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Theses

Theses/Dissertations

2001

Chromium Reduction

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Reactive Media For Chromium Reduction Under Alkaline Conditions For Use In Permeable Reactive Barriers, Sachin V. Apte Jan 2001

Reactive Media For Chromium Reduction Under Alkaline Conditions For Use In Permeable Reactive Barriers, Sachin V. Apte

Theses

The purpose of this study was to select the appropriate reactive media for chromate reduction to treat groundwater (high pH) with permeable reactive barriers. The study addresses groundwater contamination for three chromium refining sites located in Hudson County, New Jersey. The use of iron (Fe0) as a reactive medium was studied and found to be insufficient for use in permeable reactive barriers because of the high pH conditions of groundwater at these sites. Pyrite and iron (Fe0)-pyrite mixtures were studied as viable reactive media by considering their passivation kinetics, reductive capacities and solubility properties.

Column experiments …