Engineering Commons^™

Compounds Released From Biomass Deconstruction: Understanding Their Effect On Cellulose Enzyme Hydrolysis And Their Biological Activity, Angele Djioleu

Graduate Theses and Dissertations

The effect of compounds produced during biomass pretreatment on cellulolytic enzyme was investigated. Liquid prehydrolyzates were prepared by pretreating switchgrass using 24 combinations of temperature, time, and sulfuric acid concentration based on a full factorial design. Temperature was varied from 140°C to 180°C; time ranged from 10 to 40 min; and the sulfuric acid concentrations were 0.5% or 1% (v/v). Identified products in the prehydrolyzates included xylose, glucose, hydroxymethylfurfural (HMF), furfural, acetic acid, formic acid, and phenolic compounds at concentration ranging from 0 to 21.4 g/L. Pretreatment conditions significantly affected the concentrations of compounds detected in prehydrolyzates. When assayed in …

Synthesis Of Palladium And Palladium-Copper Nanostructures As Electrocatalysts, Haibin Wu

Graduate Theses and Dissertations

Pd and its alloys are alternatives of Pt as promising catalysts and electrocatalysts for many reactions. Size controlled synthesis of nanoparticles remains a major research subject, since smaller size particles show better catalytic performance. In this work, we developed a modified chemical wet method to prepare Pd and Pd-Cu nanostructures with uniform small size. Different sizes and shapes of Pd nanostructures were successfully synthesized by using the two reducing agents (i.e., L-ascorbyl-6-palmitate or phenylphosphinic acid). The reducing agents play a role to control the final morphologies and sizes of particles. The use of L-ascorbyl-6-palmitate favors to form irregular branch shapes …

Experimental Verification And Integration Of A Next Generation Smart Power Management System, Tavis Clemmer

Graduate Theses and Dissertations

With the increase in energy demand by the residential community in this country and the diminishing fossil fuel resources being used for electric energy production there is a need for a system to efficiently manage power within a residence. The Smart Green Power Node (SGPN) is a next generation energy management system that automates on-site energy production, storage, consumption, and grid usage to yield the most savings for both the utility and the consumer. Such a system automatically manages on-site distributed generation sources such as a PhotoVoltaic (PV) input and battery storage to curtail grid energy usage when the price …

Incorporating Environmental And Social Factors Into Decision-Making Of An Oil And Gas Industry To Improve Sustainability, Gaurav Dabhadkar

Graduate Theses and Dissertations

The energy industry (including the oil and gas industry) is facing unparalleled scrutiny and demands from stakeholders including investors, regulators (industry and environmental), communities, and other stakeholders. Sustainable development is one of the major concerns of the oil and gas industry. Companies are seeking to increase sustainability of their operations by considering environmental and Social concerns in addition to economic concerns. Oil and gas companies need to take decisions at different stages of the product life cycle (e.g. planning, design, exploration, production, and clean-up) which have direct or indirect impact on the organization's objectives. Addressing economic, technical, Social, and environmental …

Top-Down Aluminum Induced Crystallization For Photovoltaics, Seth Daniel Shumate

Graduate Theses and Dissertations

Passivating silicon solar cell surfaces is critical to fabricating very high efficiency and low cost photovoltaic devices. The sun-facing surface of the solar cell, known as the emitter, is particularly important when designing a solar cell. This work focused first on an alternative method of forming the emitter of silicon solar cells, and secondly on a method for improving the surface passivation of both these non-traditional and standard n-type solar cells.

Top-down aluminum induced crystallization (TAIC) was used for forming a polycrystalline silicon layer from amorphous silicon using aluminum to catalyze the crystallization at much lower temperatures than otherwise possible. …

Enhancement Of The Performance Of Gaas Based Solar Cells By Using Plasmonic, Anti-Reflection Coating And Hydrophobic Effects, Yahia Fayiz Makableh

Graduate Theses and Dissertations

Investigation of renewable energy resources is gaining huge momentum in recent years due to the limited fossil fuels, and their detriment impact on the environment. Solar energy is promising to meet the increased energy demand. In order to achieve this goal, solar energy has to be harvested efficiently at low cost. Therefore, higher efficiency solar cells are the primary focus of research worldwide. Photovoltaics based on InAs/GaAs intermediate band solar cells and their device performance enhancements are investigated in this dissertation. The device enhancement is carried out by surface modification methods. The dissertation work is inspired by the need of …

Transformation Of Swine Manure And Algal Consortia To Value-Added Products, Mahmoud A. Sharara

Graduate Theses and Dissertations

The swine production sector is projected to grow globally. In the past, this growth manifested itself in increased herd sizes and geographically concentrated production. Although economically sound, these trends had negative consequences on surrounding ecosystems. Over-application of manure resulted in water quality degradation, while long-term storage of manure slurries was found to promote release of potent GHG emissions. There is a need for innovative approaches for swine manure management that are compatible with current scales of production, and increasingly strict environmental regulations.

This study aims to investigate the potential for incorporating gasification as part of a novel swine manure management …