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Shi Xue Dou

MgB2

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Specific Heat And Magnetic Relaxation Analysis Of Mgb2 Bulk Samples With And Without Additives, C. Senatore, P. Lezza, R. Lortz, Olga V. Shcherbakova, Wai Kong Yeoh, S. X. Dou, R. Flukiger Dec 2015

Specific Heat And Magnetic Relaxation Analysis Of Mgb2 Bulk Samples With And Without Additives, C. Senatore, P. Lezza, R. Lortz, Olga V. Shcherbakova, Wai Kong Yeoh, S. X. Dou, R. Flukiger

Shi Xue Dou

The effects of SiC and Carbon doping on the superconducting properties of MgB2 polycrystalline samples have been analysed by means of specific heat and magnetic relaxation measurements. It is known that the addition of nanometric powders of SiC and C leads to the enhancement of Birr and Jc. However, the underlying physical mechanism is not completely understood. Magnetic relaxation measurements did not show detectable effects of both the additions on the pinning properties of MgB2. It follows that doping acts mainly introducing disorder into the superconductor and thus raising Bc2. In the case of MgB1.9C0.1, specific heat measurements show that …


In-Field Jc Improvement By Oxygen-Free Pyrene Gas Diffusion Into Highly Dense Mgb2 Superconductor, Minoru Maeda, Jung Ho Kim, Y Zhao, Yoon-Uk Heo, K Takase, Y Kubota, C Moriyoshi, F Yoshida, Y Kuroiwa, S X. Dou Jun 2013

In-Field Jc Improvement By Oxygen-Free Pyrene Gas Diffusion Into Highly Dense Mgb2 Superconductor, Minoru Maeda, Jung Ho Kim, Y Zhao, Yoon-Uk Heo, K Takase, Y Kubota, C Moriyoshi, F Yoshida, Y Kuroiwa, S X. Dou

Shi Xue Dou

Oxygen-free pyrene gas as a carbon (C) dopant was delinked and incorporated into highly dense MgB2 structure via a gas phase diffusion method. The technique offers the advantages that molecular C is homogeneously distributed into MgB2 and substituted at the boron sites without any severe deterioration of grain connectivity. The C substitution causes a significant shrinkage of the a-lattice parameter and an increase in the lattice strain, resulting in high disorder. The introduction of structural disorder as a result of C doping leads to a considerable enhancement of the in-field critical current density (Jc) and upper critical field.


Nanocoating Of Particles For Optimal Doping And Universal Enhancement Of Current-Carrying Ability In "Organic" Mgb2-Xcx Superconductors, Olga V. Shcherbakova, Alexey V. Pan, S X. Dou, Rashmi Nigam, David Wexler Jun 2013

Nanocoating Of Particles For Optimal Doping And Universal Enhancement Of Current-Carrying Ability In "Organic" Mgb2-Xcx Superconductors, Olga V. Shcherbakova, Alexey V. Pan, S X. Dou, Rashmi Nigam, David Wexler

Shi Xue Dou

The universal approach of liquid mixing has been found to produce “organic” MgB2−xCx superconductors with structural and supercurrent-carrying properties unattainable by other techniques. We show by transmission electron microscopy combined with energy dispersive spectroscopy that these unique properties are enabled through coating of boron particles with a nanolayer of carbon. The subsequent reaction between carbon-encapsulated boron and magnesium results in enhanced carbon content x in the crystal lattice, as determined by x-ray diffraction pattern analysis. Among various carbon-containing compounds investigated, polycarbosilane has been found to be the optimal dopant for MgB2 superconductor, producing the largest critical current density due to …


Identification Of Factors Limiting The Critical Current Density In Mgb2 _Xcx Superconductors At Low Magnetic Fields, Olga V. Shcherbakova, Alexey V. Pan, Jianli Wang, Andrey Shcherbakov, S. X. Dou, David Wexler Jun 2013

Identification Of Factors Limiting The Critical Current Density In Mgb2 _Xcx Superconductors At Low Magnetic Fields, Olga V. Shcherbakova, Alexey V. Pan, Jianli Wang, Andrey Shcherbakov, S. X. Dou, David Wexler

Shi Xue Dou

Structural analysis and electromagnetic measurements have been performed on a range of samples prepared by the liquid mixing approach to doping MgB2 are sugar, malic acid, and polycarbosilane. The results obtained have allowed us to clarify the contributions of the factors limiting critical current at low magnetic fields in doped MgB2.


Comparison Of Small-Field Behaviour In Mgb2, Low And High Temperature Superconductors, Alexey V. Pan, S X. Dou Jun 2013

Comparison Of Small-Field Behaviour In Mgb2, Low And High Temperature Superconductors, Alexey V. Pan, S X. Dou

Shi Xue Dou

Different types of superconductors have been investigated at small magnetic fields (Ba) over wide temperature (T) ranges at different Ba orientations. It has been shown that the temperature dependence of the characteristic field (B*), separating the Ba-independent critical current density (Jc) plateau (single vortex pinning regime) and the region with Jc(Ba) (collective pinning), can be attributed either to the temperature dependence of the magnetic penetration depth for Nb-film and MgB2bulk superconductors, or to thermally activated processes for Bi-based superconductors and YBa2Cu3O7−δ superconducting films. In both cases the vortex pinning influence appears to have a secondary role, affecting the effective vortex …


Increased Superconductivity For Cnt Doped Mgb2 Sintered In 5t Pulsed Magnetic Field, Wenxian Li, Ying Li, Rong Hua Chen, Rong Zeng, Lin Lu, Yun Zhang, Michael Tomsic, Matthew Rindfleisch, S. X. Dou Jun 2013

Increased Superconductivity For Cnt Doped Mgb2 Sintered In 5t Pulsed Magnetic Field, Wenxian Li, Ying Li, Rong Hua Chen, Rong Zeng, Lin Lu, Yun Zhang, Michael Tomsic, Matthew Rindfleisch, S. X. Dou

Shi Xue Dou

The superconductivity of carbon nanotube (CNT) doped MgB2 sintered in pulsed magnetic field (PMF) was investigated with Raman scattering measurements and Raman spectral fit analysis. Although the carbon (C) substitution for the boron (B) is increased for the sample sintered in PMF, its superconductivity is advanced comparing with the sample sintered without PMF. The improved critical transition temperature, Tc, is attributed to the strengthening of the electron-phonon coupling (EPC) in MgB2, as reflected by the broadened E 2g mode in the Raman spectra, because the carbon atoms are homogeneously distributed in the boron planes.


Improvement Of Jc And Hc2 In Mgb2 Superconductor With Citric Acid Addition, Rong Zeng, Lin Lu, Jianli Wang, Wenxian Li, Dongqi Shi, Josip Horvat, S. X. Dou Jun 2013

Improvement Of Jc And Hc2 In Mgb2 Superconductor With Citric Acid Addition, Rong Zeng, Lin Lu, Jianli Wang, Wenxian Li, Dongqi Shi, Josip Horvat, S. X. Dou

Shi Xue Dou

This paper reports on the fabrication and characterization of citric acid (CA)-C6H8O7 added MgB2 superconductor. The relationships between microstructures, critical current density (Jc), critical temperature (Tc), upper critical field (Hc2), irreversibility field (Hirr), and normal state resistivity for 10 wt% C6H8O7 added MgB2 samples sintered at temperatures from 650C to 950C were systematically studied. A reduction in Tc and in lattice parameter a due to the C substitution and possible oxygen (O) effects occurs wtih C6H8O7 addition. Jc, Hc2, and Hirr are significantly enhanced, however, with the addition of C6H8O7. All the samples exhibit Jc above 104 A/cm2 at 5 …


Reduction Of Superconducting Transition Temperature And Flux Pinning In Al And C Codoped Mgb2 With Insight From First-Principles Calculations, Aihua Li, Xiaolin Wang, S X. Dou, Qiwen Yao, Zhenxiang Cheng, Saeid Soltanian, J M. Yoo, P Munroe Jun 2013

Reduction Of Superconducting Transition Temperature And Flux Pinning In Al And C Codoped Mgb2 With Insight From First-Principles Calculations, Aihua Li, Xiaolin Wang, S X. Dou, Qiwen Yao, Zhenxiang Cheng, Saeid Soltanian, J M. Yoo, P Munroe

Shi Xue Dou

We report for the first time the Al and C codoping effect on the structures and superconductivity in MgB2. It was found that both the lattice parameters and the Tc decreased monotonically with increasing doping level of both Al and C. The Tc dropped to 27.5 and 7 K for x=0.2 and for x =0.4, respectively. The reduction of Tc for the codoping was found to be quicker than for individual Al doping and slower than for individual C doping at the same doping levels. First-principles calculations indicated that the observed decrease in Tc …


Effects Of C Substitution On The Pinning Mechanism Of Mgb2, Jianli Wang, Rong Zeng, Jung Ho Kim, Lin Lu, S. X. Dou Jun 2013

Effects Of C Substitution On The Pinning Mechanism Of Mgb2, Jianli Wang, Rong Zeng, Jung Ho Kim, Lin Lu, S. X. Dou

Shi Xue Dou

The temperature and magnetic field of the critical current density of four selected pure and C-doped MgB2 samples have been investigated in detail and the flux pinning mechanism has been analyzed. It was found that the sintering temperature and the substitution of carbon can significantly modify the flux pinning mechanism. Below 30 K, the reduced field dependences of the reduced pinning force for all investigated samples were found to closely obey one scaling law, reflecting the presence of only one dominant pinning mechanism. A delta T-c pinning mechanism was found to be mainly responsible in pure MgB2 samples while the …


Superconducting Properties Of Carbonaceous Chemical Doped Mgb2, Wenxian Li, S X. Dou Jun 2013

Superconducting Properties Of Carbonaceous Chemical Doped Mgb2, Wenxian Li, S X. Dou

Shi Xue Dou

The discovery of superconductivity in magnesium diboride (MgB2: 39 K, in January 2001) (Nagamatsu et al., 2001) has generated enormous interest and excitement in the superconductivity community and the world in general, but especially among researchers into superconductivity in non-oxide and boron related compounds.


"Organic" Mgb2-Xcx Superconductor With High Performance Enabled By Liquid Mixing Approach, Olga V. Shcherbakova, Alexey V. Pan, Emil Babic, S. X. Dou Jun 2013

"Organic" Mgb2-Xcx Superconductor With High Performance Enabled By Liquid Mixing Approach, Olga V. Shcherbakova, Alexey V. Pan, Emil Babic, S. X. Dou

Shi Xue Dou

Comparative analysis of structural and electromagnetic characteristics have been performed on nano SiC- and polycarbosilane-doped MgB2 samples prepared by the dry and liquid mixing approaches. The total benefit of liquid mixing approach for fabrication of "organic" MgB2 superconductor with excellent electromagnetic performance has been demonstrated


Mechanism Of Enhancement In Electromagnetic Properties Of Mgb2 By Nano Sic Doping, S X. Dou, Olga V. Shcherbakova, W. K. Yeoh, J. H. Kim, Saeid Soltanian, Xiaolin Wang, C. Senatore, R. Flukiger, M. Dhalle, O. Husnjak, E. Babic Jun 2013

Mechanism Of Enhancement In Electromagnetic Properties Of Mgb2 By Nano Sic Doping, S X. Dou, Olga V. Shcherbakova, W. K. Yeoh, J. H. Kim, Saeid Soltanian, Xiaolin Wang, C. Senatore, R. Flukiger, M. Dhalle, O. Husnjak, E. Babic

Shi Xue Dou

A comparative study of pure, SiC, and C doped MgB2 wires has revealed that the SiC doping allowed C substitution and MgB2 formation to take place simultaneously at low temperatures. C substitution enhances Hc2, while the defects, small grain size, and nanoinclusions induced by C incorporation and low-temperature processing are responsible for the improvement in Jc. The irreversibility field (Hirr) for the SiC doped sample reached the benchmarking value of 10 T at 20 K, exceeding that of NbTi at 4.2 K. This dual reaction model also enables us to predict desirable dopants for enhancing the performance properties of MgB2.


Magnetic Field Processing To Enhance Critical Current Densities Of Mgb2 Superconductors, S X. Dou, Wai Kong Yeoh, Olga V. Shcherbakova, Josip Horvat, Jung Ho Kim, Alexey V. Pan, David Wexler, Yongqing Li, W X. Li, Z M. Ren, Paul G. Munroe, J Z. Cui Jun 2013

Magnetic Field Processing To Enhance Critical Current Densities Of Mgb2 Superconductors, S X. Dou, Wai Kong Yeoh, Olga V. Shcherbakova, Josip Horvat, Jung Ho Kim, Alexey V. Pan, David Wexler, Yongqing Li, W X. Li, Z M. Ren, Paul G. Munroe, J Z. Cui

Shi Xue Dou

A magnetic field of up to 12T was applied during the sintering process of pure MgB2 and carbon nanotube(CNT)dopedMgB2wires. The authors have demonstrated that magnetic field processing results in grain refinement, homogeneity, and enhancement in Jc(H) and Hirr. The extent of improvement in Jc increases with increasing field. The Jc for a 10T field processed CNTdoped sample increases by a factor of 3 at 10K and 8T and at 20K and 5T, respectively. Hirr for the 10T field processed CNTdoped sample reached 9T at 20K, which exceeded the best value of SiC dopedMgB2 at 20K. Magnetic field processing reduces the …


Correlation Between Doping Induced Disorder And Superconducting Properties In Carbohydrate Doped Mgb2, Jung Ho Kim, S X. Dou, Sangjun Oh, M Jercinovic, E Babic, T Nakane, Hiroaki Kumakura Jun 2013

Correlation Between Doping Induced Disorder And Superconducting Properties In Carbohydrate Doped Mgb2, Jung Ho Kim, S X. Dou, Sangjun Oh, M Jercinovic, E Babic, T Nakane, Hiroaki Kumakura

Shi Xue Dou

A comprehensive study of the effects of carbohydrate doping on the superconductivity of MgB2 has been conducted. In accordance with the dual reaction model, more carbon substitution is achieved at lower sintering temperature. As the sintering temperature is lowered, lattice disorder is increased. Disorder is an important factor determining the transition temperature for the samples studied in this work, as evidenced from the correlations among the lattice strain, the resistivity, and the transition temperature. It is further shown that the increased critical current density in the high field region can be understood by a recently-proposed percolation model [M. Eisterer et …


Influence Of Heat Treatment On Superconductivity Of Mgb2 Bulk Sintered In Flowing Welding Grade Ar Atmosphere, Yun Zhang, Cheng Lu, Sihai Zhou, K. C. Chung, Y. K. Kim, S. X. Dou Jun 2013

Influence Of Heat Treatment On Superconductivity Of Mgb2 Bulk Sintered In Flowing Welding Grade Ar Atmosphere, Yun Zhang, Cheng Lu, Sihai Zhou, K. C. Chung, Y. K. Kim, S. X. Dou

Shi Xue Dou

In this paper, MgB2 samples were sintered in flowing welding grade Ar. The effect of the sintering time varying from 10 minutes to 3 hours on superconductivity of MgB2 has been investigated. It has been found that both Hc2 and Hirr increase with the sintering time and they have linear relationships with microstrain. The sample sintered for 30 min exhibits the highest Jc at high fields. The reason can be attributed to the improved connectivity and the increased Hc2.


Preparing Mgb2 With Excessive Mg Environment Sintering And Two-Step Sintering Approach, S X. Dou, Sihai Zhou, Alexey V. Pan, Jaimoo Yoo, Yun Zhang, Kookchae Chung Jun 2013

Preparing Mgb2 With Excessive Mg Environment Sintering And Two-Step Sintering Approach, S X. Dou, Sihai Zhou, Alexey V. Pan, Jaimoo Yoo, Yun Zhang, Kookchae Chung

Shi Xue Dou

MgB2 superconductors were made with two processes in this work. In one case, the SiC doped MgB2 pellets were sintered in excessive Mg medium. It is found that the samples sintered in excessive Mg medium present Mg-rich composition comparing with the one sintered in Ar gas. The density is higher and the resistance is lower due to the penetration of the Mg into the pores and grain boundary of MgB2, which is beneficial to the Jc improvement. In the other case, a two-step process was employed to make MgB2. Jc of the sample with the composition of MgB4 is very …


Effect Of Mg/B Ratio On The Superconductivity Of Mgb2 Bulk With Sic Addition, Yun Zhang, S X. Dou, Cheng Lu, Sihai Zhou, Wenxian Li Jun 2013

Effect Of Mg/B Ratio On The Superconductivity Of Mgb2 Bulk With Sic Addition, Yun Zhang, S X. Dou, Cheng Lu, Sihai Zhou, Wenxian Li

Shi Xue Dou

To improve the self-field critical current density (Jc) and critical temperature (Tc) in SiC-doped MgB2, optimization of the nominal Mg/B mixing ratio has been performed. The effects of the nominal Mg/B mixing ratio (x:2) on the superconductivity, Raman spectra, current transport properties, and flux pinning mechanisms in MgB2 with 10 wt.% SiC doping were investigated systematically, with x varied from 1 to 1.2. It has been found that the sample with the Mg/B ratio of 1.15:2 exhibited the best Jc performance for all fields (0–8.5 T), and its Tc was also enhanced. The optimized Mg/B ratio diminished the interband scattering …


Stress/Strain Induced Flux Pinning In Highly Dense Mgb2 Bulks, Rong Zeng, S X. Dou, Lin Lu, Wenxian Li, Chung-Kiak Poh, Jung Ho Kim, Josip Horvat, Dongqi Shi, Jianli Wang, Paul G. Munroe, X. F. Wang, Rongkun Zheng, S. P. Ringer, M Rindfleisch, Mike Tomsic Jun 2013

Stress/Strain Induced Flux Pinning In Highly Dense Mgb2 Bulks, Rong Zeng, S X. Dou, Lin Lu, Wenxian Li, Chung-Kiak Poh, Jung Ho Kim, Josip Horvat, Dongqi Shi, Jianli Wang, Paul G. Munroe, X. F. Wang, Rongkun Zheng, S. P. Ringer, M Rindfleisch, Mike Tomsic

Shi Xue Dou

We have systematically studied the flux pinning behavior of MgB2 bulks synthesized by direct diffusion of Mg into pressed pellets of high purity crystalline B powder, with and without mixing with C and SiC nanoparticles, at a reaction temperature of 850degC for 10 hrs. All of the samples showed very high purity and high density, but their microstructure and flux pinning behavior showed significant differences. It was found that the pure MgB2 agrees with the deltaTc pinning model, nano-C doped MgB2 agrees with the deltal pinning model, while the SiC+MgB2 composite agrees with the deltaepsiv pinning model (stress/strain field pinning), …


Influence Of The Iron Sheath On The Local Supercurrent Distribution In Mgb2 Wires, Marie Roussel, Alexey V. Pan, Sihai Zhou, S X. Dou Jun 2013

Influence Of The Iron Sheath On The Local Supercurrent Distribution In Mgb2 Wires, Marie Roussel, Alexey V. Pan, Sihai Zhou, S X. Dou

Shi Xue Dou

The magnetic behavior of iron sheathed magnesium diboride (MgB2) wires was investigated. Global magnetization measurements have shown unusual critical current density variations compare to a superconductor with no magnetic environment. Local quantitative studies, through MO images, are linked to these global magnetization measurements in order to better understand the observed results. It is shown that the current distribution is affected by the soft magnetic sheath interacting with the superconducting core.


Superconducting Properties Of Mgb2: Polycarbosilane Versus Conventional Nano-Sic Doping, Olga V. Shcherbakova, Alexey V. Pan, David Wexler, S. X. Dou Jun 2013

Superconducting Properties Of Mgb2: Polycarbosilane Versus Conventional Nano-Sic Doping, Olga V. Shcherbakova, Alexey V. Pan, David Wexler, S. X. Dou

Shi Xue Dou

The effect of polycarbosilane (PCS) doping on the superconducting properties of MgB2 was systematically investigated. Highly reactive C and Si appeared after PCS decomposition facilitating incorporation of C into the MgB2 lattice, as well as the reaction between Si and Mg, resulting in formation of a large number of small Mg2Si particles within MgB2 grains. C-substitution induced crystal lattice defects and impurities act as strong pinning centers, significantly improving Jc(Ba) performance in the high field region. The differences in the effects of SiC and PCS doping have been studied and are described to the structural transformation that occurs in MgB2 …


Carbohydrate Doping To Enhance Electromagnetic Properties Of Mgb2 Superconductors, Jung Ho Kim, Sihai Zhou, Md S. Hossain, Alexey V. Pan, S X. Dou Jun 2013

Carbohydrate Doping To Enhance Electromagnetic Properties Of Mgb2 Superconductors, Jung Ho Kim, Sihai Zhou, Md S. Hossain, Alexey V. Pan, S X. Dou

Shi Xue Dou

The effect of carbohydrate doping on lattice parameters, microstructure, Tc, Jc, Hirr, and Hc2 of MgB2 has been studied. In this work the authors used malic acid as an example of carbohydrates as an additive to MgB2. The advantages of carbohydrate doping include homogeneous mixing of precursor powders, avoidance of expansive nanoadditives, production of highly reactive C, and significant enhancement in Jc, Hirr, and Hc2 of MgB2, compared to undoped samples. The Jc for MgB2+30 wt% C4H6O5 sample was increased by a factor of 21 at 5 K and 8 T without degradation of self-field Jc.


Dependence Of Magnetoelectric Properties On Sintering Temperature For Nano-Sic-Doped Mgb2/Fe Wires Made By Combined In Situ/Ex Situ Process, Wenxian Li, Rong Zeng, Jiazhao Wang, Y Li, S. X. Dou Jun 2013

Dependence Of Magnetoelectric Properties On Sintering Temperature For Nano-Sic-Doped Mgb2/Fe Wires Made By Combined In Situ/Ex Situ Process, Wenxian Li, Rong Zeng, Jiazhao Wang, Y Li, S. X. Dou

Shi Xue Dou

Very fine nano-SiC particles (nm) were doped into a MgB2 superconductor. The influence of self-field supercurrent on the high-field performance of the nano-SiC-doped MgB2/Fe wires is discussed based on comparison of the critical current densities of the in situ processed nano-SiCdoped MgB2 wires and those of the nano-SiC-doped MgB2/Fe wires processed by the combination of in situ/ex situ methods.


Kinetic Roughening Of Magnetic Flux Penetration In Mgb2 Thin Films, Andrea Lucarelli, Stephanie Hummert, Andrea Chaney, Gunter Lupke, Brian Moeckly, Yue Zhao, S X. Dou Jun 2013

Kinetic Roughening Of Magnetic Flux Penetration In Mgb2 Thin Films, Andrea Lucarelli, Stephanie Hummert, Andrea Chaney, Gunter Lupke, Brian Moeckly, Yue Zhao, S X. Dou

Shi Xue Dou

Time-resolved magneto-optical studies are performed on MgB2 thin film samples grown by in situ pulsed laser deposition and in situ reactive deposition technique. The latter reveal dendritic avalanche-free flux penetration. The kinetic roughening of magnetic flux penetration is studied for applied ac current. Dynamic scaling laws determined for both static field and ac current are consistent with the directed percolation depinning model, placing the vortex dynamics in MgB2 in the same universality class as YBCO and Nb.


Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou Jun 2013

Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou

Shi Xue Dou

The effect of processing temperature on structural and superconducting properties of 10 wt.% sugar- and 10 wt.% PCS-doped MgB2 wires is systematically investigated. It is demonstrated that these dopants significantly enhance the electromagnetic performance of Fe-clad MgB2 superconductor and increase its potential for practical application. The enhancement of in-field critical current density (Jc(Ba)) and upper critical field (Bc2) is due to formation of a large amount of lattice defects caused by impurities and C substitution into the MgB2 crystal lattice. High temperature sintering of sugar-doped sample results in as high Bc2 value as 37 T (at 5 K), which correlates …


Silicon Oil: A Cheap Liquid Additive For Enhancing In-Field Critical Current Density In Mgb2, Xiaolin Wang, Zhenxiang Cheng, S X. Dou Jun 2013

Silicon Oil: A Cheap Liquid Additive For Enhancing In-Field Critical Current Density In Mgb2, Xiaolin Wang, Zhenxiang Cheng, S X. Dou

Shi Xue Dou

In this work, the authors report on significant flux pinning enhancement in MgB2 that has been easily obtained using a liquid additive, silicon oil. MgB2 bulk samples with 0 up to 30 wt % silicon oil added were prepared by an in situ reaction. Results showed that the Si and C released from the decomposition of the silicon oil formed Mg2Si and substituted into B sites, respectively. Increasing the amount of the Si oil up to 15 wt % has resulted in the reduction of the lattice parameters, as well as Tc and R(300 K)/R(Tc) values, accompanied by a significant …


Specific Heat And Magnetic Relaxation Analysis Of Mgb2 Bulk Samples With And Without Additives, C. Senatore, P. Lezza, R. Lortz, Olga V. Shcherbakova, Wai Kong Yeoh, S. X. Dou, R. Flukiger Jun 2013

Specific Heat And Magnetic Relaxation Analysis Of Mgb2 Bulk Samples With And Without Additives, C. Senatore, P. Lezza, R. Lortz, Olga V. Shcherbakova, Wai Kong Yeoh, S. X. Dou, R. Flukiger

Shi Xue Dou

The effects of SiC and Carbon doping on the superconducting properties of MgB2 polycrystalline samples have been analysed by means of specific heat and magnetic relaxation measurements. It is known that the addition of nanometric powders of SiC and C leads to the enhancement of Birr and Jc. However, the underlying physical mechanism is not completely understood. Magnetic relaxation measurements did not show detectable effects of both the additions on the pinning properties of MgB2. It follows that doping acts mainly introducing disorder into the superconductor and thus raising Bc2. In the case of MgB1.9C0.1, specific heat measurements show that …


Enhancement Of The In-Field Jc Of Mgb2 Via Sicl4 Doping, Xiaolin Wang, S X. Dou, Md S. Hossain, Zhenxiang Cheng, X.Z Liao, Shaban R. Ghorbani, Qiwen Yao, Jung Ho Kim, Tania M. Silver Jun 2013

Enhancement Of The In-Field Jc Of Mgb2 Via Sicl4 Doping, Xiaolin Wang, S X. Dou, Md S. Hossain, Zhenxiang Cheng, X.Z Liao, Shaban R. Ghorbani, Qiwen Yao, Jung Ho Kim, Tania M. Silver

Shi Xue Dou

We present the following results. (1) We introduce a doping source for MgB2, liquid SiCl4, which is free of C, to significantly enhance the irreversibility field (Hirr), the upper critical field (Hc2), and the critical current density (Jc) with a little reduction in the critical temperature (Tc). (2) Although Si can not be incorporated into the crystal lattice, a significant reduction in the a-axis lattice parameter was found, to the same extent as for carbon doping. (3) Based on the first-principles calculation, it is found that it is reliable to estimate the C concentration just from the reduction in the …


Intergrain Connectivity Of Mgb2 Ceramics Studied By Impedance Analysis, C.C Wang, C Wang, Rong Zeng, S X. Dou Jun 2013

Intergrain Connectivity Of Mgb2 Ceramics Studied By Impedance Analysis, C.C Wang, C Wang, Rong Zeng, S X. Dou

Shi Xue Dou

First, by using of the conventional Rowell analysis, we demonstrated that the addition of nano BN particles can effectively eliminate MgO and pores in MgB2 resulting in a very high density and good connectivity of BN-doped MgB2. Then, another method—low-frequency dielectric impedance analysis—was introduced to characterize the properties of the grain boundaries of MgB2. A comparative impedance study was performed in the frequency range from 100 Hz to 100 MHz on pure and nano BN-doped MgB2. The study revealed some following interesting results: (1) a dielectric resonance around frequency of 108 in both samples was observed, which was argued to …


Strong Competition Between The Delta L And Delta T-C Flux Pinning Mechanisms In Mgb2 Doped With Carbon Containing Compounds, Shaban R. Ghorbani, Xiaolin Wang, Md S. Hossain, Qiwen Yao, S X. Dou, Sung-Ik Lee, K C. Chung, Y K. Kim Jun 2013

Strong Competition Between The Delta L And Delta T-C Flux Pinning Mechanisms In Mgb2 Doped With Carbon Containing Compounds, Shaban R. Ghorbani, Xiaolin Wang, Md S. Hossain, Qiwen Yao, S X. Dou, Sung-Ik Lee, K C. Chung, Y K. Kim

Shi Xue Dou

The transport and magnetic properties of 10 wt % malic acid and 5 wt % nanocarbon doped MgB2 have been studied by measuring the resistivity (p), critical current density (jc), connectivity factor (AF), irreversibility field (Hirr), and upper critical field (Hc2). The pinning mechanisms are studied in terms of the collective pinning model. It was found that both mean free path (δl) and critical temperature (δTc) pinning mechanisms coexist in both doped MgB2. For both the malic acid and nanocarbon doped samples, the temperature dependence of the crossover field, which separates the single vortex and the small bundle pinning regime, …


Influence Of Antimony Trioxide Nanoparticle Doping On Superconductivity In Mgb2 Bulk, Yun Zhang, S X. Dou Jun 2013

Influence Of Antimony Trioxide Nanoparticle Doping On Superconductivity In Mgb2 Bulk, Yun Zhang, S X. Dou

Shi Xue Dou

In this work, antimony trioxide (Sb2O3) has been doped into MgB2 samples to act as an additive. The doping level varies from 2.5 to 15 wt%. The effects of Sb2O3 addition on the lattice parameters, critical temperature (Tc), critical current density (Jc), and upper critical field (Hc2) have been investigated in detail. It has been found that Sb2O3 doping results in a small depression in Tc. The Jc value is 2.4 × 103 A·cm−2 for the 2.5% Sb2O3-doped sample at 5 K and 8 T, which is more than two times higher than for the undoped sample. The significant Jc …