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A Nonconjugated Bridge In Dimer-Sensitized Solar Cells Retards Charge Recombination Without Decreasing Charge Injection Efficiency, Kenji Sunahara, Matthew J. Griffith, Takayuki Uchiyama, Pawel Wagner, David L. Officer, Gordon G. Wallace, Attila J. Mozer, Shogo Mori
A Nonconjugated Bridge In Dimer-Sensitized Solar Cells Retards Charge Recombination Without Decreasing Charge Injection Efficiency, Kenji Sunahara, Matthew J. Griffith, Takayuki Uchiyama, Pawel Wagner, David L. Officer, Gordon G. Wallace, Attila J. Mozer, Shogo Mori
Faculty of Engineering and Information Sciences - Papers: Part A
Dye sensitized solar cells (DSSCs) employing a dimer porphyrin, which was synthesised with two porphyrin units connected without conjugation, have shown that both porphyrin components can contribute to photocurrent generation, that is, more than 50 % internal quantum efficiency. In addition, the open-circuit voltage (Voc) of the DSSCs was higher than that of DSSCs using monomer porphyrins. In this paper, we first optimized cell structure and fabrication conditions. We obtained more than 80% incident photon to current conversion efficiency from the dimer porphyrin sensitized DSSCs and higher Voc and energy conversion efficiency than monomer porphyrin sensitized solar cells. To examine …