Engineering Commons^™

Environmental And Energy Saving Technologies Of Vinyl Chloride Production, Mykola Kurta

USF Tampa Graduate Theses and Dissertations

Recently, because of the increase of environmental concerns in process design, the need to enhance conversion to product and prevent generation of wasteful byproducts in the reactor network has become urgent. This prevents high cost treatment and separation costs downstream in the process. Therefore, in this thesis I focus on making production of vinyl chloride monomer (VCM) more efficient and on possible ways of industrial organochlorine waste (OCW) recycling. In particular, in the first experiment, we investigate how catalyst and its structure can affect product output.

Infrared spectroscopy and X-ray diffraction analysis were utilized to investigate the structure of the …

Socioeconomic Factors' And Water Source Features' Effect On Household Water Supply Choices In Uganda And The Associated Environmental Impacts, Christine M. Prouty

USF Tampa Graduate Theses and Dissertations

Over the last twenty years or more, Uganda has benefitted from significant strides in water and sanitation initiated by the United Nations' Millennium Development Goals. While the rapid progress towards development has been vastly beneficial, it is also important that it does not occur at the expense of the environment. The environmental impacts of these water sources must be evaluated and understood. However, to develop a robust understanding of the impact requires inclusion of the community members who use these sources and their perceptions of them. Consequently, the goal of this research is to investigate the interrelationships between socioeconomic factors, …

Environmental Implications Of Pavements: A Life Cycle View, Bin Yu

USF Tampa Graduate Theses and Dissertations

Environmental aspect of pavement, unlike its economic counterpart, is seldom considered in the theoretical study and field practices. As a highly energy and material intensive infrastructure, pavement has great potential to contribute to the environment protection, which, in root, depends on the in-depth understanding of the environmental impacts, holistically and specifically. A life cycle assessment (LCA) model is used to fulfill the goal.

This research firstly carried out extensive literature review of LCA studies on pavement to identify the major research gaps, including: incompleteness of the methodology, controversy of the functional unit, and unawareness of feedstock energy of asphalt, etc. …

Towards Rans Parameterization Of Vertical Mixing By Langmuir Turbulence In Shallow Coastal Shelves, Nityanand Sinha

USF Tampa Graduate Theses and Dissertations

Langmuir turbulence in the upper ocean is generated by the interaction between the wind-driven shear current and the Stokes drift velocity induced by surface gravity waves. In homogenous (neutrally stratified) shallow water, the largest scales of Langmuir turbulence are characterized by full-depth Langmuir circulation (LC). LC consists of parallel counter-rotating vortices aligned roughly in the direction of the wind. In shallow coastal shelves, LC has been observed engulfing the entire water column, interacting with the boundary layer and serving as an important mechanism for sediment re-suspension.

In this research, large-eddy simulations (LES) of Langmuir turbulence with full-depth LC in a …

Effect Of Cement Chemistry And Properties On Activation Energy, Andre J. Bien-Aime

USF Tampa Graduate Theses and Dissertations

The objective of this work is to examine the effect of cement chemistry and physical properties on activation energy. Research efforts indicated that time dependent concrete properties such as strength, heat evolution, and thermal cracking are predictable through the concept of activation energy. Equivalent age concept, which uses the activation energy is key to such predictions. Furthermore, research has shown that Portland cement concrete properties are affected by particles size distribution, Blaine fineness, mineralogy and chemical composition. In this study, four Portland cements were used to evaluate different methods of activation energy determination based on strength and heat of hydration …

Risk Assessment Of Driving Safety In Long Scaled Bridge Under Severe Weather Conditions, Shengdi Chen

USF Tampa Graduate Theses and Dissertations

Weather conditions have certain impacts on roadway traffic operations, especially traffic safety. Bridges differ from most surface streets and highways in terms of their physical properties and operational characteristics. This research assess the driving risk under different weather conditions through focus group firstly, then it develops a multi-ordered discrete choice model that is used to analyze and evaluate driving risks under both single and dual weather conditions. The data is derived from an extensive questionnaire survey in Shanghai. And the questionnaire includes those factors related to roadway, drivers, vehicles, and traffic that may have significant impacts on traffic safety under …

Optimized Correlation Of Geophysical And Geotechnical Methods In Sinkhole Investigations: Emphasizing On Spatial Variations In West-Central Florida, Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

Abstract

Sinkholes and sinkhole-related features in West-Central Florida (WCF) are commonly identified using geotechnical investigations such as standard penetration test (SPT) borings and geophysical methods such as ground penetrating radar (GPR) and electrical resistivity tomography (ERT). Geophysical investigation results can be used to locate drilling and field testing sites while geotechnical investigation can be used to ground truth geophysical results. Both methods can yield complementary information. Geotechnical investigations give important information about the type of soil, groundwater level and presence of low-density soils or voids at the test location, while geophysical investigations like GPR surveys have better spatial coverage and …

Assessing Appropriate Technology Handwashing Stations In Mali, West Africa, Colleen Claire Naughton

USF Tampa Graduate Theses and Dissertations

Proper hand hygiene is the most effective and efficient method to prevent over 1.3 million deaths annually from diarrheal disease and Acute Respiratory Infections (ARIs). Hand hygiene is also indispensable in achieving the fourth Millennium Development Goal (MDG) to reduce the childhood mortality rate by 2/3rds between 1990 and 2015. Handwashing has been found in a systematic review of studies to reduce diarrhea by 47%#37; and is, thus, capable of preventing a million deaths (Curtis et. al., 2003). Despite this evidence, hand washing rates remain seriously low in the developing world (Scott et al., 2008).

This study developed and implemented …

Investigation Of Mercury Use, Release, Deposition, And Exposures In The Tampa Bay Area, Ryan Algernon Michael

USF Tampa Graduate Theses and Dissertations

I investigate the links between mercury use, release, deposition, and population exposure in Tampa Bay, with the focus of identifying levers for reducing population mercury exposures. To achieve this, I investigated the trends in mercury use and release by products and processes in the Tampa Bay area using a Material Flow Analysis. Analysis of USEPA National Emissions Inventory data over time (1999 - 2008) identified relevant air source emission categories, and explored and compared state and regional trends in mercury emissions. To understand source contributions to wet deposited mercury in the Tampa Bay area, I analyzed trends in mercury deposition …

Corrosion Of Post-Tensioning Strands In Ungrouted Ducts - Unstressed Condition, Michael John Hutchison

USF Tampa Graduate Theses and Dissertations

Recent failures and severe corrosion distress of post-tensioned (PT) bridges in Florida have revealed corrosion of the 7-wire strands in tendons. Post-tensioned duct assemblies are fitted with multiple 7-wire steel strands and ducts are subsequently filled with grout. During construction, the length of time from the moment in which the strands have been inserted into the ducts, until the ducts are grouted, is referred to as the `ungrouted' period. During this phase, the steel strands are vulnerable to corrosion and consequently the length of this period is restricted (typically to 7 days) by construction guidelines. This investigation focuses on determining …

Prediction Of The Performance Of A Flexible Footing On A Stone-Column Modified Subgrade, Justin Callahan

USF Tampa Graduate Theses and Dissertations

When foundations are designed on weak clay layers, it is a common practice to modify the subgrade by installing stone columns. Currently used methods for determining the level of ground modification, represented by the percentage of soil replaced (replacement ratio), assume a rigid foundation. These analytical methods provide the designer with the potential settlement reduction based on the compressibility parameters of the subgrade and the replacement ratio. The deficiencies of these methods are the assumption of rigidity of the foundation and the consideration of the settlement reduction as the only design criterion. Furthermore, they do not consider the effects that …

Modeling And Design Of Photocatalytic Reactors For Air Purification, Yangyang Zhang

USF Tampa Graduate Theses and Dissertations

Photocatalysis is a promising technique for the remediation of indoor air pollution. Photocatalysis utilizes semiconductor photocatalysts (such as TiO₂ or ZnO) and appropriate light to produce strong oxidizing agents (OH*) that are able to break down organic compounds and inactivate bacteria and viruses. The overall goal of the research is to develop an efficient photocatalytic reactor based on mass transfer for indoor air purification. This study has focused on the enhancement of the effectiveness of the photocatalytic process by the introduction of artificial roughness on the reactor catalyst surface. The major effect of artificial roughness elements on the catalytic …

Time Scale Of Groundwater Recharge: A Generalized Modeling Technique, Makhan Virdi

USF Tampa Graduate Theses and Dissertations

Estimating the quantity of water that reaches the water table following an infiltration event is vital for modeling and management of water resources. Estimating the time scale of groundwater recharge after a rainfall event is difficult because of the dependence on nonlinear soil characteristics and variability in antecedent conditions. Modeling the flow of water through the variably saturated zone is computationally intensive since it requires simulation of Richards' equation, a nonlinear partial differential equation without a closed-form analytical solution, with parametric relationships that are difficult to approximate. Hence, regional scale coupled (surface water - groundwater) hydrological models make simplistic assumptions …

Evaluation Of A Pilot Land-Based Marine Integrated Aquaculture System, Suzanne Boxman

USF Tampa Graduate Theses and Dissertations

Recirculating aquaculture systems (RAS) produce aquaculture products on land with minimal discharge of waste products and minimal water loss. High costs associated with waste treatment for RAS have triggered the growth of integrated aquaculture systems (IAS) which incorporate macrophytes (aquatic plants) into the treatment train. The objective of this research was to examine a pilot scale inland marine IAS with three different methods for solids treatment: a sand filter followed by a plant bed, only a plant bed, and geotextile bags. Florida Pompano (Trachinotus carolinus) were grown along with Smooth Cordgrass (Spartina alterniflora), Black Needle Rush …

Community And Household Management Strategies For Water Supply And Treatment In Rural And Peri-Urban Areas In The Developing World, Ryan William Schweitzer

USF Tampa Graduate Theses and Dissertations

Eighty percent of the 780 million people worldwide that access water from an unimproved source live in rural areas. In rural areas, water systems are often managed by community based organizations and many of these systems do not provide service at the designed levels. The Sustainability Analysis Tool developed in Chapter 2 can inform decision making, characterize specific needs of rural communities in the management of their water systems, and identify weaknesses in training regimes or support mechanisms. The framework was tested on 61 statistically representative geographically stratified sample communities with rural water systems in the Dominican Republic. The results …

Improving Implementation Of A Regional In-Line Chlorinator In Rural Panama Through Development Of A Regionally Appropriate Field Guide, Benjamin A. Yoakum

USF Tampa Graduate Theses and Dissertations

Access to safe drinking water has a direct effect on improving human health and their quality of life. One country still struggling with providing access to safe drinking water to all of its population is Panama. Panama's largest indigenous group, the Ngöbe people, is disproportionately affected by lack of access to safe drinking water. One way Panama's Ministry of Health (MINSA) is attempting to increase access to safe drinking water to the Ngöbe people is by disinfecting the water already captured by rural gravity fed water systems constructed within in the Ngöbe-Bugle reservation. This is accomplished using an in-line chlorinator …

Geometric Optimization Of Retroreflective Raised Pavement Markers, Lukai Guo

USF Tampa Graduate Theses and Dissertations

As the field service life of retroreflective raised pavement marker (RRPM) is much shorter than expected, it is necessary to identify the causes and thus improve the RRPM structural design to mitigate the main failure modes, such as poor retention from pavements, structural damage, and loss of retroreflectivity. One strategy for extending RRPM service life is to enhance RRPM geometric characteristics to decrease critical stresses in markers. The main purpose of this thesis is to analyze the relationship between stresses, failure modes, and RRPM profiles. Based on this research, some measures are suggested in order to avoid corresponding failure modes …

A Study On Lane-Change Recognition Using Support Vector Machine, Weiping Deng

USF Tampa Graduate Theses and Dissertations

This research focuses primary on recognition of lane-change behaviors using support vector machines (SVMs). Previous research and statistical results show that the vast majority of motor vehicle accidents are caused by driver behavior and errors. Therefore, the interpretation and evaluation of driver behavior is important for road safety analysis and improvement. The main limit to understanding driver behavior is the data availability. In particular, a full-scale lane-change data set is difficult to collect in a real traffic environment because of the safety and cost issues. Considering the data demands of the recognition model development and the obstacles of field data …

Embodied Energy And Carbon Footprint Of Household Latrines In Rural Peru: The Impact Of Integrating Resource Recovery, Christopher M. Galvin

USF Tampa Graduate Theses and Dissertations

Over seventy percent of the 2.5 billion people who still lack access to basic sanitation worldwide live in rural areas (WHO/UNICEF, 2012). Despite concerns of water scarcity, resource depletion, and climate change little research has been conducted on the environmental sustainability of household sanitation technologies common in rural areas of developing countries or the potential of resource recovery to mitigate the environmental impacts of these systems. The environmental sustainability, in terms of embodied energy and carbon footprint, was analyzed for four household sanitation systems: (1) Ventilated Improved Pit (VIP) latrine, (2) pour-flush latrine, (3) composting latrine, and (4) biodigester latrine. …

Effect Of Localized Corrosion Of Steel On Chloride-Induced Concrete Cover Cracking In Reinforced Concrete Structures, Ezeddin Rafaa Busba

USF Tampa Graduate Theses and Dissertations

Abstract: Concrete cover cracking due to reinforcement corrosion is widely accepted as a limit-state indicator in defining the end of functional service life for existing reinforced concrete (RC) structures undergoing corrosion. Many of the currently available durability prediction models are incapable of providing realistic estimates of remaining service lives of RC structures beyond the corrosion initiation point. Therefore, the need to incorporate the length of the corrosion propagation stage in a comprehensive durability prediction approach has recently received much research attention. Previous research focus however was mostly limited to the case of uniformly corroding reinforcement with only few studies addressing …

Assessment Of A Modified Double Agar Layer Method To Detect Bacteriophage For Assessing The Potential Of Wastewater Reuse In Rural Bolivia, Sakira N. Hadley

USF Tampa Graduate Theses and Dissertations

Water scarcity is a global concern that impacts many developing countries, forcing people to depend on unclean water sources for domestic, agricultural, and industrial needs. Wastewater is an alternative water source that contains nutrients needed for crop growth. Wastewater reuse for agriculture can cause public health problems because of human exposure to pathogens. Pathogen monitoring is essential to evaluate the compliance of wastewater with established World Health Organization (WHO) and U.S. Environmental Protection Agency (EPA) wastewater reuse guidelines. Indicator organisms are commonly used to detect pathogens in water and wastewater because they are quick and easy to measure, non-pathogenic, and …

Modeling Nitrogen Transformations In A Pilot Scale Marine Integrated Aquaculture System, Brian Mccarthy

USF Tampa Graduate Theses and Dissertations

Integrated aquaculture systems (IAS) are a type of recirculating aquaculture systems (RAS) where the wastewater is treated and returned to the fish tanks. The important difference between the two is that in an IAS, wastes from the aquaculture component are recovered as fertilizer to produce an agricultural product whereas in an RAS, waste organics, nutrients and solids are treated and discharged. A pilot marine IAS at Mote Aquaculture Research Park in Sarasota, FL was studied for this project. Water quality monitoring, measurements of fish health and growth rates of fish and plants were performed over a two-year period to determine …

Flexible Urban Water Distribution Systems, Seneshaw Amare Tsegaye

USF Tampa Graduate Theses and Dissertations

With increasing global change pressures such as urbanization and climate change, cities of the future will experience difficulties in efficiently managing scarcer and less reliable water resources. However, projections of future global change pressures are plagued with uncertainties. This increases the difficulty in developing urban water systems that are adaptable to future uncertainty.

A major component of an urban water system is the distribution system, which constitutes approximately 80-85% of the total cost of the water supply system (Swamee and Sharma, 2008). Traditionally, water distribution systems (WDS) are designed using deterministic assumptions of main model input variables such as water …

Effects Of Solvent Composition And Hydrogen Pressure On The Catalytic Conversion Of 1,2,4,5-Tetrachlorobenzene To Cyclohexane, Margaret Elizabeth Cone

USF Tampa Graduate Theses and Dissertations

Halogenated hydrophobic organic compounds (HHOCs) such as 1,2,4,5-tetrachlorobenzene (TeCB) present a threat to both human health and the environment. The common occurrence and recalcitrant nature of HHOCs as soil contaminants necessitate an effective soil remediation method. Wee and Cunningham (2008, 2011, 2013) proposed a clean-up technology called Remedial Extraction and Catalytic Hydrodehalogenation (REACH), which pairs solvent extraction of HHOC contaminants from soil with catalytic hydrodehalogenation to destroy contaminants. Wee and Cunningham (2008, 2011, 2013) utilized a palladium (Pd) catalyst to hydrodehalogenate TeCB to benzene. However, benzene is still a toxic contaminant. Prior research has demonstrated that Pd-catalyzed hydrodehalogenation (HDH) can …

Spatial Transferability Of Activity-Based Travel Forecasting Models, Sujan Sikder

USF Tampa Graduate Theses and Dissertations

Spatial transferability of travel forecasting models, or the ability to transfer models from one geographical region to another, can potentially help in significant cost and time savings for regions that cannot invest in extensive data-collection and model-development procedures. This issue is particularly important in the context of tour-based/activity-based models whose development typically involves significant data inputs, skilled staff, and long production times. However, most literature on model transferability has been in the context of traditionally used trip-based models, particularly for linear regression-based trip generation and logit-based mode choice models, with little evidence on the transferability of activity-based models and that …

Kelvin Probe Electrode For Contactless Potential Measurement On Concrete-Properties And Applications, Michael Thomas Walsh

USF Tampa Graduate Theses and Dissertations

The practical feasibility of using a Kelvin Probe as a novel reference electrode in the measurement of both potential and polarization pulse response of reinforcing steel in concrete is demonstrated. Potential values measured using a KP reflect greater stability and repeatability than can typically be attained with conventional reference electrodes. Duplicate reinforced concrete beam test specimens with well-differentiated centrally corroding rebar segments were analyzed using both the Kelvin Probe (KP) and a conventional Saturated Calomel Electrode (SCE). Potential profile maps were developed using potential values recorded under static conditions with both the SCE and the KP. Nominal polarization resistance was …

Effect Of Solids Retention Time On The Denitrification Potential Of Anaerobically Digested Swine Waste, Maureen Njoki Kinyua

USF Tampa Graduate Theses and Dissertations

Three continuously stirred tank reactors (CSTR) were operated in semi continuous mode treating swine waste using anaerobic digestion. The reactors were used to test the effect of solid retention time (SRT) on CH4 yield, total ammonia nitrogen (TAN) concentrations, % volatile solids (VS), chemical oxygen demand (COD) and volatile fatty acids (VFA) removal, readily biodegradable COD concentration and the denitrification potential for the effluent in a biological nutrient removal (BNR) system. During Phase I of the study, the three reactors were operated at the same 28 day SRT for 16 weeks. SRTs were then changed during the 12 week Phase …

Evaluating Cfrp-Masonry Bond Using Thermal Imaging, Joseph Christopher Ross

USF Tampa Graduate Theses and Dissertations

This study presents results from non-destructive testing to evaluate the degradation of the CFRP-masonry bond using thermal imaging. The goal of the research was to identify locations where there was evidence of bond deterioration that could subsequently be verified through destructive pull-off testing.

Four full-scale masonry walls were built outdoors at the University of South Florida in 1995 to evaluate the effectiveness of CFRP for repairing settlement damage. Two of the settlement-damaged walls were repaired using single layer, commercially available unidirectional CFRP systems that used Tonen (wall 3) and Henkel (wall 2) epoxies. These two walls were the subject of …