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Full-Text Articles in Engineering
Spectroscopic Investigations Of Excited Charge Carriers In Ii-Vi Nanoparticles, William Matthew Sanderson
Spectroscopic Investigations Of Excited Charge Carriers In Ii-Vi Nanoparticles, William Matthew Sanderson
Arts & Sciences Electronic Theses and Dissertations
The large absorption cross sections and the tunability of the energetic spacings between the states in the conduction (CB) and valence band (VB) within a semiconductor nanoparticle (NP) make them promising media for capturing electromagnetic radiation and converting it into charge carriers, or electricity. In photovoltaic devices that incorporate semiconductor NPs, it would be ideal if every photon could be absorbed by a NP and the carriers could be collected with perfect efficiency and without loss of energy. The relaxation pathways of the carriers within the NPs down to the band edge and their fate at the band edge contribute …
Wave Function Engineering In Cdse/Pbs Core/Shell Nanocrystal Heterostructures, Brian Matthew Wieliczka
Wave Function Engineering In Cdse/Pbs Core/Shell Nanocrystal Heterostructures, Brian Matthew Wieliczka
Arts & Sciences Electronic Theses and Dissertations
Colloidal semiconducting nanocrystals hold significant potential for third generation photovoltaics as solution processable materials that can surpass the Shockley-Queisser limit through multiexciton generation. In pursuit of this goal, the synthesis and optical characterization of CdSe/PbS core/shell quantum dots is reported. The spectroscopic behavior of these particles demonstrates their potential for use in optoelectronic devices, taking advantage of wave function engineering of the electron and hole. The rock salt PbS shell grows on all sides of the underlying zinc blende CdSe quantum dot, creating a core/shell structure. With increasing shell thickness, the band edge absorption and photoluminescence transitions decrease in energy …