Engineering Commons^™

A Comprehensive Investigation Of The Influence Of Geometric Structure On The Shape Memory Performance Of Nafion, Jade Thomas

Physics Undergraduate Honors Theses

While perfluorosulfonic acid (PFSA) membranes have primarily been used in fuel cells due to their chemical, thermal, and mechanical stability, one PFSA, Nafion, boasts two unique characteristics: a broad glass transition (~55 °C to 130 °C) and a temperature-persistent electrostatic network. The combination of these two characteristics endows Nafion with exceptional shape memory properties – the ability of a material to morph and transform into pre-programmed shapes when exposed to an external stimulus – with enhanced permanent shape memorization, and a potentially near-infinite number of temporary shape memorization. This study focused on expanding the base of knowledge surrounding Nafion’s shape …

A Comprehensive Investigation Of The Influence Of Geometric Structure On The Shape Memory Performance Of Nafion, Jade Thomas

Mechanical Engineering Undergraduate Honors Theses

While perfluorosulfonic acid (PFSA) membranes have primarily been used in fuel cells due to their chemical, thermal, and mechanical stability, one PFSA, Nafion, boasts two unique characteristics: a broad glass transition (~55 °C to 130 °C) and a temperature-persistent electrostatic network. The combination of these two characteristics endows Nafion with exceptional shape memory properties – the ability of a material to morph and transform into pre-programmed shapes when exposed to an external stimulus – with enhanced permanent shape memorization, and a potentially near-infinite number of temporary shape memorization. This study focused on expanding the base of knowledge surrounding Nafion’s shape …

Damage Control Measures In Composites: Focus On Damage Tolerance Of Aerospace Structures, Kais Jribi

Doctoral Dissertations and Master's Theses

Barely Visible Impact Damage (BVID) in composite materials presents a stealthy yet significant risk to structural integrity, particularly challenging due to its elusive nature. The approach adopted here diverges from traditional methodologies, focusing on the novel application of Digital Image Correlation (DIC) to map surface area changes during in-situ Compression After Impact (CAI) tests. This technique allows for an in-depth analysis of planar strains along the x and y axes, shedding light on the material's behavior under stress.

A pivotal advancement lies in developing a method for precisely identifying when BVID-induced delamination recommences. By meticulously analyzing strain pattern deviations along …

Adaptive Control Of An Aeroelastic System For Active Flutter Suppression And Disturbance Rejection, Patrick Sterling Downs

Doctoral Dissertations and Master's Theses

The future of aircraft design strives for lighter weight, more aerodynamically efficient structures. These improvements may come with the drawback of increased structural flexibility and elevated aeroelastic effects, often resulting in a lower flutter speed. This motivates the implementation of advanced control methods to control aeroelastic systems over a range of flight conditions, suppress and delay the onset of flutter, and compensate for disturbances, actuator dynamics, and unmodeled nonlinear dynamics.

This dissertation first develops a novel method for constructing time-domain simulation models of two and three-dimensional aeroelastic systems, resulting in models that are suitable for the implementation of state-space control …

Ti Nano Powder Speckle Pattern Creation And Use In Dic Of Zno Modified Single Carbon Fibers, James Matthew Harris

Doctoral Dissertations and Master's Theses

As the use of composites continues to grow across aerospace, naval, automotive, construction, 3D printing, and other countless industries, so does the desire to continuously improve their mechanical properties. Improving the adherence of the fiber-matrix interface is one important step for amplifying the capabilities of composites. Work has been performed in modifying carbon fibers by growing zinc oxide (ZnO) nanorods in the fiber surface using a hydrothermal approach, increasing interfacial area and fiber-matrix friction. Macroscale evaluation has shown that the interfacial modification decreases the inter-ply movement and reduces the processing strains and residual stresses. To fully understand the mechanism taking …

Starfish: A Compact, Biomimetic, And Adaptive Shape Memory Alloy Orbital Debris Remover, Katelyn Branaman

Doctoral Dissertations and Master's Theses

This thesis aims to turn the tides on the orbital debris issue through the fabrication and demonstration of a compact, biomimetic, and adaptive shape memory alloy actuated orbital debris remover. The design, referred to as Starfish, is discussed in detail along with its fabrication process and object capture ability. A hard skeleton crafted from PETG was combined with shape memory alloy wires and extension springs to create a biomimetic structure that operates similar to the human hand, capable of gripping a wide range of objects. Relevant simulations were performed and discussed, the iterative fabrication process used to create each component …

A Comparison Of Beamforming Characteristics In Isotropic And Composite Plate Structures For Use In Structural Health Monitoring, Sarah Ketchersid

Doctoral Dissertations and Master's Theses

Structural health monitoring in plate-like simple structures using phased array beamsteering of guided Lamb waves is useful in damage detection and evaluation efforts. Lamb waves can be effectively used for beamsteering using a linear array. The experimentation primarily focuses on beamsteering in the aluminum panel, which involves developing a simulation based on extracted data to visualize the dispersion of waves across the panel. By evaluating parameters such as slowness, velocity, and amplitude direction and variation for a specific metallic plate, the wavefront generated by a single wave source can be represented as a function of propagation angle and distance from …

Graphene Reinforced Polymer Composite For Small-Scale Vertical Axis Wind Turbine Rotors, Kunal A. Bachim

Mechanical and Aerospace Engineering Theses

Polymers have evolved as an indispensable asset in various sectors ranging from packaging and construction to energy and aerospace. However, the accumulation of polymer waste poses a necessity to shift toward sustainable waste management processes. Mechanical recycling is a primary method in establishing a circular economy approach for polymers. However, a fundamental challenge arises in this process: a decrease in the mechanical performance of the recycled product compared to that of its pristine counterpart.

This project addresses the challenge of enhancing the recyclability of polyethylene terephthalate (PET) from discarded polymer material by incorporating graphene nanoparticles into the polymer matrix during …

Stochastic Point Process Modeling For Engineering Applications, Samarth Motagi

Doctoral Dissertations and Master's Theses

Hawkes model or self-exciting point process model is a branching point process model. The model classifies the dataset of discrete events to background and offspring events. It has been used to study interconnected events in many fields, but relatively little work exists in applying these concepts to engineering problems. In our research, we use a self-exciting point process model for two engineering applications: (a) To identify secondary crashes from a given traffic data and (b) To quantify the agglomeration state and size of nanoparticles from computationally generated carbon nanotube microstructure using stochastic percolation model and experimentally generated titanium nanoparticle microstructures. …

Robotic Arms For Microgravity Manufacturing, Connor Talley, Joshua Diamond, Mickael Bah

Senior Design Project For Engineers

There is a need to reduce manufacturing cost in space to avoid sending earth manufactured parts that could suffer damage during launch. The proposed idea consists of a dual robotic arm system attached on a precision gantry setup. The team developed an innovative design that is flexible and efficient for different assemblies, improving space manufacturing. With its two specialized robotic arms, our system maximizes versatility by catering to a wide variety of applications from manufacturing to assembly. The dual arms made of Al 7075 coupled with the gantry provides stability and performance in microgravity environments.

Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, Brandon Eugene Williams

All Dissertations

While Carbon Fiber Reinforced Polymers (CFRPs) have exceptional mechanical properties concerning their overall weight, their failure profile in demanding high-stress environments raises reliability concerns in structural applications. Two crucial limiting factors in CFRP reliability are low-strain material degradation and low fracture toughness. Due to CFRP’s low strain degradation characteristics, a wide variety of interlaminar damage can be sustained without any appreciable change to the physical structure itself. This damage suffered by the energy transfer from high- stress levels appears in the form of microporosity, crazes, microcracks, and delamination in the matrix material before any severe laminate damage is observed. This …

Interfacial Thermomechanical Behavior Of Hybrid Carbon Fibers, Sriraj Srihari

Doctoral Dissertations and Master's Theses

The carbon fiber/epoxy interface is of great importance in composite design due to its load transfer mechanisms from the weak epoxy to the stronger fiber. Improving the strength of the interface reduces the risk of failure at the interface and improves the load transfer to the fiber. In this study, two types of nano-species ZnO nanowires and nickel-based metal organic frameworks were grown on carbon fibers to improve the interfaces. The interfacial mechanics of the enhanced fibers are evaluated using nanoindentation studies. Composite samples with Aeropoxy matrix and vertically aligned fibers are fabricated for this purpose. A Bruker TI-980 TriboIndenter …

Data-Driven Porosity Prediction For Directed Energy Deposition, Georgia E. Kaufman

Electrical and Computer Engineering ETDs

Stochastic flaw formation leading to poor print quality is a major obstacle to the utility of directed energy deposition (DED), a laser and metal powder-based additive manufacturing technology for construction and repair of custom metal parts. While melt pool temperature variability is known to be a major factor in flaw formation, control schemes to decrease flaw formation are limited by a lack of physics-based models that fully and accurately describe DED. In this work, a stochastic reachability analysis with a data-driven model based on thermal images of the melt pool was conducted to determine the likelihood of violating melt pool …

In-Situ Thermal And Deformation Characterization Of Additive Manufacturing Processes, Nicholas Phillips

Doctoral Dissertations and Master's Theses

Additive manufacturing (AM) is a rapidly growing industry with numerous applications in the aerospace industry such as aircraft parts and emergency tools on the International Space Station. Defects in additively manufactured structures, however, can waste a lot of time and money. Being able to monitor the manufacturing process for defects is one of the first steps which can be taken to mitigate these losses. This study focuses on the use of thermography in conjunction with deep learning to identify flaws during 3D printing of composite structures made using Onyx, a mixture of chopped carbon fiber and nylon, composite prints. In …

Wast3d Potential, Andrew Larsen

Masters Theses

Waste is obsolete. Standard building industry practices are harmful to the environment. Non-traditional construction methods were examined as alternatives. Circular design logic was the guiding principle in material choice. Additive manufacturing is a proven modern method for building construction. Research on 3D printing case studies revealed that recycled plastic is a proven material and readily available. Removing plastic waste from the environment and sequestering it in architectural components gives the material a new purpose. The component of focus was a building block for a wall assembly. Inspiration was taken from the hexagonal Basalt rock formations found near volcanic fault lines. …

Improving The Tensile Mechanical Properties Of Direct Energy Deposited (Ded) Inconel 718 Aircraft Components Using A Standard Heat Treatment, Spencer Vincent Flynn

Materials Engineering

This project aimed to improve the mechanical properties of as-printed additively manufactured Inconel 718 samples using a heat treatment usually used for cast and wrought Inconel 718. The mechanical properties sought to be optimized were yield strength, ultimate tensile strength, elongation, and reduction in area. The property goals were to match or exceed those of cast and heat treated Inconel 718. Wire-fed electron beam direct energy deposition (DED) was used to manufacture the samples, which were then heat treated using the AMS 5663 standard in an inert atmosphere. The samples were then tested in tension to obtain data on their …

Study Of A Carbon Fiber Reinforced Polymer Composite Using A Biobased Polyurethane As A Thermosetting Resin, Teddy Mageto

Electronic Theses & Dissertations

Carbon Fiber Reinforced Polymer composites (CFRP) have garnered increasing interest in recent years especially in the aerospace and automobile industries where they are gradually replacing metals as structural materials. This is owing to their light weight, high strength, high modulus, and excellent strength-to-weight ratio. Polymers are typically used as thermosetting resins in these composites. However, the synthesis of polymers currently is conducted via petrochemical processes which leads to adverse effects on the environment. To this end, in this work a biobased Polyurethane (PU) was used as a thermosetting resin in a CFRP. The biobased PU was synthesized by the reaction …

Feasibility Of Thermoplastic Extrusion Welding As A Joining Method For Vacuum-Assisted Additively Manufactured Tooling, Chase C. Flaherty

Electronic Theses and Dissertations

In recent years, additive manufacturing (AM) has been successfully utilized for the production of large-scale composite tooling. Within these endeavors, however, limited research has focused on joining methods between printed sections. This work evaluates the feasibility of thermoplastic extrusion welding as a joining method for additively manufactured tooling structures. This joining method was assessed based on industry specifications of conventional thermoset tooling for wind blade manufacturing utilizing the vacuum-assisted resin transfer molding (VARTM) process. The specifications include requirements for the mechanical strength, vacuum integrity, roughness, and hardness of the tool surface. The feasibility of this welded polymer joint was demonstrated …

Investigation Into Sintered Lunar Regolith Construction Methods And Novel Usability Evaluation, Thomas A. Cox

Electronic Theses and Dissertations

Since the Apollo missions in the late 1960's, there has been a growing interest shared by many countries around the world to return to the Moon and establish a permanent Lunar settlement. The first phase of temporary Lunar bases will be established over the next several years. For a permanent human presence on the Moon, it will be necessary to use locally available resources for the construction of Lunar habitats and other infrastructure. Sintering Lunar regolith has been shown to be a promising method for producing structural material with a variety of desirable properties from strength to radiation shielding. While …

A Systematic Study Into The Design And Utilization Of Burn Wire As A Means Of Tensioning And Releasing Spacecraft Mechanisms Through Applied Joule Heating, Chandler Dye

Mechanical Engineering Undergraduate Honors Theses

The joule heating characteristics of Nichrome burn wires, often used as a thermal cutting device in mechanisms designed to fasten and release CubeSat deployables, are examined in the following thesis. Wires ranging from 0.125 inches to 2 inches long, and diameters of 30 Ga and 40 Ga, are investigated through analytical calculations and thermal simulations based on heat transfer due to joule heating, and through physical circuitry-based experiments. The temperature data is used to generate heating curves to predict the time it takes for Nichrome wires to fail under varying testing parameters. This research aims to catalog a series of …

Classification Of Electrical Current Used In Electroplastic Forming, Tyler Grimm

All Dissertations

Electrically assisted manufacturing (EAM) is the direct application of an electric current to a workpiece during manufacturing. This advanced manufacturing process has been shown to produce anomalous effects which extend beyond the current state of modeling of thermal influences. These purported non-thermal effects have collectively been termed electroplastic effects (EPEs).

While there is a distinct difference in results between steady-state (ideal DC) testing and pulsed current testing, the very definition of these two EAM methods has not been well established. A "long" pulse may be considered DC current; a "short" pulse may produce electroplastic effects; and even "steady-state" current shapes …

Superfly Amphibian, Devonte Andrews, Ahmed Hamza, Kwesi Onumah, Eva Sanchez

Senior Design Project For Engineers

Following a Short Takeoff and Landing (STOL) mission profile, this seaplane is designed to carry 19 passengers and 1 flight crew with a range of 200 nautical miles. The seaplane is equipped with two turbo-prop engines and is economically comparable to current seaplanes in terms of servicing and operating expenses. The aircraft is capable of operating in remote locations with limited infrastructure due to its STOL abilities, allowing for increased access to difficult-to-reach areas. The seaplane's design incorporates modern materials and technologies to enhance efficiency, safety, and comfort for passengers and crew. The aircraft's versatility and cost-effectiveness make it an …

The Role Of Slip System Activation On Ni-Based Superalloy High Temperature Fatigue, Alexandru Lopazan

Doctoral Dissertations and Master's Theses

Nickel-based superalloys are used extensively in the aviation industry, particularly in aircraft engine components. These materials are desirable due to their high strength, resistance to creep, corrosive environment, and high temperature. It has been well documented that material fatigue is characterized by material microstructure, type of loading, and other parameters. Currently, research into the effects of fatigue on complex materials like nickel-based superalloys is being pursued. Previous research has found that preconditioning of Inconel 718 samples at 700 ℃ with 1.0% strain led to an improved fatigue life. It has been suggested that this could be caused by the activation …

Characterization Of Bistability Behavior In Unsymmetric Cfrp Laminates, Evan Medora

Doctoral Dissertations and Master's Theses

Composite laminates of unsymmetric layup families often exhibit twin stable shapes at room temperature, a phenomenon known as bistability. Unsymmetric bistable composite laminates have often been suggested for applications in aerospace morphing structures, damping, and energy storage, because of their ability to easily change their shape while being homogenized with the rest of the composite structure.

This study analyzes the mechanisms responsible for bistability in unsymmetrical [0/0/90/90] laminates through a combination of experiments and modeling. Several unsymmetrical laminates with different aspect ratios were fabricated using autoclave processing. Digital image correlation (DIC) is used to monitor laminate strains in situ during …

Determination Of Damage Initiation Mechanisms In Aerospace Alloys Due To Stress Corrosion Cracking Via In-Situ Microscale Characterization Techniques, Remelisa Esteves

Electronic Theses and Dissertations, 2020-

Aluminum alloys are used on aerospace vehicles due to their high strength-to-weight ratio, formability and machinability. However, they become vulnerable to stress corrosion cracking (SCC) during their service life. SCC is primarily caused by the material's stress condition, a suitable corrosive environment and material susceptibility. It is also influenced by a mixture of electrochemical, mechanical, and chemical factors. Due to the complexity of SCC, tools with better resolution and sensitivity are needed to better understand the impact and interaction of the contributing factors. A vast amount of research has been done to study SCC behavior, but the scale of characterization …

Characterizing Air Plasma Sprayed Aluminum Oxide Coatings For The Protection Of Structures In Lunar Environments, Perla Latorre Suarez

Electronic Theses and Dissertations, 2020-

Wear-resistant ceramic and ceramic composite coatings are significant to provide durability and support long-duration missions to the moon's surface for rovers, landers, robotic systems, habitats, and many other components. On the Lunar surface, structural components are continuously exposed to lunar dust projectiles that can cause protective coating delamination around the affected area, of protective coatings and this may not be physically visible. Ceramic coatings, composed of alumina, present excellent resistance to different types of wear due to their high strength and hardness as well as the ability to protect structural components from regolith impacts, wear, and abrasive damage. Air Plasma …

Molecular Dynamics Modeling Of Polymers For Aerospace Composites, Swapnil Sambhaji Bamane

Dissertations, Master's Theses and Master's Reports

Polymer matrix composite materials are widely used as structural materials in aerospace and aeronautical vehicles. Resin/reinforcement wetting and the effect of polymerization on the thermo-mechanical properties of the resin are key parameters in the manufacturing of aerospace composite materials. Determining the contact angle between combinations of liquid resin and reinforcement surfaces is a common method for quantifying wettability. It is challenging to determine contact angle values experimentally of high-performance resins on CNT materials such as CNT, graphene, bundles or yarns, and BNNT surfaces. It is also experimentally difficult to determine the effect of polymerization reaction on material properties of a …

Study Of Nanocomposite Materials Using Molecular Dynamics, Prashik Sunil Gaikwad

Dissertations, Master's Theses and Master's Reports

There is an increase in demand for new lightweight structural materials in the aerospace industry for more efficient and affordable human space travel. Polymer matrix composites (PMCs) with reinforcement material as carbon nanotubes (CNTs) have shown exceptional increase in the mechanical properties. Flattened carbon nanotubes (flCNTs) are a primary component of many carbon nanotube (CNT) yarn and sheet materials, which are promising reinforcements for the next generation of ultra-strong composites for aerospace applications. These flCNT/polymer materials are subjected to extreme pressure and temperature during curing process. Therefore there is a need to investigate the evolution of properties during the curing …

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Surface Preparation Study, Ryan Ferguson

Williams Honors College, Honors Research Projects

This work explores a custom air atmospheric pressure plasma treatment (APPT) machine’s effectiveness in cleaning and chemically activating a CFRP surface. It is explore by implementing water contact angle (WCA) measurements, water-break free (WBF) testing, and adhesive tubular lap-joint (TLJ) tensile testing. An 8x3 test matrix of different machine parameters is defined with the bounding conditions being the machine’s capabilities and industry standard recommendations. Each configuration of the test matrix is explored after treatment at multiple time intervals up to 2 weeks afterwards to gain insight into the outlife of the treatments with the intention of adhesively bonding to the …