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Full-Text Articles in Engineering
Nitrogen Radiofrequency Plasma Treatment Of Graphene, Antoine Bident, Nathalie Caillault, Florence Delange, Christine Labrugere, Guillaume Aubert, Cyril Aymonier, Etienne Durand, Alain Demourgues, Yongfeng Lu, Jean-François Silvain
Nitrogen Radiofrequency Plasma Treatment Of Graphene, Antoine Bident, Nathalie Caillault, Florence Delange, Christine Labrugere, Guillaume Aubert, Cyril Aymonier, Etienne Durand, Alain Demourgues, Yongfeng Lu, Jean-François Silvain
Department of Electrical and Computer Engineering: Faculty Publications
The incorporation of nitrogen (N) atoms into a graphitic network such as graphene (Gr) remains a major challenge. However, even if the insertion mechanisms are not yet fully understood, it is certain that the modification of the electrical properties of Gr is possible according to the configuration adopted. Several simulations work, notably using DFT, have shown that the incorporation of N in Gr can induce an increase in the electrical conductivity and N acts as an electron donor; this increase is linked to the amount of N, the sp2/sp3 carbon configuration, and the nature of C-N bonding. …
A Facile Graphene Conductive Polymer Paper Based Biosensor For Dopamine, Tnf-Α, And Il-6 Detection, Md Ashiqur Rahman, Ramendra Kishor Pal, Nazmul Islam, Robert Freeman, Francois Berthiaume, Aaron Mazzeo, Ali Ashraf
A Facile Graphene Conductive Polymer Paper Based Biosensor For Dopamine, Tnf-Α, And Il-6 Detection, Md Ashiqur Rahman, Ramendra Kishor Pal, Nazmul Islam, Robert Freeman, Francois Berthiaume, Aaron Mazzeo, Ali Ashraf
Mechanical Engineering Faculty Publications and Presentations
Paper-based biosensors are a potential paradigm of sensitivity achieved via microporous spreading/microfluidics, simplicity, and affordability. In this paper, we develop decorated paper with graphene and conductive polymer (herein referred to as graphene conductive polymer paper-based sensor or GCPPS) for sensitive detection of biomolecules. Planetary mixing resulted in uniformly dispersed graphene and conductive polymer ink, which was applied to laser-cut Whatman filter paper substrates. Scanning electron microscopy and Raman spectroscopy showed strong attachment of conductive polymer-functionalized graphene to cellulose fibers. The GCPPS detected dopamine and cytokines, such as tumor necrosis factor-alpha (TNF-α), and interleukin 6 (IL-6) in the ranges of 12.5–400 …
Multifunctional Graphene–Polymer Nanocomposite Sensors Formed By One-Step In Situ Shear Exfoliation Of Graphite, Ali Ashraf, Elizabeth Chang, Md Ashiqur Rahman, Dipannita Ghosh, Nazmul Islam, Jennifer K. Lynch-Branzoi
Multifunctional Graphene–Polymer Nanocomposite Sensors Formed By One-Step In Situ Shear Exfoliation Of Graphite, Ali Ashraf, Elizabeth Chang, Md Ashiqur Rahman, Dipannita Ghosh, Nazmul Islam, Jennifer K. Lynch-Branzoi
Mechanical Engineering Faculty Publications and Presentations
Graphene nanocomposites are a promising class of advanced materials for sensing applications; yet, their commercialization is hindered due to impurity incorporation during fabrication and high costs. The aim of this work is to prepare graphene–polysulfone (G−PSU) and graphene–polyvinylidene fluoride (G−PVDF) nanocomposites that perform as multifunctional sensors and are formed using a one-step, in situ exfoliation process whereby graphite is exfoliated into graphene nanoflakes (GNFs) directly within the polymer. This low-cost method creates a nanocomposite while avoiding impurity exposure since the raw materials used in the in situ shear exfoliation process are graphite and polymers. The morphology, structure, thermal properties, and …
Graphene Twistronics: Tuning The Absorption Spectrum And Achieving Metamaterial Properties, Ammar Armghan, Meshari Alsharari, Khaled Aliqab, Osamah Alsalman, Juveriya Parmar, Shobhit K. Patel
Graphene Twistronics: Tuning The Absorption Spectrum And Achieving Metamaterial Properties, Ammar Armghan, Meshari Alsharari, Khaled Aliqab, Osamah Alsalman, Juveriya Parmar, Shobhit K. Patel
Department of Mechanical and Materials Engineering: Faculty Publications
Graphene twistronics using multilayer graphene is presented in such a way that it provides a metamaterial effect. This manuscript also analyzes the prediction of behavior using machine learning. The metamaterial effect is achieved by twisting the graphene layers. Graphene twistronics is a new concept for changing the electrical and optical properties of bilayer graphene by applying a small angle twist between the layers. The angle twists of 5o, 10o, and 15o are analyzed for the proposed graphene twistronics design. Tuning in the absorption spectrum is achieved by applying small twists to the angles of the …
Non-Destructive Infrared Thermographic Curing Analysis Of Polymer Composites, Md Ashiqur Rahman, Javier Becerril, Dipannita Ghosh, Nazmul Islam, Ali Ashraf
Non-Destructive Infrared Thermographic Curing Analysis Of Polymer Composites, Md Ashiqur Rahman, Javier Becerril, Dipannita Ghosh, Nazmul Islam, Ali Ashraf
Mechanical Engineering Faculty Publications and Presentations
Infrared (IR) thermography is a non-contact method of measuring temperature that analyzes the infrared radiation emitted by an object. Properties of polymer composites are heavily influenced by the filler material, filler size, and filler dispersion, and thus thermographic analysis can be a useful tool to determine the curing and filler dispersion. In this study, we investigated the curing mechanisms of polymer composites at the microscale by capturing real-time temperature using an IR Thermal Camera. Silicone polymers with fillers of Graphene, Graphite powder, Graphite flake, and Molybdenum disulfide (MoS2) were subsequently poured into a customized 3D printed mold for …
Using Nanomaterials As Excellent Immobilisation Layer For Biosensor Design, Azeez Olayiwola Idris, Seyi Philemon Akanji, Benjamin O. Orimolade, Foluke Omobola Grace Olorundare, Shohreh Azizi, Bhekie Mamba, Malik Maaza
Using Nanomaterials As Excellent Immobilisation Layer For Biosensor Design, Azeez Olayiwola Idris, Seyi Philemon Akanji, Benjamin O. Orimolade, Foluke Omobola Grace Olorundare, Shohreh Azizi, Bhekie Mamba, Malik Maaza
Research outputs 2022 to 2026
The endless development in nanotechnology has introduced new vitality in device fabrication including biosensor design for biomedical applications. With outstanding features like suitable biocompatibility, good electrical and thermal conductivity, wide surface area and catalytic activity, nanomaterials have been considered excellent and promising immobilisation candidates for the development of high-impact biosensors after they emerged. Owing to these reasons, the present review deals with the efficient use of nanomaterials as immobilisation candidates for biosensor fabrication. These include the implementation of carbon nanomaterials—graphene and its derivatives, carbon nanotubes, carbon nanoparticles, carbon nanodots—and MXenes, likewise their synergistic impact when merged with metal oxide nanomaterials. …
A Molecular Dynamics Study Of Water Confined In Between Two Graphene Sheets Under Compression, Ming-Lang Tseng, Ayomide Adesiyan, Abdelaziz Gassoumi, Nima E. Gorji
A Molecular Dynamics Study Of Water Confined In Between Two Graphene Sheets Under Compression, Ming-Lang Tseng, Ayomide Adesiyan, Abdelaziz Gassoumi, Nima E. Gorji
Articles
Several studies have demonstrated interest in creating surfaces with improved water interaction and adaptive properties because the behavior of water confined at the nanoscale plays a significant role in the synthesis of materials for technological applications. Remarkably, confinement at the nanoscale significantly modifies the characteristics of water. We determine the phase diagram of water contained by graphene stack sheets in slab form, at T=300 K, and for a constant pressure using molecular dynamics simulations. We discover that, as shown in the simulation, water can exist in both the liquid and vapor phases depending on the confining geometry and compressibility ratio. …