Engineering Commons^™

Two-Dimensional Nanomaterials And Nanocomposites For Sensing, Separation, And Energy Applications, Md Ashiqur Rahman

Theses and Dissertations

Two-dimension (2D) nanomaterials have gained popularity for the last few decades due to their excellent mechanical, electrical and thermal properties. These unique properties of 2D nanomaterials can be exploited in various applications specially in sensor, energy, and separation devices. In this study, the sensing and energy generation performance of PVDF/PAni fiber mat systems made by the forcespinning method with and without graphene coating. The graphene-coated nanocomposites show an average output voltage of 75 mV (peak-to-peak) which is 300% higher compared to bare fiber mats and an output current of 24 mA (peak-to-peak) by gentle finger pressing. Moreover, the graphene-coated PVDF/PAni …

Experimental Characterization And Manufacture Of Polymer Nanocomposite Dielectric Coatings For High-Temperature Superconductor Applications, Jacob Ryan Mahon

Theses and Dissertations

Increased implementation of high-temperature superconducting (HTS) power transmission has the potential to revolutionize the efficiency of electrical grids and help unlock a fully electric transportation infrastructure. Realizing the benefits of HTS systems has been impeded by a lack of available dielectric insulation materials that can 1) withstand the extreme cryogenic operating environment of superconductors and 2) demonstrate low temperature processing that is compatible with existing superconductor manufacturing methods. Solving this problem necessitates a high-performance dielectric material with multifunctional properties specifically suited for operation in HTS systems. A polyamide and silicon dioxide (PA/SiO2) nanocomposite material with exceptional thermal stability has been …

Lubrication Performance Of Vegetable Oils Modified With Halloysite Clay Nanotubes (Hnt) As Lubricant Additives, Md Abu Sayeed Biswas

Theses and Dissertations

Vegetable oil-based nano-lubricants are a great alternative to petroleum-based lubricants because of their less adverse impact on the environment. This work evaluates the tribological performance of sunflower, corn, and peanut oils modified with halloysite clay nanotubes (Al2Si2O2(OH)2nH2O) as lubricant additives at different concentrations. To analyze the tribological performance of the nano-lubricants, a block-on-ring tribometer was used following the ASTM G-077-17 standard procedure. Characterization of HNT was carried out by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Thermogravimetric Analysis (TGA). The effect of the HNT on the lubrication performance of the newly developed vegetable oil-based nano-lubricants was evaluated, and the …

Development Of Vegetable Oil-Based Nano-Lubricants Using Montmorillonite Clay (Mmt) Nanoparticles As Lubricant Additives, Md Mashfiqur Rahman

Theses and Dissertations

Because of the environmental impact and price volatility, there has been a growing concern on the use of petroleum-based lubricants. This issue has stimulated research into the development of biodegradable lubricants like vegetable oils. In this study, the tribological and rheological behavior of sunflower, peanut, and corn oils modified with Montmorillonite nanoclay (MMT) as lubricant additives were evaluated at various concentrations. A custom-made block on ring tribotester was used to evaluate the wear and friction characteristics of the nano-lubricants, following the ASTM G-077-05 standard. The effects of concentration and shear rate on shear viscosity were studied using a parallel plate …

Understanding Heterostructure Chemiresistive Gas Sensing At Room Temperature, Yale Wang

Theses and Dissertations

Chemiresistive sensors are the most widely investigated gas sensors due to their ease in fabrication, cost-effectiveness, simplicity of operation, and offer advances in miniaturization. Up to date, typical and well-researched resistive-type sensing materials include semiconductor metal oxides, noble metals, carbon-based nanomaterials (e.g., graphene and carbon nanotubes), and conducting polymers. Gas sensors based on a single material were found difficult to meet the practical requirements for multi-sensing properties, including sensitivity, selectivity, speed of response/recovery, stability, limit of detection, and room temperature operation. Rational design through a combination of chemically or electronically dissimilar nanomaterials is an effective route to enhancing gas sensing …

Novel Nanostructured Materials For Solar Fuel Production And Advanced Rechargeable Batteries, Cunyu Zhao

Theses and Dissertations

Non-renewable fossil fuels are the major sources to meet the energy, electricity and transportation demands of today's world. The over consumption of fossil fuels will lead to the increasing energy crisis and disastrous effects such as air pollution, global warming etc.

The primary greenhouse gas is CO2 mainly emits from the combustion of fossil fuels. Photocatalytic reduction of CO2 using sunlight as the energy input is a promising way to reduce CO2 level in the atmosphere and in the meantime produce alternative fuels such as CO, methane, methanol, etc. Among the various photocatalyst materials reported, nanomaterial TiO2 is the most …

Tuning The Performance Of Nanocarbon-Based Gas Sensors Through Nanoparticle Decoration, Shumao Cui

Theses and Dissertations

Tin dioxide (SnO₂) is a well–known gas sensing material, but it becomes sensitive only at elevated temperatures (e.g., above 200 °C). Nanoparticles (NPs) combined with nanocarbons, such as carbon nanotubes (CNTs) and graphene, form a new class of hybrid nanomaterials that can exhibit fascinating gas sensing performance due to tunable electron transfer between NPs and nanocarbons induced by gas adsorption. Indeed, sensors made of SnO₂ NPs&ndascoated CNTs have shown outstanding room–temperature sensing performance to various gases, including those that are undetectable by either SnO₂ or CNTs alone.

The objectives of this dissertation study are to synthesize …

Influence Of Media Size And Flow Rate On The Transport Of Silver Nanoparticles In Saturated Porous Media: Laboratory Experiments And Modeling, Travis J. Meidinger

Theses and Dissertations

Silver nanoparticles (AgNPs) are widely produced and used. Because of their potential toxicity and the possibility of their release into the environment, it is important to understand the factors involved in their transport; particularly how they may move in groundwater, which is a potential pathway to human and environmental receptors. By passing a solution of 15 mg/L AgNPs with an average size of 17 nm through sand-filled glass columns, this study looks at the physical effects of flow rate and media size on transport. Three different sand sizes ( 0.074, 0.21-0.297, and 0.4-2.0mm) were used, as well as two different …

Synthesis And Characterization Of One Dimensional Boron-Based Nanomaterials, Rui Li

Theses and Dissertations

One dimensional (1D) metal borate and boride nanomaterials have attracted tremendous attention due to their good chemical inertness, high-temperature stability, excellent mechanical properties, and low thermal expansion coefficient.

Beta-BaB2O4 (BBO) is a well-known nonlinear optical material with a high second-order nonlinear susceptibility, wide transparency range, and high damage threshold. Using a low temperature, organic-free hydrothermal technique, single-crystalline barium polyborate Ba3B6O9(OH)6 (BBOH) nanorods were synthesized. It was found that BBO nanospindles can be achieved by annealing the BBOH nanorods at a relatively low temperature of 810 oC. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) techniques were …