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Particle And Dredge-Scale Kinetic Studies Of Hydrophobic Organic Chemical Desorption From Sediment, Justin Edward Birdwell
Particle And Dredge-Scale Kinetic Studies Of Hydrophobic Organic Chemical Desorption From Sediment, Justin Edward Birdwell
LSU Doctoral Dissertations
The discharge of hydrophobic organic chemicals (HOCs) and other hazardous substances from anthropogenic sources to surface waters and the atmosphere has led to the widespread contamination of bottom sediments throughout the world. HOCs collect in sediments due to their affinity for organic matter and other sorbents present on and within their solid matrices. There is interest in the movement of HOCs from historically contaminated, resuspended sediments to surface waters due to the connection between chemical desorption and bioavailability. Quantitatively accurate predictions of contaminant concentrations in environmental media are needed for reliable risk assessment and to develop strategies for protection of …
Measurement Of Metal Migration In Sediment Caps With X-Ray Fluorescene, Ming Yin
Measurement Of Metal Migration In Sediment Caps With X-Ray Fluorescene, Ming Yin
LSU Doctoral Dissertations
ABSTRACT Sand is often used as a passive barrier to slow release of metals from the sediment and to separate benthic organisms from the sediment. Materials that effectively adsorb metals have the potential to provide significantly greater effectiveness by further retarding metal release. In this thesis, the effectiveness of apatite and Phosphil®, which contain phosphate in a form that can absorb many metals, is evaluated with a series of sorption and migration column experiments using Cr, Cu, Zn and Pb. Langmuir shape isotherms were observed suggesting that the effectiveness of these materials decreases at high concentration. The sorption isotherm experiments …