emitted. Targeted replacement of MRE constituents may be more effective in reducing volatile organic compound (VOC) and polycyclic aromatic hydrocarbon (PAH) emissions than the variation of fiberboard packaging designs, while …

Material And Design Considerations For A Portable Ultra-Violet (Uv) Light Emitting Diode (Led) Water Purification Device, Drew D. Gallucci

Theses and Dissertations

Department of Defense personnel often deploy to austere environments where clean water is not readily available. Ultraviolet (UV) radiation through the use of light emitting diodes (LEDs) in a portable device offers a potential method for expedient water treatment. This research studied the application of one diode, low power, UV LEDs and nine diode, high power, UV LEDs within a portable steel reactor and Teflon reactors of three different wall thicknesses. Reactor efficiency was determined through measuring and comparing the rate constants for Advanced Oxidation of hydrogen peroxide with yellow tartrazine as a witness dye. Experiments conducted with low power …

A Simulation-Based Analysis Of Chemical And Radiological Hazard Zones Adapted To Physical Boundaries, Mickie J. Sundheim

Theses and Dissertations

In the United States, industrial and terrorist use of chemical, biological, radiological, and nuclear (CBRN) materials pose a risk to public safety. During the initial phase of typical CBRN incidents, emergency responders establish hazard zones based on standard distances from published guidelines and recommendations. This research investigates how standard hazard zones change in a real world environment that accounts for physical boundaries. Using a python simulation in ArcGIS®, new hazard zones were created by expanding standard hazard zones to follow nearby roads, railroads, and rivers. The new and standard zones were compared by calculating the population and area affected by …

The Effect Of Ph And Pulsed Ultraviolet Light Emitting Diode Duty Cycles On The First Order Rate Constant And Byproduct Profile Of The Advanced Oxidation Of Tartrazine, Brandon M. Stewart

Theses and Dissertations

Water treatment capability is required for military operations, production of drinking water, and industrial wastewater treatment. The Advanced Oxidation Process (AOP) is one of many viable steps for treating water; however, it is important to understand the byproducts of the treatment process to avoid creating other constituents more severe than the first. Tartrazine (TAR) was oxidized with pulsed Ultra- Violet (UV) Light Emitting Diodes (LEDs) in combination with hydrogen peroxide (H2O2) in an AOP at the laboratory scale. The relative concentration of TAR was reduced from 1 to between 1 – 0.75 over pH values between 6 and 9, and …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …