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Samuel A Morton

Contact angle; Surfactant; Adsorption; Surface cleaning; Thermodynamic model; Interfacial tension; Hexadecane; Critical micelle concentration; Sodium dodecyl sulfate; Cetyl trymethyl ammonium bromide

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Thermodynamic Method For Prediction Of Surfactant Modified Oil Droplet Contact Angle, Samuel Morton, David Keffer, R. Counce, D. Depaoli, M. Hu Dec 2015

Thermodynamic Method For Prediction Of Surfactant Modified Oil Droplet Contact Angle, Samuel Morton, David Keffer, R. Counce, D. Depaoli, M. Hu

Samuel A Morton

A model applying surfactant self-assembly theory and classical thermodynamics has been developed to aid in the prediction of solid surface cleaning by aqueous surfactant solutions. Information gained from a combination of surfactant self-assembly behavior and cleaning system parameters, such as oil species, surfactant type, temperature, alkalinity, and solid surface type has been shown to provide insight into surface cleaning. The model combines minimization of free energy, pertinent component distribution mechanisms, and surfactant self-assembly processes to provide a methodology for the predicting of oil droplet contact angles. Such predictive capabilities will allow for the development of beneficial environmental and economic changes …