Engineering Commons^™

Liquid Phase Nano Metal Catalyzed Dechlorination Of Chlorinated Organic Compounds, Omneya El-Sharnouby

Electronic Thesis and Dissertation Repository

1,2-Dichloroethane (1,2-DCA) is among the most prevalent groundwater chlorinated organic compounds (COCs) found at hazardous sites throughout the world. Given its pervasive contamination and adverse health effects, there is considerable interest in developing novel remediation technologies for successfully treating 1,2-DCA along with other COCs from water sources. Chemical reduction by nano zero valent iron (monometallic (nZVI) or bimetallic (Pd-nZVI)) has proven to be a successful field applicable technology, yet it has failed in degrading such a recalcitrant compound as 1,2-DCA.

In this study, the development of a field applicable nano metal based technology capable of degrading 1,2-DCA was carried out. …

Novel Approaches For Assessment Of Copper Toxicity: Fast Scan Cyclic Voltammetry And Optical Bioassays, Annette R. Tremonti

Wayne State University Dissertations

Anthropogenic activities negatively impact fresh water ecosystems through toxic contaminants that are released into the environment. Copper (Cu) is a water contaminant that is fundamentally persistent once introduced into the environment that has the potential for bioaccumulation. Although Cu toxicity has been studied for decades, there is still a continuing problem with new sources and pathways. New approaches are needed to understand distribution and transport of Cu and its potential for complex biological impacts beyond the simple assessment of lethality. Several novel approaches were used in this research project to advance our understanding of Cu toxicity, including fast scan cyclic …

Designing A Permeable Reactive Barrier For The Remediation Of Copper Contaminated Groundwater., Christopher Walkons

Dissertations, Master's Theses and Master's Reports

This project details the design of a sorption based pilot-scale permeable reactive barrier (PRB) for the removal of copper from groundwater. The reactive material for the barrier is the residual of coagulants used in drinking water treatment operations. Physical and chemical properties of these water treatment residuals (WTR) have been studied to optimize PRB design. Batch reactor tests have shown that equilibrium sorption of copper can be fit to a Langmuir type isotherm. Kinetic and column experiments have been conducted to understand the significance of chemical and physical mass transfer limitations. A leaching test indicated the concentrations of hazardous elements …

Removal Of Iron, Zinc, And Copper From Waters Impacted By Acid Mine Drainage Using Natural Zeolite, Mackayla Janae Thyfault

Open Access Theses & Dissertations

In this research, the adsorption behavior of zeolites with respect to iron (Fe), zinc (Zn), and copper (Cu) has been studied in order to assess its application to heavy metal removal in polluted settings caused by acid mine drainage (AMD). The St. Cloud zeolitic deposit used in this project was characterized using a sieve analysis; the effective diameter and coefficient of uniformity were calculated. Batch studies were performed, and the samples were analyzed using ICP-OES. Batch studies used metal concentrations ranging from 50 mg/L to 650 mg/L. Freundlich, Linear, Langmuir, and BET adsorption isotherms were applied and evaluated to the …

Functional Characterization Of Green Sorption Media And Scaling Of Pilot Studies For Copper Removal In Stormwater Runoff, Cameron Houmann

Electronic Theses and Dissertations

Green adsorption media with the inclusion of renewable and recycled materials can be applied as a stormwater best management practice for copper removal. A green adsorption media mixture composed of recycled tire chunk, expanded clay aggregate, and coconut coir was physicochemically evaluated for its potential use in an upflow media filter. The results found that the use of the green adsorption media mixture in isolation or the coconut coir with an expanded clay filtration chamber could be an effective and reliable stormwater best management practice for copper removal. A suite of tests were conducted on the media mixture and the …

Evaluation Of Point Of Use Drinking Water Treatment Systems For Colonias In The Southwest United States, Isaac Campos Flores

Open Access Theses & Dissertations

Clean drinking water is often taken for granted in first world countries, such as the United States. However, thousands of colonias residents (settlements in the Southwest US that lack access to basic infrastructure) still lack access to clean drinking water. Such is the case in the Paso Del Norte Region. In Doña Ana County, NM, and El Paso County, TX, colonia residents typically rely on shallow domestic wells and hauled water, respectively. However, both water sources can pose health concerns from elevated total dissolved solids and microbiological contamination. With connection to centralized water treatment and distribution still years away, colonias …

Chemophysical Characteristics And Application Of Biosorption Activated Media (Bam) For Copper And Nutrient Removal In Stormwater Management, Jamie Jones

Electronic Theses and Dissertations

For high groundwater table areas, stormwater wet detention ponds are utilized as the preferred stormwater management throughout the state of Florida. Previous research has found that accumulations of nutrients, algae, heavy metals, pesticides, chlorophyll a, fecal coliform bacteria and low concentrations of dissolved oxygen (DO) are common characteristics of stormwater wet detention ponds. Although these pollutant levels are not regulated within the ponds, states are required to compute the pollutant load reductions through total maximum daily load (TMDL) programs to meet the water quality requirements addressed by the Clean Water Act (CWA). In this study, field sampling data of stormwater …

Detecting Copper Residues In Sediments From Aquatic Copper-Based Pesticide Applications, Ben Willis

All Theses

Copper-based algaecides and herbicides are commonly used to mitigate risks of problematic algae and weeds, however there are concerns regarding copper accumulation from treatments. Modeling and laboratory experiments can be used to predict copper accumulation and measurement in sediments, as well as benthic invertebrate responses following treatments. Modeling was used to estimate copper residual concentrations in sediments from algaecide and herbicide treatments. Reported and measured method detection limits (MDLs; minimum concentration of an analyte of interest that can be measured with 99 percent confidence in a specific matrix using an analytical method) were compared to model estimated copper residual concentrations …

Voltammetric Study Of Interaction Of Copper And Model Fungal Secreted Ligands, Ran Liu

Electronic Theses and Dissertations

In lieu of Abstract, excerpt from Conclusion of Voltammetric Study of Interaction of Copper and Model Fungal Secreted Ligands: In summary, the cyclic voltammetry study shows evidence that the chelatormediated Fenton reaction is favored in the wood cell wall, where it may promote the degradation process. Also, reaction mechanisms between Cu(II), 2,3-DHBA and H202 have been proposed which provide at least partial explanations for the H202 cycle, and the mechanism for non-enzymatic, chelator-mediated Fenton reactions in brown rot wood decay processes. Future research in this area should explore cyclic voltarnrnetry analyses of Cu(I1) and ligands secreted by fungi, such as …

Effects Of Heavy Metals (Cadmium, Copper, And Mercury) On Reproduction, Growth, And Survival Of Brine Shrimp (Artemia Salina) From The Great Salt Lake, Karl A. Gebhardt

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this paper is to report findings concerning the effects of cadmium, copper, and mercury on the brine shrimp Artemia Salina, of the Great Salt Lake. Metal toxicity was observed in relation to acute susceptibility, growth, reproduction, and hatching of the brine shrimp.

Heavy metal concentrations such as cadmium, copper, and mercury are known to be considerably higher in the Great Salt Lake than those in both freshwater and seawater. No published study has been concerned with heavy metal effects on organisms in salinities greater than seawater (35 grams per liter total dissolved solids). The experiments reported …

Effect Of Recovery On The Recrystallized Grain-Size Of High Purity Aluminum, Rodney L. Helterline

Bachelors Theses and Reports, 1928 - 1970

When a cold-worked metal is annealed, it’s physical properties hange as a result of a new grain structure. The annealing treatment is divided into three stages according to the changes that occur in the distorted metal: (1) recovery, (2) recrystallization, and (3) grain growth.

The Application Of Electric Energy To The Metallurgy Plants In Montana, Edwin J. Duncan

Bachelors Theses and Reports, 1928 - 1970

Since the year 1800, metallurgy has been affiliated with electricity. In fact, the two industries have grown side by side, being naturally dependent upon each other and having a parallel growth.

The Construction And Operation Of A Universal Specimen Mount With Protective Lead Shield For The Purpose Of Determining Pole Figures Using The Schulz-Decker Transmission Technique, Richard L. Fausner

Bachelors Theses and Reports, 1928 - 1970

It was the purpose of this study to construct a universal mount, to construct a protective lead shield, to operate the instrument, and to provide a pole figure using the transmission method of Schulz and Decker. There are at present several lengthy x-ray methods of determining the grain orientation of metals. These methods are mainly photographic. In order to provide a rapid means of obtaining the necessary information concerning the grain orientation of a metal, a universal mount was constructed.

Host Rocks And Gangue Minerals Associated With Copper Deposits In Plutonic Igneous Rocks, Richard D. Montgomery

Bachelors Theses and Reports, 1928 - 1970

All of the information on the various districts has come directly from published reports. The investigation was suggested by Mr. Forbes Robertson. The geographical extent of the deposits was confined to the western United States. Many of these deposits are of the disseminated porphyry type. A few of the de­posits, such as at Butte, Montana, were of the fissure vein type.

The Effect Of Manganese On The Age Hardening Of Aluminum-Copper Alloys, Keith P. Burgess

Bachelors Theses and Reports, 1928 - 1970

It is known that age-hardening occurs in alloys of the solid solution type containing a hardening constituent, of a metal or metallic compound which is more soluble in the solvent phase at higher tempertures than at lower temperatures.

The Benefication Of A Low-Grade, Montana Scheelite Ore, Walter G. Parker

Bachelors Theses and Reports, 1928 - 1970

The increasing importance of tungsten as an industrial metal and the recent discoveries of extensive deposits of low-grade tungsten ores in Montana led to the investigation which is reported in this paper. The purpose of this investigation was to determine if a saleable concentrate could be obtained from one of these low-grade, Montana scheelite ores.

Variation Of Induction And Hysteresis Curves For The Heusler Alloy, Cu2mna1, Ford W. Knight

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the fundamental magnetic characteristics of induction and hysteresis, for the alloy Cu₂MnAl. This is a ternary, ferromagnetic Heusler alloy. The problem is not only to determine these characteristics for the alloy as-cast but to heat treat it and observe the manner in which different heat treat­ments affect these two fundamental magnetic characteristics.

The Effect Of Ferric Iron Upon The Current Efficiency And The Deposition Of Copper In The Electrowinning Of Copper From Copper Sulphate Solutions, James L. Owings

Bachelors Theses and Reports, 1928 - 1970

In the hydrometallurgy of copper, probably the most widely used method for the precipitation of copper is by electrolysis using insoluble anodes. The process is similar in many respects to the electrolytic refining of copper; one of the main differences is the use of insoluble anodes in electrowinning as compared to the use of impure copper anodes in electrorefining. Impurities, however, are common to both processes. The nature of these impurities differ and the problem of purifying the electrolyte is also different.

The Effect Of Iron Upon The Electrowinning Of Copper With An Amalgam Electrode, John A. Alexander

Bachelors Theses and Reports, 1928 - 1970

Current commercial use of the mercury cathode cell is limited to two types of electrolytic sodium cells-­the Castner cell and the Sorenson cell. Mercury as a cathode medium has also found application in polarographic analysis, a method of a simultaneous quantitative and qualitative analysis of several metal components of solution.

An Investigation Of The Hardening Properties Of Some Alpha Copper Indium Alloys, Charles W. Mcpherson

Bachelors Theses and Reports, 1928 - 1970

Precipitation hardening alloys has assumed a major role in modern da^y development of alloys. In his search for stronger, harder materials, the metallurgist has often been limited by the cost of metals which posses the needed properties.

The Electrolytic Purification Of An Impure Cadmium Sulfate Solution With A Cell Utilizing A Mercury Cathode And A Lead Anode, W. D. Mcmaster

Bachelors Theses and Reports, 1928 - 1970

Cadmium is produced solely as a by-product and all cadmium of commerce is obtained from zinc ores. It is a rare occurrence when zinc deposits are found which do not contain some cadmium.

Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson

Bachelors Theses and Reports, 1928 - 1970

The polarograph has been applied to a large number of chemical and metallurgical analyses, and is especially applicable to solution control analysis and to the deter­mination of minute quantities of ions in the presence of large amounts of other ions.

Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson

Bachelors Theses and Reports, 1928 - 1970

The term "vacuum distillation" is used to des­cribe the process employed when certain elements are separated either from their mother compounds or from one another by distilling them under reduced atmos­pheric pressure.

Ferromagnetic Alloys In The System Cu-Mn-Zn, W. Michael Yim

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine whether ferromagnetic alloys exist in the ternary sys­tem Cu-Mn-Zn analogous to the other Heusler alloys. The work in this thesis is a preliminary investi­gation on these alloys using a common metallographic re­search technique and augmented with X-ray methods.

Mineralization Of The Bonanza Mine, H. M. Callaway

Bachelors Theses and Reports, 1928 - 1970

The Bonanza mine of the Emery mining district in Powell County is on the largest veins in the area, and is developed to a depth of 680 feet by an incline shaft following the dip of the structure. Sulfide ores carrying gold and silver values are mined throughout the area which is easily accessible by road from Deerlodge, Montana, ten miles west of the district.

An Investigation Into The Precipitation Of Copper From Mine Water By Cupric Copper Reduction, And The Subsequent Precipitation Of Copper As Cuprous Chloride, Jack T. Gentry

Bachelors Theses and Reports, 1928 - 1970

The objective of this thesis is to determine the possibility of applying a different method to the re­covery of the copper dissolved in the Butte mine waters, and thereby precipitate a purer cement copper with greater efficiency and less iron consumption.

A Study Of The Differential Seperation Of Galena And Sphalerite, Wilfred E. Nagel

Bachelors Theses and Reports, 1928 - 1970

The smelting of complex lead ores is a difficult operation, especially when they contain considerable amounts of iron and zinc. When these ores are smelted, all of the zinc, which is valuable and well worth recovering, goes into the slag. With the advent of the flotation processes, and the ability of these processes to concentrate the lead and zinc minerals into separate products, the smelting of complex lead ores was to a great extent simplified.

Separation Of Cadmium From Zinc In The Purification Step Of The Leaching Cycle, L. C. Powell

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the effect of the factors listed previously by conducting a series of tests that will indicate the ex­tent to which the purification is influenced by time, temperature, zinc oust size, zinc dust quantity, iron concentration, two stage precipitation, and aeration.

A Mineral Dressing And Economic Study Of A Complex Arsenical Ore, Luigi D. Piana

Bachelors Theses and Reports, 1928 - 1970

The factors that influence the choice of a method for treat­ment of an ore comprise the technical and economic limitations and advantages, derived in detail and balanced according to the exigencies of the particular situation.

An Investigation Of The Precipitation Of Cobalt With Zinc Dust, Lyle Hallberg

Bachelors Theses and Reports, 1928 - 1970

Cobalt, as well as copper, cadmium, and other impurities, is removed by selective precipitation with zinc during the zinc electrolyte purification cycle, and the purification residue may be treated by a Cadmium Plant for the recovery of cadmium.