Engineering Commons^™

Review Of Methodological Decisions In Life Cycle Assessment (Lca) Of Biorefinery Systems Across Feedstock Categories, James Gaffey, Maurice N. Collins, David Styles

Publications

The application of life cycle assessment (LCA) to biorefineries is a necessary step to estimate their environmental sustainability. This review explores contemporary LCA biorefinery studies, across different feedstock categories, to understand approaches in dealing with key methodological decisions which arise, including system boundaries, consequential or attributional approach, allocation, inventory data, land use changes, product end-of-life (EOL), biogenic carbon storage, impact assessment and use of uncertainty analysis. From an initial collection of 81 studies, 59 were included within the final analysis, comprising 22 studies which involved dedicated feedstocks, 34 which involved residue feedstocks (including by-products and wastes), and a further 3 …

Influence Of Side Dilution Jets On Swirling And Non-Swirling Pulverised Biomass Turbulent Annular Flows, Syed E. Gillani, Yasir M. Al-Abdeli, Zhao F. Tian

Research outputs 2022 to 2026

The use of pulverised biomass in non-premixed combustion systems, featuring turbulent annular flows (swirling, non-swirling) with downstream air dilution jets, is of immense practical importance. The overall combustion performance and emissions heavily rely on the underlying flow dynamics, turbulence and dispersion behaviour of the pulverised biomass particles. Despite the practical significance of side dilution jets in aiding complete combustion and controlling pollutants, the fundamental understanding of side dilution jets influence on the biomass particle velocity field, turbulence, and dispersion characteristics is still lacking. However, the presence of a multi-phase (solid-gas) flow field, highly turbulent annular flows, swirl, and cross-wise turbulent …

Maximizing Charge Dynamics In Znin2s4/Cn Van Der Waals Heterojunction For Optimal Hydrogen Production From Photoreforming Of Glucose, Jinqiang Zhang, Xinyuan Xu, Lei Shi, Huayang Zhang, Shaobin Wang, Hongqi Sun

Research outputs 2022 to 2026

Biomass photoreforming stands out as a promising avenue for green hydrogen, leveraging solar energy for the generation and transformation of clean and renewable energy resources. The pursuit of efficient photocatalysts is motivated by the unsatisfied hydrogen evolution performance arising from the complex and stubborn structure of biomass. Herein, we loaded 2-dimensional (2D) ZnIn2S4 onto 2D carbon nitride nanosheets, resulting in the formation of Van der Waals (VDW) heterojunctions (ZIS/CN). Band structure and morphology of CN were rationally tailored through precursor engineering to effectively magnify interfacial internal electric field and minimize diffusion pathway within the VDW heterostructure, realizing optimal charge dynamics …

Synthesis And Characterization Of Cellulose Microfibril-Reinforced Polyvinyl Alcohol Biodegradable Composites, Fatemeh Mahdiyeh-Boroujeni, Gabriella Fioravanti, Ronald Kander

School of Design and Engineering Papers

The pursuit of an environmentally sustainable manufacturing process requires the substitution of less damaging and recyclable solutions for harmful reagents. This study aims to assess the effectiveness of using cellulose microfibrils synthesized via different hydrolysis reactions as reinforcing agents in polyvinyl alcohol (PVA) at varying concentrations. The investigation explores the morphology, thermal properties, and chemical behavior of the cellulose particles. The cellulose microfibrils (CMFs) produced using citric acid exhibited the highest yield and aspect ratio. Notably, particles from organic acids demonstrated greater thermal stability, with oxalic acid-derived particles displaying the maximum thermal degradation temperature. Subsequently, cast films of PVA reinforced …

De-Risking Pretreatment Of Microalgae To Produce Fuels And Chemical Co-Products, Jacob S. Kruger, Skylar Schutter, Eric P. Knoshaug, Bonnie Panczak, Hannah Alt, Alicia Sowell, Stafanie Van Wychen, Matthew Fowler, Kyoko Hirayama, Anuj Thakkar, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Conversion of microalgae to renewable fuels and chemical co-products by pretreating and fractionation holds promise as an algal biorefinery concept, but a better understanding of the pretreatment performance as a function of algae strain and composition is necessary to de-risk algae conversion operations. Similarly, there are few examples of algae pretreatment at scales larger than the bench scale. This work aims to de-risk algal biorefinery operations by evaluating the pretreatment performance across nine different microalgae samples and five different pretreatment methods at small (5 mL) scale and further de-risk the operation by scaling pretreatment for one species to the 80 …

A Review On Biochar As An Adsorbent For Pb(Ii) Removal From Water, Pushpita Kumkum, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Heavy metal contamination in drinking water is a growing concern due to its severe health effects on humans. Among the many metals, lead (Pb), which is a toxic and harmful element, has the most widespread global distribution. Pb pollution is a major problem of water pollution in developing countries and nations. The most common sources of lead in drinking water are lead pipes, faucets, and plumbing fixtures. Adsorption is the most efficient method for metal removal, and activated carbon has been used widely in many applications as an effective adsorbent, but its high production costs have created the necessity for …

A Review On Biomass As A Substitute Energy Source: Polygeneration Influence And Hydrogen Rich Gas Formation Via Pyrolysis, Tawanda Matamba, Arash Tahmasebi, Jianglong Yu, Alireza Keshavarz, Hussein R. Abid, Stefan Iglauer

Research outputs 2022 to 2026

Hydrogen rich gas production and advantages of polygeneration during biomass conversation through pyrolysis were extensively reviewed in this paper. Different innovative pyrolysis setups and the effect of reaction conditions such as pressure, temperature, catalyst type, biomass type, and reactor type on the formation of hydrogen and other value-added chemicals has been exploited. High temperatures and pressures together with application of catalysts was reported to favour the enhancement of hydrogen by promoting secondary pyrolysis reactions and hence the production of H2 gas. Compared to one-stage pyrolysis systems, pyrolysis data from two-stage pyrolysis reaction systems reported improved production of hydrogen and value-added …

Experiments And Modelling Of Biomass Pulverisation In Swirling And Non-Swirling Bluff Body-Stabilised Turbulent Annular Flows, Syed Ehtisham Gillani, Yasir M. Al-Abdeli, Zhao F. Tian

Research outputs 2022 to 2026

Deeper insights into particle loading have practical significance in applications particularly when this affects fuel-oxidiser mixing and flame stabilisation, as occurs in pulverised fuel (biomass) combustion systems. The underlying particle flow and dispersion characteristics not only play a crucial role in controlling overall combustion performance but can also impact emissions. A fundamental understanding of particle flow dynamics and dispersion behaviour for raw pulverised biomass, under non-swirling and swirling conditions need further systematic investigation to better understand the interplay between swirling and non-swirling bluff-body stabilised recirculation zones and particles emitted from a centralised jet. This work uses Particle Image Velocimetry (PIV) …

Carbohydrates Generated Via Hot Water As Catalyst For Co2 Reduction Reaction, Yang Yang, Heng Zhong, Jiong Cheng, Yun Hang Hu, Richard Lee Smith Jr, Fangming Jin

Michigan Tech Publications, Part 2

Combining terrestrial biomass with submarine-type hydrothermal environments for CO2 reduction is a possible approach for realizing new energies while achieving sustainable circulation of carbon. Herein, carbohydrateenabled CO2 reduction based on NaHCO3 conversion to formate revealed that hydrothermal environments facilitated direct hydrogen transfer from carbohydrates (glucose, cellulose) to CO2/NaHCO3 with hot water (250–300 °C, 5–20 MPa) acting as homogeneous catalyst in absence of any conventional catalysts giving CO2/ NaHCO3 reduction efficiencies as high as 76% for cellulose. Time-resolved operando hydrothermal DRIFTS spectra of glycolaldehyde in hot water (250 °C, autogenous pressure) verified that water catalyzed NaHCO3 reduction by converting the -CHO …

Reduced Metal Nanocatalysts For Selective Electrochemical Hydrogenation Of Biomass-Derived 5-(Hydroxymethyl)Furfural To 2, 5-Bis(Hydroxymethyl)Furan In Ambient Conditions, Baleeswaraiah Muchharla, Moumita Dikshit, Ujjwal Pokharel, Ravindranath Garimella, Adetayo Adedeji, Kapil Kumar, Wei Cao, Hani Elsayed-Ali, Kishor Kumar Sadasivuni, Naif Abdullah Al-Dhabi, Sandeep Kumar, Bijandra Kumar

Chemistry & Biochemistry Faculty Publications

Selective electrochemical hydrogenation (ECH) of biomass-derived unsaturated organic molecules has enormous potential for sustainable chemical production. However, an efficient catalyst is essential to perform an ECH reaction consisting of superior product selectivity and a higher conversion rate. Here, we examined the ECH performance of reduced metal nanostructures i.e., reduced Ag (rAg) and reduced copper (rCu) prepared via electrochemical or thermal oxidation and electrochemical reduction process, respectively. Surface morphological analysis suggests formation of nanocoral and entangled nanowire structure formation for rAg and rCu catalysts. rCu exhibits slight enhancement in ECH reaction performance in comparison to the pristine Cu. However, the rAg …

Modeling The Production Of Microalgal Biomass In Large Water Resource Recovery Facilities And Its Processing Into Various Commodity Bioproducts, James Pierson, Gopi Raju Makkena, Sandeep Kumar, Vinod Kumar, Vivekanand Vivekanand, Hasan Husain, Muhammad Ayser, Venkatesh Balan

Civil & Environmental Engineering Faculty Publications

Algae are capable of sequestering nutrients such as nitrates and phosphates from wastewater in the presence of sunlight and carbon dioxide (CO₂) to build up their body mass and help combat climate change. In the current study, we carried out different case studies to estimate the volume of algal biomass that could be produced annually using the rotating algal biofilm (RAB) method in three large-scale water resource recovery facilities (WRRFs) in Texas: Fort Worth, Dallas, and Houston. We calculated the total amount of lipids, carbohydrates, and proteins that could be fractionated from the algal biomass while using the …

Partially Oxidative Torrefaction Of Woody Biomass Pellets: Burning Behaviour And Emission Analysis, Sajid Riaz, Yasir M. Al-Abdeli, Ibukun Oluwoye

Research outputs 2022 to 2026

Non-conventional torrefaction under partially oxidative conditions is an emerging cost-effective thermochemical pre-treatment method to improve the quality of biomass for energy applications. The literature lacks data on the combustion of biomass torrefied under oxygen-deficient atmosphere with actual reactor conditions (inevitable non-uniformities in the thermal environment). In this work, a dual mode fixed-bed biomass (torrefaction) reactor and combustor was operated on Australian biomass pellets, to torrefy the fuels at 275 °C for 30 min using partially oxidative atmosphere (O₂: 5 vol %, balance N₂) and then to combust them. Combustion behaviour with a particular focus on gaseous …

The Heat Is On: The Collaborations, Capacities, And Management Style Required For The Establishment And Sustainability Of Community-Owned Renewable Energy District Heating Systems In Austria, Ireland, Northern Ireland, Wales, And Scotland, Gerard Doyle

Articles

International reviews of countries’ progress at tackling climate change show that Ireland is making small levels of progress on tackling issues associated with climate change. This paper will highlight the pivotal role the State performs, both at national and local level, in creating the conditions essential for the establishment of community-owned renewable energy district heating systems. In particular, the State can provide funding for these initiatives to acquire the management and technical expertise essential for their establishment and maintenance. This paper will also examine a theoretical framework, referred to as capacity analysis, to explain the capacities that need to be …

Paper Mill Sludge Biochar To Enhance Energy Recovery From Pyrolysis: A Comprehensive Evaluation And Comparison, Zhongzhe Liu, Matthew Hughes, Yiran Tong, William Kreutter, Hugo Cortes Lopez, Simcha L. Singer, Daniel Zitomer, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Bio-oil and pyrolysis gas (py-gas) are two pyrolysis products available for potential energy recovery. Crude bio-oil, however, is typically corrosive and unstable, requiring special combustion equipment or catalytic upgrading to produce drop-in-grade fuel. In contrast, py-gas is readily useable in standard equipment for energy recovery. Previous research revealed that Ca-impregnated biochar catalyst improved bio-oil to py-gas conversion. Biochar produced from paper mill sludge (p-sludge) has very high Ca content. In this study, the catalytic ability of p-sludge biochar was systematically evaluated for the first time in pyrolysis. P-sludge biochar resulted in higher py-gas yield (40 wt% of total pyrolysis products) …

Optimal Design Of Photovoltaic, Biomass, Fuel Cell, Hydrogen Tank Units And Electrolyzer Hybrid System For A Remote Area In Egypt, Hoda Abd El-Sattar, Salah Kamel, Hamdy M. Sultan, Hossam Zawbaa, Francisco Jurado

Articles

In this paper, a new isolated hybrid system is simulated and analyzed to obtain the optimal sizing and meet the electricity demand with cost improvement for servicing a small remote area with a peak load of 420 kW. The major configuration of this hybrid system is Photovoltaic (PV) modules, Biomass gasifier (BG), Electrolyzer units, Hydrogen Tank units (HT), and Fuel Cell (FC) system. A recent optimization algorithm, namely Mayfly Optimization Algorithm (MOA) is utilized to ensure that all load demand is met at the lowest energy cost (EC) and minimize the greenhouse gas (GHG) emissions of the proposed system. The …

Optimal Design Of Photovoltaic, Biomass, Fuel Cell, Hydrogen Tank Units And Electrolyzer Hybrid System For A Remote Area In Egypt, Abd El-Sattar Abd El-Sattar, Salah Kamel, Hamdy M. Sultan, Hossam Zawbaa, Francisco Jurado

Articles

In this paper, a new isolated hybrid system is simulated and analyzed to obtain the optimal sizing and meet the electricity demand with cost improvement for servicing a small remote area with a peak load of 420 kW. The major configuration of this hybrid system is Photovoltaic (PV) modules, Biomass gasifier (BG), Electrolyzer units, Hydrogen Tank units (HT), and Fuel Cell (FC) system. A recent optimization algorithm, namely Mayfly Optimization Algorithm (MOA) is utilized to ensure that all load demand is met at the lowest energy cost (EC) and minimize the greenhouse gas (GHG) emissions of the proposed system. The …

Prospects Of Biogas And Evaluation Of Unseen Livestock Based Resource Potential As Distributed Generation In India, Gagandeep Kaur, Naveen Kumar Sharma, Jaspreet Kaur, Mohit Bajaj, Hossam Zawbaa, Rania A. Turky, Salah Kamel

Articles

The power sector of developing countries is the backbone of the economy, and robust implementation of energy policies can play a significant role in its expansion. India is blessed to have ample natural resources; the only necessity is to identify these unseen resources comprehensively. India is an agricultural country with plenty of livestock generated biomass, which is renewable and easily accessible in rural India. The paper estimated the potential of electrical energy through biogas production from livestock generated dung in all states of India. Estimation of biogas from the gross livestock dung generation from all states and largely populated livestock …

Role Of Primary Freeboard On Staged Combustion Of Hardwood Pellets In A Fixed Bed Combustor, Awais Junejo, Yasir Al-Abdeli, Jacobo Porteiro

Research outputs 2022 to 2026

In staged fixed bed biomass combustion, primary air is supplied beneath the fuel bed with secondary air then provided above in the freeboard region. For fixed bed configurations, the freeboard is further divided into a primary freeboard length (LI), which is upstream of the secondary air and a secondary freeboard length (LII), measured from the secondary air all the way to the exhaust port. Despite extensive research into fixed bed configurations, no work has been successfully completed that resolves the effects of changing LI on fuel conversion, both in the fuel bed and within the freeboard of batch-type biomass combustors. …

Recent Updates On Ions And Nutrients Uptake By Halotolerant Freshwater And Marine Microalgae In Conditions Of High Salinity, Abdul Mannan Zafar, Muhammad Asad Javed, Ashraf Aly Hassan, Khalid Mehmood, Endalkachew Sahle-Demessie

Department of Civil and Environmental Engineering: Faculty Publications

Algae is an appropriate natural resource to augment the optimal use of undesired ions in water and wastewater. Increasing algal cells, the consumption of particular ions, including chloride, nitrate, phosphate, and ammonium, provides a suitable way to optimize water treatment processes. Different algal species have the capability to survive in extreme salinities by developing resistance against osmotic pressure in saline water. The current study reviews the effect of salinity on algal biomass production, algal growth rate, chlorides, nitrates, phosphates, chemical oxygen demand (COD), total nitrogen, total phosphorus, and ammonium ions. Mainly algae cultivated in freshwater, synthetic brackish water, seawater, and …

A Review Of Characteristics Of Bio-Oils And Their Utilization As Additives Of Asphalts, Ran Zhang, Zhanping You, Jie Ji, Qingwen Shi, Zhi Suo

Michigan Tech Publications

Transforming waste biomass materials into bio-oils in order to partially substitute petroleum asphalt can reduce environmental pollution and fossil energy consumption and has economic benefits. The characteristics of bio-oils and their utilization as additives of asphalts are the focus of this review. First, physicochemical properties of various bio-oils are characterized. Then, conventional, rheological, and chemical properties of bio-oil modified asphalt binders are synthetically reviewed, as well as road performance of bio-oil modified asphalt mixtures. Finally, performance optimization is discussed for bio-asphalt binders and mixtures. This review indicates that bio-oils are highly complex materials that contain various compounds. Moreover, bio-oils are …

Exploration Of The Sludge Biodiesel Pathway, Zachary Christman

Department of Agronomy and Horticulture: Dissertations, Theses, and Student Research

Wastewater sludge is an overlooked source of fat, oil, and grease (FOG) that could be converted into biodiesel. The United States produces about 8 million tons of sludge per year. The disposal cost for this amount of sludge is about 2 billion US dollars. The widespread availability and low cost of sludge compared to other biodiesel raw materials make it an economical choice for a renewable fuel. Using sludge as a raw material can produce 25 to 30 mg per gram of fatty acid methyl ester (FAME); the main component of biodiesel. Sludge biodiesel has the potential of transforming a …

Nsf Career Award Supports Schwartz's Research On The Chemical Process For Making Rubber Component, Marcus Wolf

General University of Maine Publications

advance his ongoing dissection of the Lebedev process. The well-known, multi-step chemical reaction is used to make butadiene from biomass-derived ethanol. However, little research has been conducted on the Lebedev process at the molecular level. Understanding the intricacies of this process will help researchers create new catalysts necessary for the chemical reactions to make goods from both petroleum and biomass, that would increase butadiene yield.

Kinetics And Thermodynamics Of Thermal Inactivation For Recombinant Escherichia Coli Cellulases, Cel12b, Cel8c, And Polygalacturonase, Peh28; Biocatalysts For Biofuel Precursor Production, Eman Ibrahim, Ahmed Mahmoud, Kim D. Jones, Keith E. Taylor, Ebtesam N. Hosseney, Patrick L. Mills, Jean M. Escudero

Civil Engineering Faculty Publications and Presentations

Lignocellulosic biomass conversion using cellulases/polygalacturonases is a process that can be progressively influenced by several determinants involved in cellulose microfibril degradation. The current paper focuses on the kinetics and thermodynamics of thermal inactivation of recombinant E. coli cellulases, cel12B, cel8C, and a polygalacturonase, peh 28, derived from Pectobacterium carotovorum sub sp. carotovorum. Several consensus motifs conferring the enzymes’ thermal stability in both cel12B and peh28 model structures have been detailed earlier, which were confirmed for the three enzymes through the current study of their thermal inactivation profiles over the 20-80 °C range using the respective activities on carboxymethylcellulose and …

Challenges To Levulinic Acid And Humins Valuation In The Sugarcane Bagasse Biorefinery Concept, Emília Savioli Lopes, Jean Felipe Leal Silva, Elmer Ccopa Rivera, Alana Petrina Gomes, Melina Savioli Lopes, Rubens Maciel Filho, Laura Plazas Tovar

Faculty Publications

© 2020, Springer Science+Business Media, LLC, part of Springer Nature. Levulinic acid (LA) is currently one of the most promising chemicals derived from biomass. However, its large-scale production is hampered by the challenges in biomass hydrolysis and the poor selectivity due to the formation of humins (HUs). This study addresses these challenges using the biorefinery concept of biomass fractionation. A three-step process (pretreatment, delignification, and acid-catalyzed conversion) was optimized to produce LA from SCB considering the yield (YLA), efficiency (ELA), and concentration of LA (CLA) as functions of temperature, reaction time, acid concentration, and solids loading. By means of a …

A Review Of Coal Heating Value Correlations With Application To Coal Char, Tar, And Other Fuels, Andrew P. Richards, Denver Haycock, Jacob F. Frandsen, Thomas H. Fletcher

Faculty Publications

Accurately measuring a fuel’s heating value is one of the first steps in the classification of a new fuel. Heating values are widely used in coal combustion research and are becoming more useful in other fuel types as well. Many different empirical correlations to predict heating values based on primary organic (CHONS) elemental composition are found in the literature, many of which were originally created to predict heating values of parent coal, and some of which have been extended for biomass. However, no correlations exist for heating values of coal chars and tars. Thirteen literature heating value correlations (10 model …

Potential Energy Generation From Agricultural Residue In Indonesia, Adrian Rizqi Irhamna

English Language Institute

Indonesia has great potential of biomass sources from their agricultural residue, which can potentially be used for alternative energy generation. This preliminary research explores the most suitable technology for energy generation from agricultural residue and its challenge for application in Indonesia. The study showed that biomass utilization via the direct combustion process is recommended for energy generation. It is also reported that the pretreatment process of drying and washing, are required to increase the fuel quality and plant efficiency.

Development Of Novel Catalysts For Hydrogen Gas Production From Biomass Compounds, Boanerges Bamaca

Department of Biological Systems Engineering: Dissertations and Theses

Hydrothermal biomass gasification technologies (sub- and supercritical water gasification and aqueous-phase reforming) have considerable economic, environmental, and technical advantages over other energy-extensive technologies (e.g. natural gas reforming) for hydrogen gas production. However, lack of economically feasible and highly active catalysts is a main challenge that impedes upscaling of these technologies for hydrogen gas production.

The goal of this study was to develop innovative, economically feasible and active heterogeneous supported metal catalysts for hydrothermal processes for producing hydrogen gas from biomass-derived compounds. Because of its stable structure and chemical inertness, graphene was used as catalyst support. Graphene supported metal catalysts were …

Depolymerization Of Fractionated Wood By Hydrothermal Liquefaction, Felipe Buendia-Kandia, Nicolas Brosse, Guillain Mauviel, Anthony Dufour

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

Direct thermochemical conversion of lignocellulosic biomass produces a mixture of compounds that have to be separated to produce purified building blocks. Moreover, lignin derived products have a detrimental effect on further biological conversion processes, such as fermentation. For all these reasons, it is important to develop an integrated approach for a better fractionation and valorisation of macromolecules (carbohydrates and lignin) in bio-refineries.

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Electrochemical Upgrading Of Bio-Oil: A Proof-Of-Principle Investigation, Mehmet Pala, Kun Guo, Wolter Prins, Frederik Ronsse, Korneel Rabaey, Antonin Prévoteau

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

Fast pyrolysis is an advanced thermochemical conversion technology developed to produce bio-oil from biomass. With lignocellulosic biomass, high product yields (65-75 wt.%) can be attained. Yet, certain unfavorable characteristics of bio-oil impede its utilization prospects. High water content, high oxygen content, together with instability and acidity are the recognized adverse features of bio-oil. Tackling these issues is possible by reducing the oxygen content and/or steering the oxygen functionality of bio-oils.

Electrochemical hydrogenation (ECH) is a recently proposed approach targeting the reduction of the reactive compounds in bio-oil (aldehydes, ketones etc.) to their corresponding alcohols, diols [1]. In this attractive approach, …

Uumanned Aerial Vehicle Data Analysis For High-Throughput Plant Phenotyping, Jiating Li

Department of Biological Systems Engineering: Dissertations and Theses

The continuing population is placing unprecedented demands on worldwide crop yield production and quality. Improving genomic selection for breeding process is one essential aspect for solving this dilemma. Benefitted from the advances in high-throughput genotyping, researchers already gained better understanding of genetic traits. However, given the comparatively lower efficiency in current phenotyping technique, the significance of phenotypic traits has still not fully exploited in genomic selection. Therefore, improving HTPP efficiency has become an urgent task for researchers. As one of the platforms utilized for collecting HTPP data, unmanned aerial vehicle (UAV) allows high quality data to be collected within short …