Engineering Commons^™

Electrostatic Nanosmearing Architecture Of Additive Functional Groups During High Shear Mixing Of Pharmaceutical Blends, Sajan Kumar Chatarla

Masters Theses

The main objective of the research project is to detect and quantify the rate and extent of nanosmearing of hydrophobic functional groups of additives on multiple pharmaceutical particles during high shear mixing of formulations due to electrostatics affecting critical blend properties on the bulk scale. We accomplished this task by systematically detecting the electrostatics during powder flow and its consequence on the nanosmearing distribution of additives during mixing. In the first stage, the electrostatic behavior of particles was correlated to the powder flow. Secondly, its relative influence on nanosmearing of additives during mixing was determined by developing a methodology to …

Measurement Of Activity And Stability Of Physical Vapor Deposition (Pvd) Coated Crystal Surfaces, Anuradha Krishnan

Masters Theses

The overall objective of this research work is to investigate the hydrophilic and hydrophobic forces acting on organic crystal planes and understanding the interaction of functional groups with additive molecular nanolayers. Crystals of acetaminophen and lactose were made and the surface forces were tested on Atomic Force Microscope (AFM). Uniformity of crystal surface was confirmed from the AFM study in the first stage. The growth factors of crystal planes as a function of time were studied. Adhesion forces on plain crystals were measured on both two different organic crystals made of acetaminophen and lactose. In the second stage, …

Preliminary Investigation For The Development Of Surrogate Debris From Nuclear Detonations In Marine-Urban Environments, Adam G. Seybert

Masters Theses

No nuclear weapon has ever been detonated in a United States city. However, this also means the nuclear forensic community has no actual debris from which to develop analytical methods for source attribution, making the development of surrogate nuclear debris a vital undertaking. Moreover, the development of marine-urban debris presents an unusual challenge because unlike soil and urban structures, which remain compositionally consistent, the elemental composition of harbor and port waters fluctuates considerably due to natural phenomenon and human activity. Additionally, marine vessel composition and cargo can vary dramatically. While early US nuclear tests were carried out in shallow-water coastal …

Lignin Maximization: Analyzing The Impact Of Different Feedstocks And Feedstock Ratios Using Organosolv Fractionation, Marc Banholzer

Masters Theses

Over-exploitation of fossil fuels coupled with increasing pressure to reduce carbon emissions are prompting a transition from conventional petrochemical feedstocks to sustainable and renewable sourced carbon. The use of lignocellulosic biomass as a feedstock for integrated biorefining is of current high interest, as separation into its component parts affords process streams of cellulose, hemicellulose and lignin, each of which can serve as a starting point for the production of biobased chemicals and fuels. Given the large number of potential sources of lignocellulosic feedstocks, the biorefinery will need to adapt to the supplies available over a normal growing season. Of particular …

Synthesis And Characterization Of Porous Liquids, Yuanyou Gao

Masters Theses

Porous liquids consisting of modified hollow spheres which are fabricated by surface engineering with suitable corona and canopy species is one of interesting porous liquids reported recently. By taking advantage of the liquid-like polymeric matrices as a separation medium and the empty cavities as a gas transport pathway, porous liquids can function as promising candidates for postcombustion gas separation and thermal insulation purposes. Moreover, this synthetic strategy can be applied to other nanostructure-based porous liquids, facilitating production of porous liquids with specific request. In this thesis, a new member of this type of porous liquid with hollow spheres ranging from …

Effects Of Ultrasonic Transducers On Heat Transfer In Packed Particle Beds, David Patrick Moseley

Masters Theses

The objective of this study was to determine the effects of ultrasonic transducers on heat transfer in a packed particle bed heat exchanger. Although substantial research has been devoted to ultrasound, and the associated improvements in heat transfer, data regarding the effects on packed particle beds is non-existent. This is of particular interest given the potential to improve heat transfer in a wide variety of packed particle bed systems. A 42.9% increase in the heat transfer rate was demonstrated as the result of improved fluid convection throughout the packed particle bed. Secondary effects, including acoustic cavitation, acoustic streaming and local …

The Effect Of Flexibility On Interaction Of Two Fibers Settling In Moderate Reynolds Numbers, Ahmed Alhasan

Masters Theses

The behavior of solid particles in a fluid has become an important topic. The need to improve our understanding of the mechanisms of fluid-particle interaction is the motivation for the present work. The characteristics of fibers suspensions depend on the many variables such as flexibility, Reynolds numbers, density and aspect ratio. The aim of this work is to probe effects of these variables on sedimentation behavior by using a fiber-level simulation technique. In this techniques, a D3Q15 model in a lattice Boltzmann equation with a Bhatnagar-Gross-Krook (BGK) approximation is used to simulate motion of fluids, where Navier-Stokes equations are solved …

Modeling The Thermodynamics And Dynamics Of Fluids Confined In Three-Dimensionally Ordered Mesoporous (3dom) Carbon Materials, Anish Julius Desouza

Masters Theses

Porous materials have application in adsorption based processes due to their high internal surface area and tailorable pore size. They find uses in fields such as catalysis, separation, biotechnology, and microelectronics. Fluids confined in such materials exhibit interesting behavior in regards to the condensation and evaporation mechanisms. Understanding study the behavior of fluids confined in these porous materials is necessary for the efficient design of these materials. The adsorption/desorption isotherm provides valuable information about the effect of network features like pore connectivity and pore size distribution on fluid behavior during pore condensation and evaporation. Such insight can be useful in …

Minimization Of Metamerism In Wood Grain Printing Using Different Gcr Settings, Vinay Anil Turke

Masters Theses

In printing industry, prototyping is necessary to ensure quality reproduction of jobs. Conventional printing processes like gravure cannot be used for prototyping because of high manufacturing cost of gravure cylinders. Such challenges can be successfully tackled by use of relatively cheap and flexible printing processes, such as inkjet. Even though inkjet printing is a cost effective way for prototyping, it has its own limitations, especially in the case of woodgrain printing. Wood-grain patterns need to be printed with a release coating and adhesive. Inkjet printers are incapable of printing release coating and adhesive because release coat and adhesive require certain …

Cd Transport In Eutectic Licl-Kcl And Contamination Of Zr Metal And Thermal Dehydration Of Bulk Licl-Kcl, Nicholas Azoy Earle

Masters Theses

Researchers at Idaho National Labs have noted unexpectedly high Cd content in empty cladding hulls after processing in the Mark-IV ER. It has been theorized that Cd metal is transporting from the LCC pool through the eutectic LiCl-KCl salt bath to the anode baskets containing the empty hull where it is retained as a Zr-Cd intermetallic. This study sought to replicate the Cd contamination in a dry Ar glovebox using small-scale analogue of the Mark-IV ER salt-Cd metal system.

Anhydrous eutectic LiCl-KCl was an essential regent in this research and experiments were conducted to investigate the feasibility of dehydrating nominally …

Integrated Solar Technologies With Outdoor Pedestrian Bridge Superstructure Decking, Richard K. Racz

Masters Theses

Solar technology has been a major topic in sustainable design for many years. In the last five years, however, the solar technology industry has seen a rapid growth in installations and technological advances in cell design. Combined with a rapidly declining overall system cost, the idea of introducing solar technology into a wider range of applications is becoming a focus for engineers and scientists around the world. So many variables which alter solar energy production, such as the sun and surrounding environment, determine whether a solar design is beneficial. This thesis presents a bridge deck surface integrated with solar cells …

The Impact Of Heat Exchanging Internals On Hydrodynamics Of Bubble Column Reactor, Ahmed Jasim

Masters Theses

"In this study, the impact of configuration and size of vertical heat exchanging internals in bubble columns on gas holdup, specific gas-liquid interfacial area, bubble chord length, and bubble rise velocity were investigated. Three different configurations of internals, each covering 25% of the column's cross-sectional area, were used to simulate the heat exchanging tubes utilized in the F-T process. The First configuration is a circular-like arrangement of 0.5 inch diameter vertical rods, whereas the second is a hexagonal-like arrangement of 0.5 inch diameter vertical rods. The third configuration is also a circular arrangement but of 1 inch diameter vertical rods …

Effect Of Reservoirs Heterogeneity On Injection Pressure And Placement Of Preformed Particle Gel For Conformance Control, Ze Wang

Masters Theses

"Preformed particle gels (PPG) have been successfully applied as a plugging agent for plugging fractures and then divert displacing fluid into poorly swept zones. However, PPG propagation and plugging mechanisms through open fractures have not been studied thoroughly.

This work investigated the influence of some factors (particle size, brine concentration, heterogeneity, and brine salinity) on gel injectivity, plugging performance for water flow through open fractures. Five-foot tubes were used to mimic open fractures. Three models were designed to conduct the work, including (1) single fracture with uniform fracture width, (2) single fracture with different widths, and (3) two parallel fractures …

Characterization Of Fracture Initiation In Non-Cylindrical Buckle Folds Using 3d Finite Element Analysis, Eli Jacob Steinbeck

Masters Theses

"The spatial distribution of fracture sets associated with buckle folds has been well documented in field studies. There are difficulties, however, in placing accurate constraints on the timing of the initiation of individual fracture sets during the deformation history of the fold under in-situ conditions. This study investigates specific conditions that give rise to the initiation of various fracture sets in the hinge and limb of a pericline, based on an analysis of the effective stress evolution during the processes of buckling and erosional unloading. A 3D finite element modeling approach is used to simulate the effective stress evolution in …

Fluid Flow Through Deformation Band, Huining Zhang

Masters Theses

"Cataclastic deformation bands, which are common in porous sandstone, have the potential to restrict fluid flow. Geological studies have shown that permeability of deformation band shear zones can be one to five orders of magnitude less than for the sandstone host rock. However, recent studies based on simplified analytical estimates have shown that fluid flow in jointed deformation bands may not be retarded since joints play an important role in conducting fluids. In this study, 2 dimensional finite element analysis (FEA) is used to simulate the total discharge flow rate through jointed deformations. Variations of single planar and conjugate jointed …

Iron Phosphide Nanostructures As An Efficient Bifunctional Catalysts For Water Splitting, Nikitaa Ashokan

Masters Theses

"The first part of this thesis work focuses on developing a bifunctional catalyst for electrochemical water splitting encompassing both oxygen and hydrogen evolution. A highly efficient catalyst is necessary to improve kinetics of the sluggish four electron process for oxygen evolution reaction (OER) and two-electron process for hydrogen evolution reaction (HER). Recently, transition metal phosphides have gained increasing interest in this field because of their good electrical conductivity properties as well as better catalytic activity. Many transition-metal phosphides are being considered for this application and iron phosphide (FeP) has proved to be a good HER catalyst. In this work, we …

Experimental Evaluations Of Selected Sealants To Remediate Co₂ Leakage, Aaron Jeffrey Blue

Masters Theses

"Carbon Dioxide (CO₂) sequestration into porous and permeable brine-filled aquifers is seen as one of the most feasible solutions for reducing the amount of greenhouse gases released into the atmosphere from coal-fired power plants. To safely store the CO₂, it must be trapped under an impermeable rock acting as a seal. One of the concerns with CO₂ sequestration is the generation of new fractures or reopening of existing fractures caused by CO₂ injection in the sealing formation. This project evaluates the potential of sealing these fractures by injecting sealing materials into them. These sealing …

Evaluation Of Highly Viscous Polymeric Fluids And Recrosslinked Degraded Gel, Danlu Zhang

Masters Theses

”This work presents the evaluations of two products. One can be used for hydraulic fracturing to achieve viscosity stable under high shear rate, and the other is potential to be applied to enhance oil recovery from mature oilfield.

The first experiment is to synthesize and evaluate a new polymeric fracturing fluid that can resist high shear rate of 511^-1 with favorable viscosity. Zirconium crosslinked fracturing fluids are lack of self-healing ability after shearing, and the difficulties still exist in maintaining viscous with lower polymer content exposed to high shearing conditions, therefore, the research is trying to develop a new …

Data Analysis Of Surfactant-Induced Wettability Alteration In Carbonate Reservoirs, Hao Sun

Masters Theses

"Most carbonate formations prove to be oil-wet due to oil aging effect. Therefore it is essential to employ wettability alteration methods for a more effective enhanced oil recovery process. It is confirmed by researchers that surfactant treatment has positive effects on wettability alteration of carbonate rock, from strong oil-wet to intermediate wet or to even weak water-wet. A number of experiments have the same conclusion and yet, a systematic screening guide development with the support of sufficient data analysis is lacking.

This study involves screening guide development for surfactant-induced wettability alteration method. 199 experiments collected from published literatures are analyzed …

Study On The Applicability Of Relative Permeability Modifiers For Water Shutoff Using Numerical Simulation, Dheiaa Khafief Khashan Alfarge

Masters Theses

"Water production is a challenging problem to be controlled during hydrocarbon-reservoirs production life. Disproportionate Permeability Reduction (DPR) is often used as water shutoff treatment in production wells when other conventional solutions like mechanical isolations are difficult to perform. This study applied numerical simulation methods to diagnose the factors impacting DPR treatment success on macroscopic level and to see when, where and at which conditions DPR treatment can give best results.

This work indicated that the following points should be considered before DPR treatment is executed in any reservoir to get a successful treatment. Firstly, this research explored that DPR performance …

Evaluating Completion Performance For Gas Wells In The Upper And The Lower Montney Formation, Canada, Omar Qasim Mohammed

Masters Theses

"Identifying the key drivers for success of multiple fractured horizontal wells is not straightforward, especially in unconventional reservoirs like the Montney. Al-Alwani et al. (2015) provided a statistical analysis of Montney completions based on publicly available data. They showed that for the entire well population, cumulative gas recovery per stage, declines as the number of completed stages increase. However, their statistical analysis did not differentiate between completions in the Upper/Middle/Lower Montney, and did not include perforation cluster data.

This work documents the statistical analysis of 296 cased-hole horizontal gas well completions reported in the Upper and the Lower Montney. The …

Mitigation Of Wellbore Instability In Deviated Wells By Using Geomechanical Models And Mpd Technique, Husam Raad Abbood

Masters Theses

"During drilling operations for the E oilfield in the Mishrif formation in southern Iraq, stuck pipe presents a significant wellbore stability problem for deviated wells. In this study, two solutions are utilized to address this problem. The first approach is a 1-D Geomechanical model of the Mishrif formation compiled based on the state of stress and rock strength parameters. It is utilized to assess the contribution of borehole collapse leading to the stuck pipe problems. The results of this study show that wells characterized by stuck pipe are drilled along azimuths which promote wellbore collapse. Three different failure criteria, the …

Single Phase Gas Flow Response Of Fractured Horizontal And Vertical Wells To Repeated Production, Divya Kandlakunta

Masters Theses

"Historically, the conventional approach to well production has been to produce continuously, minimizing interruptions to flow insofar as possible. Yet some operators have observed improved well flow rates and ultimate recovery after a significant well shut-in periods. These production increases have not been documented. This study investigates the production impact of cyclic production/shut-in on fractured vertical and horizontal gas well performance.

A numerical reservoir model in Stimplan software was used to model production in fracture stimulated vertical and horizontal gas wells. Reservoir permeability is varied over a range of 0.0001 md to 1 md, and the shut-in period was varied …

Bioresponsive Polymer Coating On Nanoparticles, Tunyaboon Laemthong

Masters Theses

"Nanotechnology incorporated with molecular biology became a promising way to treat cancer. The size of nanoparticles enables them to overcome the side effects noticed in cancer treatment like chemotherapy and surgery. Various types and shapes of nanoparticles have been synthesized and used in drug delivery to tumor sites. However, one of problems of using these nanoparticles is the aggregation after injecting them into human body due to flow rate of bloodstream. The coagulation and aggregation will result in clogging blood vessel and lower therapeutic efficacy.

In this thesis, a solution to the aggregation problem was proposed, which is coating biopolymer …

Study And Development Of Robust Preformed Particle Gels For Conformance Control, Yifu Long

Masters Theses

"To improve the oil recovery of mature reservoirs, technologies referring to conformance control have been widely developed and implemented. Among various technologies, preformed particle gel (PPG) treatment has attracted increasing attentions. PPGs, as a kind of deformable plyometric superabsorbent, could be pumped through injection wells as plugging agents to block the fracture or high-permeability zone in a reservoir.

In decade usage of PPGs, an intensively employed material is poly(acrylamide) (PAM) based hydrogel. However, conventional PAM gel did reveal deficient in formidable conditions, such as formations with high temperature and high salinity. Therefore, a novel PPG based on starch-grafting-poly(acrylamide)/nano-composite (SAC) hydrogel …

Numerical Analysis Of Flexural Slip During Viscoelastic Buckle Folding, Davi Rodrigues Damasceno

Masters Theses

"Flexural slip is considered to be an important folding mechanism contributing in the development of different folds such as chevron, and kink-band buckle folds. Various filed studies have provided a general conceptual and qualitative understanding of flexural slip. However, quantitative evidence of the importance of the flexural slip mechanism during fold evolution is sparse, as the actual amount of surface parallel displacement, and timing, is difficult to measure accurately, due to the lack of suitable strain markers.

In this study 2D finite element analysis is used to overcome these disadvantages and to simulate flexural slip during viscoelastic buckle folding. Variations …

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO₂ emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO₂ into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C₂-C₄) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …

Impact Of Repeated Cyclic Production Scheme On Eur In Low-Permeability Reservoirs, Samarth Gupte

Masters Theses

"Productivity in low-permeability reservoirs declines quickly compared to conventional reservoirs. These tight reservoirs have very high initial oil production rates but as soon as the oil near the fractured area is recovered, the production declines rapidly making economic oil and gas production a challenge for the industry. This study investigates the impact of repeated shut-in/production cycles on the ultimate recovery of oil in such environments.

A reservoir model with multiple fractured horizontal well having 30 transverse fractures is created using CMG. Reservoir permeability is varied over the range of 0.000001 md to 10 md and shut-in/production cycles of 2-weeks, 1-month, …

Conceptual Parameters Necessary For Modeling Wettability Alteration In An Enhanced Smart Brine-Chalk System, Ahmed Abdulkareem Hussein Albahrani

Masters Theses

"Achieving higher recovery of oil from proven carbonate reserves around the world is not an easy task. One promising new method, especially for carbonate reservoirs, is the use of "Smart Water" technology, which is an injection water with carefully determined, optimal ionic composition and salinity. Recent experiments have shown good recovery results, but the mechanism of wettability alteration by this fluid are still not well understood. The goal of this study is to review the high and optimal salinity and ionic composition literature plus perform dimensional analysis of key variables in order to shed light on the physical and chemical …

Mixed Metal Oxide Catalysts Supported On H-Beta For Hydrogenolysis Of Glycerol Into 1,3-Propanediol, Amit Kant

Masters Theses

"Bioglycerol is the by-product which is produced largely from the microbial fermentation, hydrogenolysis of glucose in the mixture of polyols, fatty ester, soap manufacturing process and fatty acid production. Hydrogenolysis of glycerol is one of the most promising ways to convert glycerol and many work has been done towards 1,3-propanediol, 1,2-propanediol and 1-propanol using various metals and mixed-metal oxides such as W, Ru, Rh, Pt, Pd, Cu, Ni and different zeolites have been extensively used as the active components.

It has been well documented that the presence of Bronsted acid sites leads to the formation of acrolein, while Lewis acid …