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Full-Text Articles in Engineering

The Role Of The 2,7-Dinitroso-1,8-Dihydroxynaphthalene-3,6-Disulfonic Acid Reagent In Determining The Thorium Ion (Iv), Nigora Qutlimurotova, Salohiddin Mahmadoliyev, Khabibullo Todjimukhamedov Apr 2021

The Role Of The 2,7-Dinitroso-1,8-Dihydroxynaphthalene-3,6-Disulfonic Acid Reagent In Determining The Thorium Ion (Iv), Nigora Qutlimurotova, Salohiddin Mahmadoliyev, Khabibullo Todjimukhamedov

CHEMISTRY AND CHEMICAL ENGINEERING

The aim is to develop a method for the amperometric determination of thorium (IV) ion with 2,7-dinitroso-1,8-dihydroxynaphthalene-3,6-disulfoxyl reagent. Methods of amperometric determination of thorium by solution of 2,7-dinitrozo-1,8-dihydroxynaphthalene-3,6-disulfonic acid on different acid-base properties of background electrolytes and buffer mixtures are considered. The half-wave potential of new reagent was found by logarithmic analysis equal 0.72 V at pH 2.82, which once again indicates on the irreversibility of the process of electrooxidation of the studied organic reagent in used acid-base medias. The conditions for amperometric titration of thorium are optimized, and the influence of outside accompanying metals on the shape of curves …


Synthesis Of 1,2,3-Triazoles Based On Propargyl Ethers Of Carbamate, Djuraev Abdukahhor, Yakubxodjaeva Malika, Ataxodjaeva Matluba, Gaibullaev Oibek Oct 2020

Synthesis Of 1,2,3-Triazoles Based On Propargyl Ethers Of Carbamate, Djuraev Abdukahhor, Yakubxodjaeva Malika, Ataxodjaeva Matluba, Gaibullaev Oibek

CHEMISTRY AND CHEMICAL ENGINEERING

By the interaction of propargyl esters of carbamate derivatives with phenylazide, 1,2,3- triazole derivatives were synthesized. Their anti-inflammatory activity was subsequently studied.During the study of biological activity, a relationship was established between the anti- inflammatory activity and the chemical structure in the studied series of 1,2,3-triazole derivatives.


Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba Oct 2020

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).


Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba Jun 2020

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).