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Full-Text Articles in Engineering
Recent Advances In Graphene-Based Materials For Fuel Cell Applications, Hanrui Su, Yun Hang Hu
Recent Advances In Graphene-Based Materials For Fuel Cell Applications, Hanrui Su, Yun Hang Hu
Michigan Tech Publications
The unique chemical and physical properties of graphene and its derivatives (graphene oxide, heteroatom-doped graphene, and functionalized graphene) have stimulated tremendous efforts and made significant progress in fuel cell applications. This review focuses on the latest advances in the use of graphene-based materials in electrodes, electrolytes, and bipolar plates for fuel cells. The understanding of structure-activity relationships of metal-free heteroatom-doped graphene and graphene-supported catalysts was highlighted. The performances and advantages of graphene-based materials in membranes and bipolar plates were summarized. We also outlined the challenges and perspectives in using graphene-based materials for fuel cell applications.
Synthesis And Characterization Of Free-Stand Graphene/Silver Nanowire/Graphene Nano Composite As Transparent Conductive Film With Enhanced Stiffness, Chuanrui Guo, Yanxiao Li, Yanping Zhu, Chenglin Wu, Genda Chen
Synthesis And Characterization Of Free-Stand Graphene/Silver Nanowire/Graphene Nano Composite As Transparent Conductive Film With Enhanced Stiffness, Chuanrui Guo, Yanxiao Li, Yanping Zhu, Chenglin Wu, Genda Chen
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
As-grown graphene via chemical vapor deposition (CVD) has potential defects, cracks, and disordered grain boundaries induced by the synthesis and transfer process. Graphene/silver nanowire/graphene (Gr/AgNW/Gr) sandwich composite has been proposed to overcome these drawbacks significantly as the AgNW network can provide extra connections on graphene layers to enhance the stiffness and electrical conductivity. However, the existing substrate (polyethylene terephthalate (PET), glass, silicon, and so on) for composite production limits its application and mechanics behavior study. In this work, a vacuum annealing method is proposed and validated to synthesize the free-stand Gr/AgNW/Gr nanocomposite film on transmission electron microscopy (TEM) grids. AgNW …
Synthesis And Characterization Of Free-Stand Graphene/Silver Nanowire/Graphene Nano Composite As Transparent Conductive Film With Enhanced Stiffness, Chuanrui Guo, Yanxiao Li, Yanping Zhu, Chenglin Wu, Genda Chen
Synthesis And Characterization Of Free-Stand Graphene/Silver Nanowire/Graphene Nano Composite As Transparent Conductive Film With Enhanced Stiffness, Chuanrui Guo, Yanxiao Li, Yanping Zhu, Chenglin Wu, Genda Chen
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
As-grown graphene via chemical vapor deposition (CVD) has potential defects, cracks, and disordered grain boundaries induced by the synthesis and transfer process. Graphene/silver nanowire/graphene (Gr/AgNW/Gr) sandwich composite has been proposed to overcome these drawbacks significantly as the AgNW network can provide extra connections on graphene layers to enhance the stiffness and electrical conductivity. However, the existing substrate (polyethylene terephthalate (PET), glass, silicon, and so on) for composite production limits its application and mechanics behavior study. In this work, a vacuum annealing method is proposed and validated to synthesize the free-stand Gr/AgNW/Gr nanocomposite film on transmission electron microscopy (TEM) grids. AgNW …
Corrosion-Induced Mass Loss Measurement Under Strain Conditions Through Gr/Agnw-Based, Fe-C Coated Lpfg Sensors, Chuanrui Guo, Liang Fan, Genda Chen
Corrosion-Induced Mass Loss Measurement Under Strain Conditions Through Gr/Agnw-Based, Fe-C Coated Lpfg Sensors, Chuanrui Guo, Liang Fan, Genda Chen
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
In this study, graphene/silver nanowire (Gr/AgNW)-based, Fe-C coated long period fiber gratings (LPFG) sensors were tested up to 72 hours in 3.5 w.t% NaCl solution for corrosion-induced mass loss measurement under four strain levels: 0, 500, 1000 and 1500 µ∈. The crack and interfacial bonding behaviors of laminate Fe-C and Gr/AgNW layer structures were characterized using Scanning Electron Microscopy (SEM) and electrical resistance measurement. Both optical transmission spectra and electrical impedance spectroscopy (EIS) data were simultaneously measured from each sensor. Under increasing strains, transverse cracks appeared first and were followed by longitudinal cracks on the laminate layer structures. The spacing …
Carbon-Based Interlayers In Perovskite Solar Cells, Aleksandr P. Litvin, Xiaoyu Zhang, Kevin Berwick, Anatoly V. Fedorov, Weitao Zheng, Alexander V. Baranov
Carbon-Based Interlayers In Perovskite Solar Cells, Aleksandr P. Litvin, Xiaoyu Zhang, Kevin Berwick, Anatoly V. Fedorov, Weitao Zheng, Alexander V. Baranov
Articles
Perovskites are solution-processed, high-performance semiconductors of interest in low-cost photovoltaics. The interfaces between the perovskite photoactive layers and the top and bottom contacts are crucial for efficient charge transport and minimizing trapping. Control of the collection of charge carriers at these interfaces is decisive to device performance. Here, we review recent progress in the realization of efficient perovskite solar cells using cheap, easily processed, stable, carbon-based interlayers. Interface materials including graphene, carbon nanotubes, fullerenes, graphene quantum dots and carbon dots are introduced and their influence on device performance is discussed.
Adhesion Of Two-Dimensional Titanium Carbides (Mxenes) And Graphene To Silicon, Yanxiao Li, Shuohan Huang, Congjie Wei, Chenglin Wu, Vadym Mochalin
Adhesion Of Two-Dimensional Titanium Carbides (Mxenes) And Graphene To Silicon, Yanxiao Li, Shuohan Huang, Congjie Wei, Chenglin Wu, Vadym Mochalin
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Two-dimensional transition metal carbides (MXenes) have attracted a great interest of the research community as a relatively recently discovered large class of materials with unique electronic and optical properties. Understanding of adhesion between MXenes and various substrates is critically important for MXene device fabrication and performance. We report results of direct atomic force microscopy (AFM) measurements of adhesion of two MXenes (Ti3C2Tx and Ti2CTx) with a SiO2 coated Si spherical tip. The Maugis-Dugdale theory was applied to convert the AFM measured adhesion force to adhesion energy, while taking into account …