Engineering Commons^™

Electrochemical Detection Of Reactive Oxygen Species Via A Platinum Microelectrode Array, Victor M. Carriere Jr.

Master's Theses

Oxidative stress, an excess of endogenous or exogenous reactive oxygen species (ROS) in the body, is closely aligned with inflammatory responses. ROS such as hydrogen peroxide, superoxide, and radical hydroxyl ion serve essential functions in fighting infection, but chronic elevation of these species irreversibly damages cellular components. Given the central role of inflammation in a variety of diseases, including Alzheimer’s Disease, atherosclerosis, and rheumatoid arthritis, a low-cost, extracellular, non-invasive assay of ROS is needed.

This work reports the use of a platinum microelectrode array (Pt MEA)-based ceramic probe to detect time- and concentration-dependent variations in hydrogen peroxide (H2O2) production by …

A Multicarrier Technique For Monte Carlo Simulation Of Electrothermal Transport In Nanoelectronics, Tyler J. Spence

Doctoral Dissertations

The field of microelectronics plays an important role in many areas of engineering and science, being ubiquitous in aerospace, industrial manufacturing, biotechnology, and many other fields. Today, many micro- and nanoscale electronic devices are integrated into one package. e capacity to simulate new devices accurately is critical to the engineering design process, as device engineers use simulations to predict performance characteristics and identify potential issues before fabrication. A problem of particular interest is the simulation of devices which exhibit exotic behaviors due to non-equilibrium thermodynamics and thermal effects such as self-heating. Frequently, it is desirable to predict the level of …

Design And Analysis Of A Traveling Wave Fault Locator, Gerald Austin Taylor

Master's Theses

The accuracy of fault location is an integral part of power system operations. Improved fault location can reduce maintenance time, increase efficiency, and save money. When a fault occurs, it sends a disturbance in the current and voltage in each direction at almost the speed of light. This disturbance is called a traveling wave, and can be used to locate faults. In efforts to increase accuracy, the use of traveling wave theory to locate faults has become more popular.

This thesis goes through the process of designing and testing a traveling wave fault locator. The design includes analog and digital …

Spring-Guided Electromagnetic Vibrations Energy Harvester, Ghufran Jaber Aldawood

Master's Theses

In recent years, vibration based energy harvesting techniques showed a promising alternative to power wireless sensor networks (WSN). Billions of low power sensors are currently used widely in wireless sensor networks (WSN) and the Internet of Things environment (IoT). These sensors are currently powered by a traditional power source, i.e. a disposable battery. Vibrations are an abundant source of kinetic energy that can serve as the power source for these sensor nodes. This approach eliminates the necessity for frequent battery replacement due to their short-life span and hazardous disposal process. The adverse and irreversible effect from the disposal of these …

Surface Engineering Solutions For Immersion Phase Change Cooling Of Electronics, Brendon M. Doran

Master's Theses

Micro- and nano-scale surface modifications have been a subject of great interest for enhancing the pool boiling heat transfer performance of immersion cooling systems due to their ability to augment surface area, improve wickability, and increase nucleation site density. However, many of the surface modification technologies that have been previously demonstrated show a lack of evidence concerning scalability for use at an industrial level. In this work, the pool boiling heat transfer performance of nanoporous anodic aluminum oxide (AAO) films, copper oxide (CuO) nanostructure coatings, and 1D roll-molded microfin arrays has been studied. Each of these technologies possess scalability in …

Effective Magnetic And Electric Response Of Composite Materials, Mona Hassan Alsaleh

Doctoral Dissertations

Metamaterials (MMs) are nanocomposite materials consisting of metal-dielectric resonators much smaller in size than the wavelength of the incident light. Common examples of metamaterials are based on split ring resonators (SRRs), parallel wires or strips and fishnet structures. These types of materials are designed and fabricated in order to provide unique optical responses to the incident electromagnetic radiation that are not available in naturally existing materials. The MMs can exhibit unusual properties such as strong magnetism at terahertz (THz) and optical frequencies. Additionally, negative index materials (NIMs) can provide negative index of refraction which can be used in many applications …

Electromagnetic Wave-Matter Interactions In Complex Opto-Electronic Materials And Devices, Raj Kumar Vinnakota

Doctoral Dissertations

This dissertation explores the fundamentals of light-matter interaction towards applications in the field of Opto-electronic and plasmonic devices. In its core, this dissertation attempts and succeeds in the the modeling of light-matter interactions, which is of high importance for better understanding the rich physics underlying the dynamics of electromagnetic field interactions with charged particles. Here, we have developed a self-consistent multi-physics model of electromagnetism, semiconductor physics and thermal effects which can be readily applied to the field of plasmotronics and Selective Laser Melting (SLM). Plasmotronics; a sub-field of photonics has experienced a renaissance in recent years by providing a large …

Understanding The Surface Fouling Mechanism Of Ultrananocrystalline Diamond Microelectrodes Using Microfluidics For Neurochemical Detection, An-Yi Chang

Doctoral Dissertations

Electrochemical methods are widely used for chronic neurochemical sensing, but thus far, the organic solution redox reactions fouled the electrodes' surface. It caused the reduction of sensitivity and the electrodes' lifetime.

Here, we present the boron-doped nanocrystalline diamond microelectrodes (BDUNCD) as the next generation electrode material for neurochemical sensor development. To aid in long-term chronic monitoring of neurochemicals, they have a wide window of electrochemical potential, extremely low background current, and excellent chemical inertness. The main research goal is to reduce the rate of electrode fouling due to the reaction by-products, and significantly extend their useful lifetime.

We systematically characterize …

Electrochemical Behavior Of Dense Electrodes For Impedancemetric Nox Sensors, Nabamita Pal

Doctoral Dissertations

NOx (NO and NO2) exhaust gas sensors for diesel powered vehicles have traditionally consisted of porous platinum (Pt) electrodes along with a dense ZrO2 based electrolyte. Advancement in diesel engine technology results in lower NOx emissions. Although Pt is chemically and mechanically tolerant to the extreme exhaust gas environment, it is also a strong catalyst for oxygen reduction, which can interfere with the detection of NOx at concentrations below 100 ppm. Countering this behavior can add to the complexity and cost of the conventional NO x sensor design. Recent studies have shown that dense electrodes are less prone to heterogeneous …

Stretching The Limits Of Dynamic Range, Shielding Effectiveness, And Multiband Frequency Response, Matthew J. Hartmann

Doctoral Dissertations

In this dissertation, an RF MEMS variable capacitor suitable for applications requiring ultrawide capacitive tuning ranges is reported. The device uses an electrostatically tunable liquid dielectric interface to continuously vary the capacitance without the use of any moving parts. As compared to existing MEMS varactors in literature, this device has an extremely simple design that can be implemented using simple fabrication methods that do not necessitate the use of clean room equipment. In addition, this varactor is particularly suited for incorporating a wide range of liquid dielectric materials for specific tuning ratio requirements.

Additionally, the shielding effectiveness performance of graphene-doped …

Design, Modeling, Fabrication, And Testing Of A Multistage Micro Gas Compressor With Piezoelectric Unimorph Diaphragm And Passive Microvalves For Microcooling Applications, Shawn Thanhson Le

Doctoral Dissertations

This dissertation investigates the development of a multistage micro gas compressor utilizing multiple pump stages cascaded in series to increase the pressure rise with passive microvalves and piezoelectric unimorph diaphragms. This research was conducted through modeling, simulation, design, and fabrication of the microcompressor and its components. A single-stage and a two-stage microcompressor were developed to demonstrate and compare the performance and effectiveness of using a cascaded multistage design.

Steady fluid flow through static microvalves structure was studied to gain insight on its gas flow dynamics and characteristics. Transient analysis combined with the structure's interaction was investigated with an analytical model …

Unmanned Vehicles Formation Control In 3d Space And Cooperative Search, Saba Ramazani

Doctoral Dissertations

The first problem considered in this dissertation is the decentralized non-planar formation control of multiple unmanned vehicles using graph rigidity. The three-dimensional formation control problem consists of n vehicles operating in a plane Q and r vehicles that operate in an upper layer outside of the plane Q. This can be referred to as a layered formation control where the objective is for all vehicles to cooperatively acquire a predefined formation shape using a decentralized control law. The proposed control strategy is based on regulating the inter-vehicle distances and uses backstepping and Lyapunov approaches. Three different models, with increasing …

Energy Harvesting Using Photovoltaic And Betavoltaic Devices, Ashish Sharma

Doctoral Dissertations

There is an important need for improvement in both cost and efficiency of photovoltaic cells. For improved efficiency, a better understanding of solar cell performance is required. An analytical model of thin-film silicon solar cell, which can provide an intuitive understanding of the effect of illumination on its charge carriers and electric current, is proposed. The separate cases of homogeneous and inhomogeneous charge carrier generation rates across the device are investigated. This model also provides for the study of the charge carrier transport within the quasi-neutral and depletion regions of the device, which is of an importance for thin-film solar …

Diamond Mems Biosensors: Development And Applications, Wenli Zhang

Doctoral Dissertations

This research focuses on the development a dielectrophoresis-enhanced microfluidic impedance biosensor (DEP-e-MIB) to enable fast response, real-time, label-free, and highly sensitive sensor for bacterial detection in clinical sample. The proposed design consists of application of dielectrophoresis (DEP) across a microfluidic channel to one of the impedance spectroscopy electrodes in order to improve the existent bacterial detection limits with impedance spectroscopy. In order to realize such a design, choice of electrode material with a wide electrochemical potential window for water is very important. Conventional electrode material, such as gold, are typically insulated for the application of DEP, and they fail when …

Intrusion Detection System Of Industrial Control Networks Using Network Telemetry, Stanislav Ponomarev

Doctoral Dissertations

Industrial Control Systems (ICSs) are designed, implemented, and deployed in most major spheres of production, business, and entertainment. ICSs are commonly split into two subsystems - Programmable Logic Controllers (PLCs) and Supervisory Control And Data Acquisition (SCADA) systems - to achieve high safety, allow engineers to observe states of an ICS, and perform various configuration updates. Before wide adoption of the Internet, ICSs used "air-gap" security measures, where the ICS network was isolated from other networks, including the Internet, by a physical disconnect [1]. This level of security allowed ICS protocol designers to concentrate on the availability and safety of …

Quartz-Mems: Wet Chemical Etching Assisted By Electromagnetic Energy Sources For The Development Of Quartz Crystal To Be Used For Microelectromechanical Systems, William J. Clower

Doctoral Dissertations

Quartz crystal resonators have been the most commonly used timing devices to date. Today's timing market requires devices to be as small as possible and consume smaller amounts of energy. Because of the market demand, many startup companies have formed to develop silicon resonators as timing devices. Silicon resonators have poor noise and temperature performance (due to its linear temperature versus frequency coefficient). At the moment the only advantage that silicon resonators have over quartz crystal resonators is a small form factor. The photolithography processing method currently being used in industry is a very tedious task, requiring multiple etching steps …

Quantum Levitation Using Metamaterials, Venkatesh K. Pappakrishnan

Doctoral Dissertations

The emergence of an attractive vacuum force (Casimir force) between two purely dielectric materials can lead to an increase in the friction and the stiction effects in nanoscale devices, resulting in degradation or decreased performance. Thus, it is of high practical importance that the conditions for the reversal of the Casimir force from attractive to repulsive are identified. Although the repulsive Casimir force has been considered for high dielectric materials as an intermediate (between the plates) medium, so far no realistic system has been proposed that can demonstrate quantum levitation with air/vacuum as a host medium. Since air is the …

On Electromagnetic And Quantum Invisibility, Pattabhiraju Chowdary Mundru

Doctoral Dissertations

The principle objective of this dissertation is to investigate the fundamental properties of electromagnetic wave interactions with artificially fabricated materials i.e., metamaterials for application in advanced stealth technology called electromagnetic cloaking. The main goal is to theoretically design a metamaterial shell around an object that completely eliminates the dipolar and higher order multipolar scattering, thus making the object invisible.

In this context, we developed a quasi-effective medium theory that determines the optical properties of multi-layered-composites beyond the quasi-static limit. The proposed theory exactly reproduces the far-field scattering/extinction cross sections through an iterative process in which mode-dependent quasi-effective impedances of the …

Hybrid Nanomaterial And Its Applications: Ir Sensing And Energy Harvesting, Yi-Hsuan Tseng

Doctoral Dissertations

In this dissertation, a hybrid nanomaterial, single-wall carbon nanotubes-copper sulfide nanoparticles (SWNTs-CuS NPs), was synthesized and its properties were analyzed. Due to its unique optical and thermal properties, the hybrid nanomaterial exhibited great potential for infrared (IR) sensing and energy harvesting.

The hybrid nanomaterial was synthesized with the non-covalent bond technique to functionalize the surface of the SWNTs and bind the CuS nanoparticles on the surface of the SWNTs. For testing and analyzing the hybrid nanomaterial, SWNTs-CuS nanoparticles were formed as a thin film structure using the vacuum filtration method. Two conductive wires were bound on the ends of the …

A Knowledge Discovery Approach For The Detection Of Power Grid State Variable Attacks, Nathan Wallace

Doctoral Dissertations

As the level of sophistication in power system technologies increases, the amount of system state parameters being recorded also increases. This data not only provides an opportunity for monitoring and diagnostics of a power system, but it also creates an environment wherein security can be maintained. Being able to extract relevant information from this pool of data is one of the key challenges still yet to be obtained in the smart grid. The potential exists for the creation of innovative power grid cybersecurity applications, which harness the information gained from advanced analytics. Such analytics can be based on the extraction …

An Integrated Plasma Spectroscopic And Capacitive Sensing Platform For Water Quality Diagnostics, John William Sweeney

Doctoral Dissertations

Even in modern times, the consumption of polluted water continues to inflict tremendous suffering on millions of people worldwide that is largely preventable with adequate sanitation practices, routine water quality diagnostics, and treatment. However, conventional water quality monitoring practices remain a time consuming endeavor, where water samples collected on-site are transported to off-site laboratories for evaluation with laboratory-scale chemical analysis devices. While considerable efforts have been made to miniaturize these devices for in-field use, many of the devices reported in the literature provide an incomplete assessment of a water contaminant's environmental impact by focusing on identifying its chemical composition and …

Position-Adaptive Localization Of An Electro-Magnetic Source Using Static And Mobile Wireless Sensor Networks, Miguel D. Gates

Doctoral Dissertations

We present new results in detection and localization of a hidden emitter using Wireless Sensor Networks (WSNs). While this type of problem has been explored extensively, this research combines multiple dynamics, such as mobility and adaptation, to extend the value beyond the typical search mission. Using Micro-Aerial Vehicles (MAVs), in conjunction with multiple static wireless sensor nodes, we create a hybrid sensor network capable of detection and localization of a hidden electro-magnetic (EM) emitter.

In order to localize the emitter, a Received Signal Strength Indicator (RSSI) is used as an approximation of distance from the transmitter to the revolving receivers. …

Unmanned Ground Vehicle Navigation And Coverage Hole Patching In Wireless Sensor Networks, Guyu Zhang

Doctoral Dissertations

This dissertation presents a study of an Unmanned Ground Vehicle (UGV) navigation and coverage hole patching in coordinate-free and localization-free Wireless Sensor Networks (WSNs). Navigation and coverage maintenance are related problems since coverage hole patching requires effective navigation in the sensor network environment. A coordinate-free and localization-free WSN that is deployed in an ad-hoc fashion and does not assume the availability of GPS information is considered. The system considered is decentralized and can be self-organized in an event-driven manner where no central controller or global map is required.

A single-UGV, single-destination navigation problem is addressed first. The UGV is equipped …

A Nanostructured Fabry-Perot Interferometer For Label-Free Biodetection, Tianhua Zhang

Doctoral Dissertations

A polymer nanostructured Fabry-Perot interferometer (FPI) based biosensor has been developed, fabricated, and tested. Different from a conventional FPI, this nanostructured FPI has a layer of Au-coated nanopores inside its cavity. The Au-coated nanostructure layer offers significant enhancement of optical transducing signals due to the localized surface Plasmon resonance (L-SPR) effect. Compared to a traditional FPI for label-free biosensing applications, the polymer nanostructured FPI based biosensor offers increased sensing surface area, extended penetration depth of the excitation light, and amplification of optical transducing signals. Using a nanostructured FPI, measurements taken had great improvements in free spectral range (FSR), finesse, and …

Nanowire Giant Magnetoresistance Thin Films For Magnetic Sensors, Bryan Cox

Doctoral Dissertations

This dissertation details a novel method to fabricate magnetic sensors using nanowire giant magnetoresistance (GMR) thin films. In 1988, Albert Fert and Peter Grünberg both independently discovered a new physical phenomenon called GMR. GMR is a quantum mechanical effect found in thin film materials that are composed of alternating nanoscale ferromagnetic and non-magnetic conductive layers. When a GMR material is in the presence of a magnetic field, a change in electrical resistance is observed. The GMR effect has been utilized to produce magnetic sensors that have been used in a variety of applications, such as computer hard drive read heads, …

Numerical Simulation Of Nanopulse Penetration Of Biological Matter Using The Adi-Fdtd Method, Fei Zhu

Doctoral Dissertations

Nanopulses are ultra-wide-band (UWB) electromagnetic pulses with pulse duration of only a few nanoseconds and electric field amplitudes greater than 105 V/m. They have been widely used in the development of new technologies in the field of medicine. Therefore, the study of the nanopulse bioeffects is important to ensure the appropriate application with nanopulses in biomedical and biotechnological settings. The conventional finite-difference time-domain (FDTD) method for solving Maxwell's equations has been proven to be an effective method to solve the problems related to electromagnetism. However, its application is restricted by the Courant, Friedrichs, and Lewy (CFL) stability condition that confines …

Fabrication And Characterization Of Hybrid Energy Harvesting Microdevices, Zhongcheng Gong

Doctoral Dissertations

In this dissertation, a hybrid energy harvesting system based on a lead zirconate titanate (PZT) and carbon nanotube film (CNF) cantilever structure has been designed, fabricated and studied. It has the ability to harvest light and thermal radiation energy from ambient energy and convert them to electricity.

The proposed micro-scale energy harvesting device consists of a composite cantilever beam (SU-8/CNF/Pt/PZT/Pt) which is fixed on a silicon based anchor and two electrode pads for wire bonding. The CNF acts as an antenna to receive radiation energy and convert it to heat energy and then transfer to the whole cantilever structure. The …

Basic Capillary Microfluidic Chip And Highly Sensitive Optical Detector For Point Of Care Application, Mingjin Yao

Doctoral Dissertations

A cost-effective and highly sensitive portable diagnostic device is needed to enable much more widespread monitoring of health conditions in disease prevention, detection, and control. Miniaturized and easy-to-operate devices can reduce the inherent costs and inefficiencies associated with healthcare testing in central laboratories. Hence, clinicians are beginning to use point of care (POC) testing and flexible clinical chemistry testing devices which are beneficial for the patient.

In our work, a low-cost and simple autonomous microfluidic device for biochemical detection was developed. The pumpless capillary system with capillary stop valves and trigger valves is fabricated on a silicon (Si) wafer and …

Passive Micromixers And Organic Electrochemical Transistors For Biosensor Applications, Senaka Krishna Kanakamedala

Doctoral Dissertations

Fluid handling at the microscale has greatly affected different fields such as biomedical, pharmaceutical, biochemical engineering and environmental monitoring due to its reduced reagent consumption, portability, high throughput, lower hardware cost and shorter analysis time compared to large devices. The challenges associated with mixing of fluids in microscale enabled us in designing, simulating, fabricating and characterizing various micromixers on silicon and flexible polyester substrates. The mixing efficiency was evaluated by injecting the fluids through the two inlets and collecting the sample at outlet. The images collected from the microscope were analyzed, and the absorbance of the color product at the …

Introducing Porous Silicon As A Sacrificial Material To Obtain Cavities In Substrate Of Soi Wafers And A Getter Material For Mems Devices, Wajihuddin Mohammad

Doctoral Dissertations

Microelectromechanical system (MEMS) resonators have been a subject of research for more than four decades. The reason is the huge potential they possess for frequency applications. The use of a MEMS resonator as the timing element has an experimental history and huge progress has been made in this direction. Vacuum encapsulated MEMS resonators are required for high precision frequency control. Hence, a device with a high quality factor and durability is needed. In this effort, a new process for producing a cavity in the substrate of Silicon on insulator (SOI) MEMS devices and augmenting it with a getter using porous …