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Materials Engineering

Oxidation

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Morphology And Roughness Of Al2o3 On Ferritic Stainless Steel Foil For Diesel Catalytic Converter Applications, Megan Butala Jun 2012

Morphology And Roughness Of Al2o3 On Ferritic Stainless Steel Foil For Diesel Catalytic Converter Applications, Megan Butala

Materials Engineering

The improved thermal properties of metal-substrate catalytic converters enable effective catalysis sooner after ignition than traditional ceramic monoliths, resulting in less harmful emissions. ACAT Global, a manufacturer of stainless steel catalytic converters, uses ferritic stainless steel substrates for low temperature catalytic converters for diesel automobiles. Production begins with an oxidizing heat treatment to increase surface roughness. The success of the second production step, the application of catalyst-containing ceramic slurry (washcoat), depends on the surface roughness that results from oxidation. Formation of the primary oxide of interest, alumina (Al2O3), is controlled by the stainless steel foil composition, …


Al2O3 Oxide Morphology For Two Fe-Cr-Al Stainless Steel Foils Used In Gasoline Engine Catalytic Converters, Jennifer Suiter Jun 2012

Al2O3 Oxide Morphology For Two Fe-Cr-Al Stainless Steel Foils Used In Gasoline Engine Catalytic Converters, Jennifer Suiter

Materials Engineering

Corrugated 0.05 in thick strips of Fe-Cr-Al ferritic stainless steel samples with 4% and 6% aluminum were heat treated, and the resulting Al2O3 oxide was analyzed using SEM imaging. Three heat treatment cycles were carried out for each sample. The heat treatments were based on future metal-substrate catalytic converter processing prior to applying the washcoat Each heat treatment started with a 90 minute ramp from room temperature to 538°C and a 32.5 minute ramp from 538°C to 899°C. The three different dwell periods at 899°C were 4 hours, 6 hours, and taking a sample out every hour …


Characterization Of The Oxidation Kinetics Of Fecral Ferritic Stainless Steels At 900°C For Catalytic Converter Applications, Stacy Stamm Jun 2011

Characterization Of The Oxidation Kinetics Of Fecral Ferritic Stainless Steels At 900°C For Catalytic Converter Applications, Stacy Stamm

Materials Engineering

This study characterized the oxidation kinetics of two types of ferritic stainless steel foils used as substrates for catalytic converters. Catalytic converters rely on an alumina layer on the surface of the foils, which allows the catalyst to attach to the substrate. Because the alumina layer is so important, this study characterized the weight gain, thickness, and composition of the alumina as it grew at 900°C for up to 400 hours. The two foils characterized were an MK foil, used for gasoline engines, and an EMS foil, used for diesel engines. The MK foil showed a percent weight gain of …