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Full-Text Articles in Engineering
V2o5/Mesoporous Carbon Composite As A Cathode Material For Lithium-Ion Batteries, Mohammad Ihsan, Qing Meng, Li Li, Dan Li, Hongqiang Wang, Kuok Hau Seng, Zhixin Chen, Shane J. Kennedy, Zaiping Guo, Hua-Kun Liu
V2o5/Mesoporous Carbon Composite As A Cathode Material For Lithium-Ion Batteries, Mohammad Ihsan, Qing Meng, Li Li, Dan Li, Hongqiang Wang, Kuok Hau Seng, Zhixin Chen, Shane J. Kennedy, Zaiping Guo, Hua-Kun Liu
Faculty of Engineering and Information Sciences - Papers: Part A
V2O5/mesoporous carbon composite has been prepared by an ultrasonically assisted method followed by a sintering process. The as-prepared V2O5/mesoporous carbon material containing 90 wt% V2O5 shows better electrochemical performance, with capacity of 163 mA h g-1 after 100 cycles at the current density of 500 mA g-1, as well as better charge/discharge rate capability for lithium storage than V2O5 nanoparticles. The improved electrochemical performance indicates that the V2O5/mesoporous carbon composite could be used as a promising cathode material for …
Structural Evolution Of Electrodes In The Ncr And Cgr Cathode-Containing Commercial Lithium-Ion Batteries Cycled Between 3.0 And 4.5 V: An Operando Neutron Powder-Diffraction Study, Wei Kong Pang, Moshiul Alam, Vanessa K. Peterson, Neeraj Sharma
Structural Evolution Of Electrodes In The Ncr And Cgr Cathode-Containing Commercial Lithium-Ion Batteries Cycled Between 3.0 And 4.5 V: An Operando Neutron Powder-Diffraction Study, Wei Kong Pang, Moshiul Alam, Vanessa K. Peterson, Neeraj Sharma
Faculty of Engineering and Information Sciences - Papers: Part A
The dissimilar lattice-evolution of the isostructural layered Li(Ni,Co,Al)O2 (NCR) and Li(Ni,Co,Mn)O2 (CGR) cathodes in commercial lithium-ion batteries during overcharging/discharging was examined using operando neutron powder-diffraction. The stacking axis (c parameter) of both cathodes expands on initial lithiation and contracts on further lithiation. Although both the initial increase and later decrease are smaller for the CGR cathode, the overall change between battery charged and discharged states of the c parameter is larger for the CGR (1.29%) than for the NCR cathode (0.33%). We find these differences are correlated to the transition metal to oxygen bond (as measured through …
A Fe/Fe3o4/N-Carbon Composite With Hierarchical Porous Structure And In Situ Formed N-Doped Graphene-Like Layers For High-Performance Lithium Ion Batteries, Yao Li, Qing Meng, Shenmin Zhu, Zeng-Hui Sun, Hao Yang, Zhixin Chen, Chengling Zhu, Zaiping Guo, Di Zhang
A Fe/Fe3o4/N-Carbon Composite With Hierarchical Porous Structure And In Situ Formed N-Doped Graphene-Like Layers For High-Performance Lithium Ion Batteries, Yao Li, Qing Meng, Shenmin Zhu, Zeng-Hui Sun, Hao Yang, Zhixin Chen, Chengling Zhu, Zaiping Guo, Di Zhang
Faculty of Engineering and Information Sciences - Papers: Part A
Fe/Fe3O4/N-carbon composite consisting of a porous carbon matrix containing a highly conductive N-doped graphene-like network and Fe/Fe3O4 nanoparticles was prepared. The porous carbon has a hierarchical structure which is inherited from rice husk and the N-doped graphene-like network formed in situ. When used as an anode material for lithium batteries, the composite delivered a reversible capacity of approximately 610 mA h g(-1) at a current density of 200 mA g(-1) even after 100 cycles, due to the synergism between the unique hierarchical porous structures, highly electrically conductive N-doped graphene- like networks and nanosized particles of Fe/Fe3O4. This work provides a …
Novel Experimental Setup For Time-Of-Flight Mass Spectrometry Ion Detection In Collisions Of Anionic Species With Neutral Gas-Phase Molecular Targets, J C. Oller, L Ellis-Gibbings, F Ferreira Da Silva, Paulo Limao-Vieira, Gustavo Garcia
Novel Experimental Setup For Time-Of-Flight Mass Spectrometry Ion Detection In Collisions Of Anionic Species With Neutral Gas-Phase Molecular Targets, J C. Oller, L Ellis-Gibbings, F Ferreira Da Silva, Paulo Limao-Vieira, Gustavo Garcia
Faculty of Engineering and Information Sciences - Papers: Part A
We report a novel experimental setup for studying collision induced products resulting from the interaction of anionic beams with a neutral gas-phase molecular target. The precursor projectile was admitted into vacuum through a commercial pulsed valve, with the anionic beam produced in a hollow cathode discharge-induced plasma, and guided to the interaction region by a set of deflecting plates where it was made to interact with the target beam. Depending on the collision energy regime, negative and positive species can be formed in the collision region and ions were time-of-flight (TOF) mass-analysed. Here, we present data on O-2 precursor projectile, …