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Improved Hydrogen Storage Properties Of Mgh2 Doped With Chlorides Of Transition Metals Hf And Fe, M Ismail Ismail, Yue Zhao, Xuebin Yu, S X. Dou
Improved Hydrogen Storage Properties Of Mgh2 Doped With Chlorides Of Transition Metals Hf And Fe, M Ismail Ismail, Yue Zhao, Xuebin Yu, S X. Dou
Shi Xue Dou
The effects of HfCl4 and FeCl3 addition on the de/rehydrogenation properties of MgH2 were investigated. Both HfCl4 and FeCl3-doped MgH2 samples started to released hydrogen at about 270 °C, a decreased of about 70 °C and about 140 °C compared to as-milled and as-received MgH2, respectively. In terms of the desorption kinetics, the HfCl4-doped MgH2 sample showed significant improvement, with 6.0 wt.% hydrogen released within 10 min at 300 °C, while the FeCl3-doped MgH2 and undoped MgH2 samples released 3.5 and 0.2 wt.% hydrogen, respectively, under the same conditions. In terms of the absorption kinetics, 5.5 wt.% hydrogen was charged …
Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou
Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou
Shi Xue Dou
Structural and magnetic properties of NdMn2−x Cu xSi2 compounds (x = 0-1.0) have been investigated by high intensity x-ray and resolution neutron diffraction (3-450 K), specific heat, dc magnetization, and differential scanning calorimetry measurements. Substitution of Cu for Mn leads to an increase in the lattice parameter a but a decrease in c at room temperature. Two magnetic phase transitions have been found for NdMn2−x Cu xSi2 compounds with TN for the antiferromagnetic ordering of Mn-sublatttice and TC for the Nd-sublattice ferromagnetic ordering, respectively. TC increases significantly with increasing Cu content from 36 K at x = 0 to 100 …
Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou
Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou
Shi Xue Dou
The structural and magnetic properties of the intermetallic compounds NdMn2−xTixSi2(x = 0, 0.1, 0.2, and 0.3) have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3–450 K. The Curie temperature and Néel temperature of NdMn2Si2 decrease from TC = 36 K and TN = 380 K to TC = 14 K and TN = 360 K, respectively, on substitution of Ti (x = 0.3) for Mn. The magnetocaloric effect at the first order ferromagnetic phase transition at TC, has been investigated in detail. Under a …
Enhancing Superconducting Properties Of Mgb2 Pellets By Addition Of Amorphous Magnetic Ni-Co-B Nanoparticles, Mislav Mustapic, Josip Horvat, Md Shahriar Hossain, Zeljko Skoko, S X. Dou
Enhancing Superconducting Properties Of Mgb2 Pellets By Addition Of Amorphous Magnetic Ni-Co-B Nanoparticles, Mislav Mustapic, Josip Horvat, Md Shahriar Hossain, Zeljko Skoko, S X. Dou
Shi Xue Dou
Amorphous magnetic Ni-Co-B nanoparticles with an average size of 5 nm were added to precursor powders of MgB2 superconductor. The preparation procedure for MgB2 pellets was optimized for obtaining the best critical current density (Jc) at elevated magnetic fields. Addition of Ni-Co-B decreases the Jc for heat treatment of precursor powders at 650 ° C. Heat treatments at 770 ° C and higher improve Jc at 20 and 5 K. This improvement occurs at both temperatures through the increase of the effective connectivity between MgB2 crystals. Vortex pinning was enhanced at 5 K, but not at 20 K. Ni-Co-B nanoparticles …
Thermoelectric Properties Of Ca3co4o9 And Ca2.8bi0.2co4o9 Thin Films In Their Island Formation Mode, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou
Thermoelectric Properties Of Ca3co4o9 And Ca2.8bi0.2co4o9 Thin Films In Their Island Formation Mode, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou
Shi Xue Dou
Ca3Co4O9 and Ca2.8Bi 0.2Co4O9 thin films were fabricated on LaAlO3 (LAO) substrate using pulsed laser deposition technique and were studied for their thermoelectric (TE) properties in Stranski-Krastanov mode for the first time. The thin films consisted of 3D clusters/islands on a 14-nm thick 2D layer with cluster density being higher for Ca 2.8Bi0.2Co4O9 thin films. The clusters also represent areas of dislocation and therefore act as carrier scattering centers, which leads to a temperature-activated type conductivity. Seebeck coefficient as high as 136 and 163 u V/K was measured for the Ca 3Co4O9 and Ca2.8Bi 0.2Co4O9 thin films, respectively, which is …
Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa
Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa
Shi Xue Dou
The layered perovskite compound Sr2-xGdxCoO 4 has not yet been subjected to detailed study so far. In this report, structures, transport, magnetic properties, and first principle calculations will be reported for the two dimensional compounds Sr 2-xGdxCoO4 (x 0.5, 0.75, 1, 1.25). Rietveld refinement revealed that these compounds are crystallized in K2NiF 4-type structures with space group I4/mmm. It was found that the lattice parameter c decreases as x increases. Through the Curies Weiss fitting of the temperature dependent magnetization, it was found that the Sr 1.25Gd0.75CoO4 sample exhibits a weak ferromagnetic to paramagnetic transition at about 62 K, with …
The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou
The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou
Shi Xue Dou
The lithium/sulfur battery is a promising electrochemical system with high capacity, which is well-known to undergo a complex multistep reaction during the discharge process. Two types of electrolytes including poly (ethylene glycol) dimethyl ether (PEGDME)-based and 1.3 - dioxolane (DOL)/ dimethoxyethane (DME)-based electrolytes were investigated here. Furthermore, LiNO3 additive was introduced into the electrolyte in order to effectively eliminate the overcharge effect. The lithium sulfur battery with 1.0 M LiN(CF3SO2)2 in PEGME with 0.1 M LiNo3 shows highly stable reversible capacity of 624.8 mAh g-1 after 200 cycles and improved average coulombic efficiency of 98 percent.
Magnetic Properties Of Bi2femno6: A Multiferroic Material With Double-Perovskite Structure, Yi Du, Zhenxiang Cheng, S X. Dou, Xiaolin Wang, Hua Zhao, Hideo Kimura
Magnetic Properties Of Bi2femno6: A Multiferroic Material With Double-Perovskite Structure, Yi Du, Zhenxiang Cheng, S X. Dou, Xiaolin Wang, Hua Zhao, Hideo Kimura
Shi Xue Dou
Single phase Bi2FeMnO6 was synthesized on Si substrates by an electrospray method. Three peaks were observed in the temperature dependence of magnetization curve, which is attributed to the inhomogeneous distribution of Fe3+ and Mn3+. The observed magnetic peaks at 150 K, 260 K, and 440 K correspond to orderings of the ferrimagnetic Fe–O–Mn, and antiferromagnetic Mn–O–Mn and Fe–O–Fe, respectively. Heat capacity measurements were carried out to confirm these magnetic transitions. The Debye temperature of Bi2FeMnO6 is 339 K, calculated from Debye–Einstein fitting.
A Significant Improvement In The Superconducting Properties Of Mgb2 By Co-Doping With Graphene And Nano-Sic, K S B De Silva, X Xu, Xiaolin Wang, D Wexler, D Attard, F Xiang, S. X. Dou
A Significant Improvement In The Superconducting Properties Of Mgb2 By Co-Doping With Graphene And Nano-Sic, K S B De Silva, X Xu, Xiaolin Wang, D Wexler, D Attard, F Xiang, S. X. Dou
Shi Xue Dou
The effects of graphene (G) and nanosilicon carbide (SiC) co-doping on the superconducting properties of MgB2 were studied using bulk samples. SiC remains one of the best dopants which can significantly improve the high field performance, while graphene is emerging as a new dopant for MgB2, which can improve the zero field critical current density (Jc). The superconducting properties characterized by Jc, the intergrain connectivity, and the critical fields were significantly improved by the use of both SiC and graphene as dopants.
Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou
Anisotropic And Excellent Magnetocaloric Properties Of La 0.7ca0.3mno3 Single Crystal With Anomalous Magnetization, J.C Debnath, Rong Zeng, Jung Ho Kim, Dapeng Chen, S X. Dou
Shi Xue Dou
Magnetic properties and the magnetocaloric effect (MCE) have been investigated in La0.7Ca0.3MnO3 single crystal with applied field along both the ab-plane and the c-direction. Due to the magnetocrystalline anisotropy, the crystal exhibits anisotropy in the MCE. Upon application of a 5 T field, the magnetic entropy changes (SM), reaching values of 7.668 J/(kg K) and 6.412 J/(kg K) for both the ab-plane and the c-direction, respectively. A magnetic entropy change of 3.3 J/(kg K) was achieved for a magnetic field change of 1.5 T at the Curie temperature, TC = 245 K. Due to the absence of grains in the …
Lanthanum Doped Multiferroic Dyfeo3: Structural And Magnetic Properties, Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou
Lanthanum Doped Multiferroic Dyfeo3: Structural And Magnetic Properties, Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou
Shi Xue Dou
Lanthanum doped multiferroic DyFeO3 was synthesized by solid state reaction. X-ray diffraction and refinement show that the lattice parameters of Dy1−xLaxFeO3 increase linearly with the La content. Raman spectroscopy reveals that the short-range force constant in Dy1−xLaxFeO3 is decreased by La3+ ion substitution. The spin reorientation phase transition temperature (TSRPT) is observed to decrease along with the doping level. The antiferromagnetic ordering temperature TN of Fe3+ ions is depressed with increasing doping level. Both decreasing TSRPT and decreasing TN indicate that Fe–Dy and Fe–Fe interactions are weakened by La substitution. It is found that the electron configuration of Fe3+ is …
The Effects Of Size And Orientation On Magnetic Properties And Exchange Bias In Co3o4 Mesoporous Nanowires, Rong Zeng, J Q Wang, Zhixin Chen, Wenxian Li, S. X. Dou
The Effects Of Size And Orientation On Magnetic Properties And Exchange Bias In Co3o4 Mesoporous Nanowires, Rong Zeng, J Q Wang, Zhixin Chen, Wenxian Li, S. X. Dou
Shi Xue Dou
Co3O4 mesoporous nanowires with average single crystalline grain sizes of about 8 nm, 12nm, 25 nm, and 45 nm were synthesized by sintering of microwave-assisted hydrothermal processed belt-Co(OH)2 precursors at 300–500 °C for 2 h. Microstructure analysis was conducted by x-ray diffraction, x-ray photoelectron spectroscopy, Raman spectroscopy, scanning electron microscopy (SEM), field emission SEM (FESEM), transmission electron microscopy (TEM), and high resolution TEM (HRTEM) to confirm the composition, structure, and orientation in the nanowires. Systematic magnetic measurements have also been conducted on the nanowires. It was found that the size and orientation have significant effects on the magnetic and exchange …
The Mechanical And The Electrical Properties Of Conducting Polypyrrole Fibers, Javad Foroughi, Shaban R. Ghorbani, Germanas Peleckis, Geoffrey M. Spinks, Gordon G. Wallace, Xiaolin Wang, S X. Dou
The Mechanical And The Electrical Properties Of Conducting Polypyrrole Fibers, Javad Foroughi, Shaban R. Ghorbani, Germanas Peleckis, Geoffrey M. Spinks, Gordon G. Wallace, Xiaolin Wang, S X. Dou
Shi Xue Dou
The mechanical and the electrical properties of polypyrrole (PPy) fibers and electrochemically deposited PPy films were studied. It was found that the PPy fibers showed a significantly higher strength than the PPy films due to better orientation of the molecular structure. The electrochemically prepared PPy films had a higher electrical conductivity than that of the fibers at high temperature. At low temperature, the PPy fibers showed the higher conductivity. The conductivity results were analyzed in the frame of the three-dimensional variable range hopping model. The results showed that at room temperature the average hopping distance for the fibers was about …
Benzoic Acid Doping To Enhance Electromagnetic Properties Of Mgb2 Superconductors, W. X. Li, Y. Li, M. Y. Zhu, R. H. Chen, X. Xu, W. K. Yeoh, J. H. Kim, S. X. Dou
Benzoic Acid Doping To Enhance Electromagnetic Properties Of Mgb2 Superconductors, W. X. Li, Y. Li, M. Y. Zhu, R. H. Chen, X. Xu, W. K. Yeoh, J. H. Kim, S. X. Dou
Shi Xue Dou
The effect of benzoic acid doping on lattice parameters, microstructure, critical temperature (T-c), critical current density (J(c)) and flux pinning force of MgB2 has been studied. In this work we used benzoic acid as an example of aromatic acids as an additive to MgB2. For different sintering process, actual carbon (C) substitution for boron (B) was estimated to be from 3.5 at% to 5.0 at% of B while T-c dropped about 2-4 K. The advantages of aromatic acid doping include homogeneous mixing of precursor powders, avoidance of expansive nano-additives, production of highly reactive C and significant enhancement in J(c) of …
Fabrication, Magnetic, And Ferroelectric Properties Of Multiferroic Bifeo3 Hollow Nanoparticles, Yi Du, Zhenxiang Cheng, S X. Dou, Darren J. Attard, Xiaolin Wang
Fabrication, Magnetic, And Ferroelectric Properties Of Multiferroic Bifeo3 Hollow Nanoparticles, Yi Du, Zhenxiang Cheng, S X. Dou, Darren J. Attard, Xiaolin Wang
Shi Xue Dou
Hollow BiFeO3 nanoparticles were synthesized by an electrospray route for the first time. The phase purity and structure have been investigated by x-ray diffraction and Raman spectroscopy. Transmission and scanning electron microscope investigations revealed that the as-obtained BiFeO3 hollow spheres were polycrystalline, with a shell thickness of 35 nm. The formation mechanism can be possibly explained by Ostwald ripening. Raman spectra have verified decreased vibrational frequencies in BiFeO3 nanoparticles. These hollow and core-shell multiferroic nanoparticles exhibit significantly enhanced ferromagnetism from 5 to 600 K due to a broken spiral spin structure. The ferroelectricity of hollow BiFeO3 particles exhibits a lower …
Magnetic And Superconducting Properties Of Spin-Fluctuation-Limited Superconducting Nanoscale Vnx, R Zeng, J Liu, G Du, W. X. Li, J Wang, J Horvat, S X. Dou
Magnetic And Superconducting Properties Of Spin-Fluctuation-Limited Superconducting Nanoscale Vnx, R Zeng, J Liu, G Du, W. X. Li, J Wang, J Horvat, S X. Dou
Shi Xue Dou
"VNx nanoparticles and nanowires have been prepared by nitrifying V2O5 nanoparticles (NP) and nanowires (NW). The V2O5 NP and NW were synthesized by a facile hydrothermal method. Magnetic susceptibility (chi) and magnetization measurements showed long range superconducting ordering (LRSO) at the temperature of 5.8 K for NW, but there was no observation of LRSO (at least down to 2 K) for the NP sample, which is a much lower temperature than for the corresponding bulk, while both NP and NW showed the absence of long range magnetic ordering, at least down to 2 K. However, the chi data showed that …
Superconducting Properties Of Carbonaceous Chemical Doped Mgb2, Wenxian Li, S X. Dou
Superconducting Properties Of Carbonaceous Chemical Doped Mgb2, Wenxian Li, S X. Dou
Shi Xue Dou
The discovery of superconductivity in magnesium diboride (MgB2: 39 K, in January 2001) (Nagamatsu et al., 2001) has generated enormous interest and excitement in the superconductivity community and the world in general, but especially among researchers into superconductivity in non-oxide and boron related compounds.
Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou
Single-Crystal Growth And Anisotropic Magnetic Properties Of Nonstoichiometric Three-Layer Sodium Cobalt Oxides, Dapeng Chen, Xiaolin Wang, C T Lin, S X. Dou
Shi Xue Dou
Large single crystals of α-NaxCoO2 (x=0.91, 0.92, and 0.93) have been successfully fabricated by using the traveling solvent floating zone method. Details on the crystal growth are discussed. The crystal structures were characterized using powder x-ray diffraction and Rietveld refinement. The magnetic susceptibility measurements show that the magnetic properties depend strongly on x. The compound was found to be antiferromagnetic at TN ≈ 20 K for x=0.91 and x=0.92, and paramagnetic for x=0.93. The in-plane and out-of-plane anisotropies were observed for the x=0.91 crystals. In addition, the derived anisotropic g-factor ratios (gab /gc) from the anisotropic susceptibility along H||ab and …
Phase Transformation And Superconducting Properties Of Mgb2 Using Ball-Milled Low Purity Boron, Xun Xu, Jung Ho Kim, Md. Shahriar-Al Hossain, Jinsoo Park, Yue Zhao, S. X. Dou, Wai Kong Yeoh, M Rindfleisch, M Tomsic
Phase Transformation And Superconducting Properties Of Mgb2 Using Ball-Milled Low Purity Boron, Xun Xu, Jung Ho Kim, Md. Shahriar-Al Hossain, Jinsoo Park, Yue Zhao, S. X. Dou, Wai Kong Yeoh, M Rindfleisch, M Tomsic
Shi Xue Dou
MgB2 samples were prepared by using 96% boron (B) powder with strong crystalline phase that had been ball milled for various times. We observed samples that contained ball-milled 96% B in comparison with one made from as-supplied commercial 96% B, with the results showing a significant enhancement in the high field critical current density (Jc) due to small grain size and better reactivity. Specifically, many grain boundaries for MgB2 could be acting as strong flux pinning centers. Based on Rowell connectivity analysis, when the ball-milling time increased, the connectivity factor, described as the active cross-sectional area fraction (AF), was decreased. …
"Density Of States, Magnetic And Transport Properties Of Nd Doped Two Dimensional Perovskite Compound Sr2coo4", Qiwen Yao, Hideo Kimura, Xiaolin Wang, Kosta Konstantinov, Hongyang Zhao, Hai Qiu, Rumi Tanahashi, Kiyoshi Ozawa, S. X. Dou
"Density Of States, Magnetic And Transport Properties Of Nd Doped Two Dimensional Perovskite Compound Sr2coo4", Qiwen Yao, Hideo Kimura, Xiaolin Wang, Kosta Konstantinov, Hongyang Zhao, Hai Qiu, Rumi Tanahashi, Kiyoshi Ozawa, S. X. Dou
Shi Xue Dou
"Structures, transport, magnetic properties, and first principle calculation results will be reported for the two dimensional layered structured perovskite compounds Sr2-xNdxCoO4 (x = 0.5, 0.75, 1, 1.25). Structure refinement results revealed that these compounds crystallized in K2NiF4-type structures with space group I4/mmm. The temperature dependence of resistivity showed semiconductor like behavior for these samples. It was found that the lattice parameter c decreases as the doping level x increases. The compounds exhibited a paramagnetic to ferromagnetic transition at temperatures of about 170, 125 K for the x = 1 and 0.75 samples, respectively. The temperature dependence of resistivity for the …
Mechanism Of Enhancement In Electromagnetic Properties Of Mgb2 By Nano Sic Doping, S X. Dou, Olga V. Shcherbakova, W. K. Yeoh, J. H. Kim, Saeid Soltanian, Xiaolin Wang, C. Senatore, R. Flukiger, M. Dhalle, O. Husnjak, E. Babic
Mechanism Of Enhancement In Electromagnetic Properties Of Mgb2 By Nano Sic Doping, S X. Dou, Olga V. Shcherbakova, W. K. Yeoh, J. H. Kim, Saeid Soltanian, Xiaolin Wang, C. Senatore, R. Flukiger, M. Dhalle, O. Husnjak, E. Babic
Shi Xue Dou
A comparative study of pure, SiC, and C doped MgB2 wires has revealed that the SiC doping allowed C substitution and MgB2 formation to take place simultaneously at low temperatures. C substitution enhances Hc2, while the defects, small grain size, and nanoinclusions induced by C incorporation and low-temperature processing are responsible for the improvement in Jc. The irreversibility field (Hirr) for the SiC doped sample reached the benchmarking value of 10 T at 20 K, exceeding that of NbTi at 4.2 K. This dual reaction model also enables us to predict desirable dopants for enhancing the performance properties of MgB2.
Correlation Between Doping Induced Disorder And Superconducting Properties In Carbohydrate Doped Mgb2, Jung Ho Kim, S X. Dou, Sangjun Oh, M Jercinovic, E Babic, T Nakane, Hiroaki Kumakura
Correlation Between Doping Induced Disorder And Superconducting Properties In Carbohydrate Doped Mgb2, Jung Ho Kim, S X. Dou, Sangjun Oh, M Jercinovic, E Babic, T Nakane, Hiroaki Kumakura
Shi Xue Dou
A comprehensive study of the effects of carbohydrate doping on the superconductivity of MgB2 has been conducted. In accordance with the dual reaction model, more carbon substitution is achieved at lower sintering temperature. As the sintering temperature is lowered, lattice disorder is increased. Disorder is an important factor determining the transition temperature for the samples studied in this work, as evidenced from the correlations among the lattice strain, the resistivity, and the transition temperature. It is further shown that the increased critical current density in the high field region can be understood by a recently-proposed percolation model [M. Eisterer et …
Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou
Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou
Shi Xue Dou
As first time, ferroelectric (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ), biocompatible (Na0.5K0.5)NbO3 (NKN), and ferromagnetic Y3Fe5O12 (YIG) nanofibers were synthesized by sol-gel assisted electrospining technique. Non-woven, bead-free 100 μm long fiber mat was formed from close-packed nanocrystals after calcination in air at 800°C (BCTZ and NKN) and 1100°C (YIG). BCTZ fibers are 200 nm in width whereas NKN and YIG fibers have smaller 50-100 nm diameter. X-ray diffraction and Raman spectroscopy show that BCTZ and NKN crystallized in tetragonal and rhombohedral polar phases in the vicinity of morphotropic phase boundary. Room temperature ferromagnetism in YIG fibers is indicated by a well formed M-H hysteresis …
Structure, Ferroelectric Properties, And Magnetic Properties Of The La-Doped Bismuth Ferrite, Zhenxiang Cheng, Aihua Li, Xiaolin Wang, S X. Dou, Kiyoshi Ozawa, Hideo Kimura, S Zhang, Thomas R. Shrout
Structure, Ferroelectric Properties, And Magnetic Properties Of The La-Doped Bismuth Ferrite, Zhenxiang Cheng, Aihua Li, Xiaolin Wang, S X. Dou, Kiyoshi Ozawa, Hideo Kimura, S Zhang, Thomas R. Shrout
Shi Xue Dou
Bi1-xLaxFeO3 ceramics with x=0, 0.1, 0.2, and 0.3 have been synthesized by solid state reaction, starting from metal oxides. A series of structure transformations is found to depend upon the doping level. Below 10% La doping, Bi1-xLaxFeO3 maintains the rhombohedral structure of BiFeO3. However, for Bi0.8La0.2FeO3 and Bi0.7La0.3FeO3, the structures change to the orthorhombic and tetragonal, respectively. La doping significantly reduces electric leakage and leads to successful observation of electrical polarization hysteresis loops. Doping with La also enhances the ferromagnetic moment, due to the broken cycloid spin structure caused by the changes in the crystalline structure.
Structure, Magnetic, And Thermal Properties Of Nd1-Xlaxcro3 (0 ≤ X ≤ 1.0), Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou
Structure, Magnetic, And Thermal Properties Of Nd1-Xlaxcro3 (0 ≤ X ≤ 1.0), Yi Du, Zhenxiang Cheng, Xiaolin Wang, S X. Dou
Shi Xue Dou
Perovskite-type Nd1−xLaxCrO3(0 ≤ x ≤1.0) polycrystalline samples were synthesized using solid state reaction. Structural studies indicate that the lattice parameters, metal–oxygen bond lengths, and angles of Nd1−xLaxCrO3 strongly depend on the La content. Two magnetic transition temperatures, Cr3+ antiferromagnetic ordering temperature (TN) and the spin reorientation phase transition temperature (TSRPT), have been observed in the M-T curves. The increase in TN and decrease in TSRPT with increasing x value can be explained by the change in the magnetic interactions due to La doping. The heat capacity of Nd1−xLaxCrO3 measured from 2 to 300 K reveals that the lattice, electronic, and …
Superconducting Properties Of Graphene Doped Magnesium Diboride, Xun Xu, Wenxian Li, Xiaolin Wang, S. X. Dou
Superconducting Properties Of Graphene Doped Magnesium Diboride, Xun Xu, Wenxian Li, Xiaolin Wang, S. X. Dou
Shi Xue Dou
Graphene, carbon in the form of monolayer sheets, has revealed astonishing and unique chemical and physical properties, which have made it an extremely active research topic in both materials science and physics (Novoselov, K. S. et al., 2004). Through chemical and materials integration, graphene is being actively exploited in a range of technological applications (Stankovich, S. et al., 2006). Superconductors can carry electrical current without any energy dissipation. The combination of both graphene and a superconductor into a composite has great potential for electrical devices and large scale applications. MgB2, a superconductor with a simple composition and two-gap feature has …
Improved Ferroelectric Properties In Multiferroic Bifeo3 Thin Films Through La And Nb Codoping, Zhenxiang Cheng, Xiaolin Wang, S X. Dou, Hideo Kimura, Kiyoshi Ozawa
Improved Ferroelectric Properties In Multiferroic Bifeo3 Thin Films Through La And Nb Codoping, Zhenxiang Cheng, Xiaolin Wang, S X. Dou, Hideo Kimura, Kiyoshi Ozawa
Shi Xue Dou
We report the significant improvement of the ferroelectric properties of BiFeO3thin film through control of electrical leakage by Nb doping. A very large remanent electrical polarization value of 80 µC/cm2 was observed in Bi0.8La0.2Nb0.01Fe0.99O3 thin film on Pt/Ti/SiO2/Si substrate. The doping effect of Nb in reducing the movable charge density due to oxygen vacancies in BiFeO3 was confirmed by the dielectric measurements. A very small loss was observed in the Nb and La codoped BiFeO3 thin film. As well as the improvement in the ferroelectric properties, the magnetic moment was also enhanced due to the doping of La.
Effect Of Boron Powder Purity On Superconducting Properties Of Bulk Mgb2, Xun Xu, Dayse Dos Santos, Jung Ho Kim, Wai Kong Yeoh, Meng J. Qin, Konstantin K. Konstantinov, S. X. Dou
Effect Of Boron Powder Purity On Superconducting Properties Of Bulk Mgb2, Xun Xu, Dayse Dos Santos, Jung Ho Kim, Wai Kong Yeoh, Meng J. Qin, Konstantin K. Konstantinov, S. X. Dou
Shi Xue Dou
In order to study the influence of the amorphous Boron powder on the superconducting properties, MgB2 bulk samples were prepared using 96% and 99% pure commercial Boron powder as well as 92% commercial Boron powder after purification process. The results showed that the original 96% and the purified 92% powders have larger particle size compared to the pure 99% Boron powder, which leads to reduce magnetic critical current densities. In order to get higher performance MgB2, the purified low grade Boron powder need further control of their microstructure such as smaller particle size to enhance flux pinning from the grain …
Superconducting Properties Of Mgb2: Polycarbosilane Versus Conventional Nano-Sic Doping, Olga V. Shcherbakova, Alexey V. Pan, David Wexler, S. X. Dou
Superconducting Properties Of Mgb2: Polycarbosilane Versus Conventional Nano-Sic Doping, Olga V. Shcherbakova, Alexey V. Pan, David Wexler, S. X. Dou
Shi Xue Dou
The effect of polycarbosilane (PCS) doping on the superconducting properties of MgB2 was systematically investigated. Highly reactive C and Si appeared after PCS decomposition facilitating incorporation of C into the MgB2 lattice, as well as the reaction between Si and Mg, resulting in formation of a large number of small Mg2Si particles within MgB2 grains. C-substitution induced crystal lattice defects and impurities act as strong pinning centers, significantly improving Jc(Ba) performance in the high field region. The differences in the effects of SiC and PCS doping have been studied and are described to the structural transformation that occurs in MgB2 …
Effect Of Different Additives On The Hydrogen Storage Properties Of The Mgh 2-Lialh 4 Destabilized System, S X. Dou, Yue Zhao, Xuebin Yu, Mohammad Ismail
Effect Of Different Additives On The Hydrogen Storage Properties Of The Mgh 2-Lialh 4 Destabilized System, S X. Dou, Yue Zhao, Xuebin Yu, Mohammad Ismail
Shi Xue Dou
The hydrogen storage properties of the MgH2-LiAlH4 (4 : 1) composite system with and withoutadditives were studied. 5 wt.% of TiF3, NbF5, NiF2, CrF2, YF3, TiCl3?1/3AlCl3, HfCl4, LaCl3, CeCl3,and NdCl3, respectively, was added to the MgH2-LiAlH4 (4 : 1) mixture, and their catalytic effect wasinvestigated. Temperature programmed desorption results show that addition of metal halides to theMgH2-LiAlH4 (4 : 1) composite system improves the onset desorption temperature. The hydrogendesorption properties of metal halide-doped MgH2-LiAlH4 (4 : 1) composites were also improved ascompared to the undoped MgH2-LiAlH4 (4 : 1) composite. Furthermore, the activation energy andthe change in enthalpy in the …