Engineering Commons^™

Production Of Anhydrous 1,4-Dioxane, Jean Yamanis

Chemical and Materials Engineering Faculty Patents

This invention relates to the production of anhydrous 1,4-dioxane by the dimerization of ethylene oxide in the presence of an acidic type of cation exchanger, preferably an acidic cation exchanger resin having sulfonic acid groups associated therewith. The 1,4-dioxane is formed by contacting ethylene oxide in the liquid phase with an acidic-type cation exchanger at a first temperature and for a time sufficient to yield a reaction product of the ethylene oxide and the cation exchanger, and thereafter heating the reaction product at a second temperature higher than the first temperature and for a time period sufficient to dissociate the …

Speciation Of Cr (Iii) And Cr (Vi) Via Reversed Phase Hplc With Inductively Coupled Plasma Emission Spectroscopic Detection (Hplc-Icp)24, Richard N. Savage, I. S. Krull, D. Bushee, R. G. Schleicher, S. B. Smith, Jr.

Materials Engineering

Chromium ions, viz., chromic (Cr⁺³ = III) and chromate (Cr⁺⁶ = VI), can be reliably, conveniently, reproducibly, and quickly separated and detected by the use of conventional paired-ion, reversed phase (RP) high performance liquid chromatography (HPLC) together with refractive index (RI) and/or inductively coupled plasma emission spectroscopic (ICP) detection. A number of novel paired-ion approaches have now been developed, using PIC A (tetrabutylammonium hydroxide) or PIC B (sodium n-alkyl sulfonate) separately in the mobile phase. This allows for the retention of each Cr species depending on the particular ion pairing reagent being used, while the remaining Cr ion …

Model Studies Of Oxygen-Intercalated Graphite, Aldona M. Butkus, Cary Y. Yang, Y. W. Tsang, C. Y. Fong

Electrical and Computer Engineering

The possibility of intercalating oxygen to reduce the conductivity of graphite has been investigated by modified intermediate neglect of differential overlap 3 and tight-binding methods. The cluster calculations suggest that the most stable position for the oxygen atom is 1.25 A above a carbon-carbon bond. The tight-binding band calculation predicts the stage-I intercalated graphite to be a zero-indirect-gap semiconductor. Higher-stage intercalated graphite is expected to have a finite insulating gap whose value is governed by the carbon-oxygen interaction.

Acuta Enews December 1982, Vol. 11, No. 12

ACUTA Newsletters

In This Issue

CANADA BELL, BY OUTSMARTING GOVERNMENT, MAY SHARPLY REDUCE REGULATION OF ITSELF

POTPOURRI

FROM THE BOARD

BELLS REP LETS 'ANTELOPE' RUN FREE AT SEMINAR

PHONE CENTER TRIVIA

INSIDE ACUTA

The Effects Of Formal Human Leadership And Computer-Generated Decision Aids On Problem Solving Via Computer : A Controlled Experiment, Computerized Conferencing & Communications Center, Starr Roxanne Hiltz, Kenneth Johnson, Murray Turoff

Computerized Conferencing and Communications Center Reports

Twenty-four groups of five professionals and managers within a variety of organizations were given the task of using a computer conference to reach agreement on the best solution to a ranking problem.

The independent variable is the structure of the conferencing capability used. Two alternative means of structuring the conferences were employed, in a two-by-two factorial design. Groups with "Human Leadership" elected one of their members to lead the group in its decision making discussion. Groups with "Computer Feedback" were given periodic tables which displayed the current "group decision" in terms of the mean rankings of items, and the degree …

Engineering Properties Of Overburden Materials For The Means Project, Vincent P. Drnevich, David L. Allen, Tommy C. Hopkins

Kentucky Transportation Center Research Report

A geotechnical investigation was performed to determine the physical properties (classification) and engineering properties of the overburden material from a proposed oil shale mining site in Montgomery County (Means Project). Three overburden materials were received in sealed meal drums and were labeled Nancy Member, Borden Formation; Clay City Bed, Farmers Member, Borden Formation; and Henley bed, Farmers Member, Borden Formation. Hereafter, they will be referred to as the Nancy, Clay City and Henley, respectively. the various types of geotechnical laboratory tests performed on these materials are listed in Table 1.

Nonlinear Anelasticity Of Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

An approximate solution of the equation of motion of a nonlinear anelastic reed at or near resonance is presented. The steady state solution reproduces the well-known nonlinear resonances. The solution also predicts the existence of auto modulations, i.e., self-excited modulations of the amplitude and phase at constant power of excitation of the reed. Numerical examples of such auto modulations are presented for an antisymmetric deformation potential. Experimental studies of finite amplitude oscillations of a magnesium reed vibrating at 72 and 431 Hz at room temperature confirm the existence of auto modulations. The experimental results can be semi quantitatively described in …

Stick Holder And Deposition Device, Larry D. Swetnam, James H. Casada, Linus R. Walton

Biosystems and Agricultural Engineering Faculty Patents

The present invention is directed to a device for positioning a stick relative to a harvesting aid. The stick holder mounts a stick relative to an operator positioned on a harvesting aid. The stick holder is designed to adjust the height and angle of the stick relative to the operator. In addition, a plant holding trough is provided adjacent to the stick holder to retain the harvested crops prior to a loaded stick being discharged from the stick holder.

Acuta Enews November 1982, Vol. 11, No. 11

ACUTA Newsletters

In This Issue

INSIDE ACUTA

PARTY LINE

FROM THE BOARD

"MOUTH OF THE SOUTH"

POTPOURRI

Approximate Solutions For Distillation Rating And Operating Problems Using The Smoker Equations, Raymond C. Waggoner, Terry L. Tolliver

Chemical and Biochemical Engineering Faculty Research & Creative Works

Algorithms for rapid solution of implicit variables in the Smoker design equations are presented. The accuracy of these solutions in the context of distillation rating and operating problems Is evaluated for distillation systems where more rigorous physical property assumptions are known to apply. Alternative methods of initially fitting the Smoker equations to rigorous tray-by-tray material and energy balance calculations as well as methods extending the procedure to handle multicomponent systems are discussed. These methods are well suited for many optimization, reliability, and control studies as well as for the fast real-time calculations such as interactive computations or on-line control. © …

Subharmonic Generation By Resonant Three‐Wave Interaction Of Deep‐Water Capillary Waves, Partha P. Banerjee, Adrianus Korpel

Electrical and Computer Engineering Faculty Publications

Subharmonic generation has been observed during the propagation of deep‐water capillary waves. The observations are shown to be in agreement with the theory of degenerate resonant noncollinear three‐wave interaction in a nonlinear, dispersive medium.

Review Of Pertinent Contract Documents Tennessee-Tombigbee Waterway Divide Cut Section 3a, Ronald D. Hughes, Robert C. Deen, David L. Allen, Tommy C. Hopkins

Kentucky Transportation Center Research Report

During construction of a portion of the Tombigbee Canal near Corinth, Mississippi, southward from Pickwick Lake (Station 13,118+00 to 13,337+50), the Contractor reported various problems, which he termed "differing site conditions." Some of the items considered as problems by the Contractor were: the amount of cherty Paleozoic material was far less than he expected or anticipated, there were deep deposits of bluish muck, the alluvial was not sufficiently stable to place in 1-foot lifts, excessively wet materials made it necessary to shift equipment frequently, the equipment had to travel over bad roads, and the materials had no bearing strength.

Strain Energy Analysis Of Pavement Designs For Heavy Trucks, Herbert F. Southgate, Robert C. Deen, Jesse G. Mayes

Kentucky Transportation Center Research Report

The first portion of this paper summarizes classical concepts of work, or strain energy, as applied to the analysis of stresses, strains, and deflections under various vehicular load configurations on pavement systems. Controlling equations for strain energy density are presented. When considering strain energy density, strain energy, or work, all components of stresses or strains must be taken into account so that total internal behavior can be evaluated. Previously, pavement thickness design systems have been developed using only a single component of strain, typically at the bottom of the asphaltic concrete layer or at the top of the subgrade. Strain …

Explicit Determination Of The Complex Refractive Index Of An Absorbing Medium From Reflectance Measurements At And Near Normal Incidence, R. M.A. Azzam

Electrical Engineering Faculty Publications

Measurement of reflectance at normal incidence R and its fractional change ΔR/R caused by a change of the angle of incidence from 0 to a small angle ϕ (ϕ≲ 20°) permits explicit determination of both the refractive index n and extinction coefficient k of an isotropic absorbing medium. The medium of incidence (ambient) is assumed to have a known refractive index (e.g., =1 for vacuum or air), and the incident light is either p or s linearly polarized.

Mechanical Properties Of Kentucky Oil Shales As Related To Mine Design Application, Tom F. Fudge Jr., David L. Allen, Tommy C. Hopkins

Kentucky Transportation Center Research Report

To develop oil shales as an alternate energy resource, it will be necessary to develop appropriate mining techniques. In this regard, the mechanical properties of the ore must be determined. Section I of this paper presents data from a laboratory study to determine these properties. Uniaxial compression tests, longitudinal frequency tests, indirect tensile tests, and triaxial tests were performed. Section II uses data from section I to design an example underground mine. Strength properties are considered in the design of roof spans and pillars. It is concluded that underground mining of Kentucky oil shale is feasible with a possible extraction …

Effects Of Construction Variations Upon Dynamic Moduli Of Asphaltic Concrete, Herbert F. Southgate

Kentucky Transportation Center Research Report

The two variables that most influence the behavior of asphaltic concrete pavements are subgrade modulus and thickness of the asphaltic concrete. Other significant variables are: temperature of the asphaltic concrete, asphaltic concrete modulus, frequency of the dynamic loading, asphalt content by weight in mix, and voids in the asphaltic concrete mix.

During a series of Road Rater tests on a experimental pavement in Kentucky, deflection test data varied widely from expected values. Test data reported by Kallas and Riley permitted the development of an equation relating asphaltic concrete modulus to its temperature and to the frequency of loading. However, after …

Warrants For Left-Turn Lanes, Kenneth R. Agent

Kentucky Transportation Center Research Report

Warrants for the installation of separate left-turn lanes were developed. Literature was reviewed, and policies and practices in other states were surveyed. Accident analyses of locations with and without separate left-turn lanes were conducted. Computer simulation was used to determine relationships among traffic delay, load factor, traffic volume, percent left-turns, cycle length, and cycle split. The relationship between left-turn accidents and conflicts was investigated.

Warrants were developed involving the following three general areas:

1. accident experience,
2. volumes (based on delay), and
3. traffic conflicts.

A Checklist For Building An Energy Efficient Home In Florida, Florida Solar Energy Center, Michael Houston

FSEC Energy Research Center®

To design and build an energy-efficient home in Florida, seriously consider each of the steps listed here. Some are common sense, most are relatively inexpensive, and all add up to much lower energy bills. In fact, by following this checklist, you could expect to be very comfortable year round in your home and save about 30%-50% on your utility bills.

Engineering Properties Of Kentucky Oil Shales, Vincent P. Drnevich, Tommy C. Hopkins, David L. Allen, Samuel S. Hale

Kentucky Transportation Center Research Report

Excavation, handling, and the environmentally safe disposal of spent oil shale and overburden materials require a knowledge of their geotechnical engineering properties. To determine these properties a laboratory investigation of the physical and geotechnical engineering properties was made. The physical tests consisted of mechanical analyses, Atterberg Limits, and specific gravity determinations. Geotechnical properties were determined by moisture-density analyses, triaxial compression, permeability tests, slake-durability, one-dimensional compression tests, and Los Angeles abrasion. A one-dimensional compression test was devised to address the problem of placement, loading, and saturation of the spent shales and overburden materials. The compacted, unprocessed oil shales were more susceptible …

Coherence Effects In Synchronously Pumped Mode‐Locked Dye Lasers, Lee W. Casperson

Electrical and Computer Engineering Faculty Publications and Presentations

A formalism is developed for describing the evolution of picosecond mode‐locked pulses in synchronously pumped dye lasers. The finite phase memory of the molecular wave functions is included, and it is found that the resultant coherence effects can be dominant for operation close to exact synchrony. Considerations of the isotropic molecular orientational distribution and the finite vibrational relaxation times are also essential in obtaining quantitative agreement with experimental results.

Polarization-Preserving Single-Layer-Coated Beam Displacers And Axicons, R. M.A. Azzam, M. Emdadur Rahman Khan

Electrical Engineering Faculty Publications

A design procedure is described to determine the thicknesses of single-layer coatings of a given dielectric on a given metallic substrate so that any input polarization of light is preserved after two reflections at the same angle of incidence from a parallel-mirror beam displacer or an axicon. This is achieved by equalizing the net complex p and s reflection coefficients (also called the radial and azimuthal eigenvalues of an axicon) after two reflections. The net polarization-independent reflectance (insertion loss) of the device is computed and found to exceed the net minimum parallel reflectance of the uncoated device for incidence above …

Research On Atmospheric Volcanic Emissions: An Overview, James P. Friend, Alan R. Bandy, Jarvis L. Moyers, William H. Zoller, Richard E. Stoiber, Arnold L. Torres, William I. Rose, M. Patrick Mccormick, David C. Woods

Department of Geological and Mining Engineering and Sciences Publications

The project "Research on Atmospheric Volcanic Emissions" is a unique effort by NASA and university scientists to investigate the detailed chemical nature of plumes from volcanic eruptions. The major goals of the project are to: 1) understand the impact major eruptions will have on atmospheric chemistry processes, 2) understand the importance of volcanic emissions in the atmospheric geochemical cycles of selected species, 3) use knowledge of the plume chemical composition to diagnose and predict magmatic processes. Project RAVE'S first mission used the NASA Lockheed Orion P-3 outfitted with equipment to measure concentrations of the gases SO₂, OCS, H …

Resources Reference Guide 1 : A Preliminary Reference Guide For The Resources Network Database System, Computerized Conferencing & Communications Center

Computerized Conferencing and Communications Center Reports

IT IS EMPHASIZED THAT THIS PRELIMINARY DOCUMENTATION FOR THE RESOURCES NETWORK DATABASE SYSTEM CONFORMS TO THE SYSTEM SPECIFICATIONS.

RESOURCES REFERENCE GUIDE 1 is for limited distribution and review. It is not a user manual. Your interaction with the system may not always be exactly as described. All major features except keyword relations are supported in part, if not fully, at this time. Operation of some facilities are some what slow pending funding for optimization.

Groups and individuals wishing to use RESOURCES on the Electronic Information Exchange System should make arrangements through the Computerized Conferencing and Communications Center at the New …

Scheme To Polarization-Correct A Waxicon, R. M.A. Azzam

Electrical Engineering Faculty Publications

No abstract provided.

Stationary Property Of Normal-Incidence Reflection From Isotropic Surfaces, R. M.A. Azzam

Electrical Engineering Faculty Publications

The complex reflection coefficients for the parallel (p) and perpendicular (s) polarizations of light that are normally incident upon an isotropic surface are proved to be stationary with respect to small changes of the angle of incidence in the neighborhood of zero. This is true not only for a single interface between isotropic media but also for any one-dimensionally inhomogeneous or multilayer reflecting structure that is stratified in the direction of the surface normal. For incident light of certain intensity, phase, and polarization, the intensity, phase, and polarization of the reflected light all remain stationary with …

An Exploratory Study On The Behavior Of Cold-Formed Steel Wall Studs, Yaochun Zhang, Teoman Peköz

CCFSS Library (1939 - present)

No abstract provided.

Mechanical & Engineering Properties Of A Cherty Paleozoic Material, Robert C. Deen, David L. Allen, Tommy C. Hopkins

Kentucky Transportation Center Research Report

The Divide Cut Section 3A of the Tennessee-Tombigbee Waterway is located in Tishomingo County, Mississippi. Construction of this portion of the canal required the excavation of a cherty residuum. This material (hereafter referred to as cherty Paleozoic material) is a member of the Fort Payne Formation, of the Mississippian Period, of the Paleozoic era. The purpose of this study was to determine the mechanical and engineering properties of the material, including its abrasiveness. Also, the mineralogy of the material was to be determined and a particular effort was made to determine if the material could be classified as Tripoli.

On …

Child Restraint Usage In Kentucky (Pre-Legislation), Kenneth R. Agent, Joseph D. Crabtree

Kentucky Transportation Center Research Report

In an attempt to increase child restraint usage, a law was enacted by the 1982 Kentucky Legislature requiring use of child restraints for children forty inches or less in height. To evaluate the effectiveness of this law, a usage survey had to be completed before the law became effective. Objectives of this study were to determine statewide child restraint usage and statistics relating to improper usage. Seatbelt usage of drivers was also analyzed.

A statewide child restraint usage rate of 14.4 percent was obtained. Only 44 percent of restraints were coded as used properly. Several factors, such as population, age …

Deflection And Evaluation Of Flexible Pavements For Design Of Overlays, Herbert F. Southgate, Gary W. Sharpe, Robert C. Deen

Kentucky Transportation Center Research Report

Personnel from the University of Kentucky Transportation Research Program (KTRP) were requested by the Tennessee Transportation Center to conduct a demonstration project concerning the collection and use of deflection data (Road Rater) for evaluation of the existing condition of flexible pavements for use in overlay design. The demonstration project involved using the Road Rater to collect deflection data on specific pavement sections selected by the Tennessee Department of Transportation (TDOT). Deflection data were evaluated in a way that provides input parameters for an overlay design procedure (see Appendix A). The Kentucky overlay design procedure was used to make recommendations concerning …

Snow-Melting System, 9th Street And I 64, Louisville, Wm. Vernon Azevedo

Kentucky Transportation Center Research Report

The 9th Street - I 64 interchange in Louisville was equipped with an automated electrical heating system for snow and ice removal. The system is capable of maintaining a clear and safe passageway. This report summarizes the performance of the heating system and describes the factors that will influence future use of this or other nonconventional methods of snow and ice removal.