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Full-Text Articles in Engineering
Unveiling The Roles Of Binder In The Mechanical Integrity Of Electrodes For Lithium-Ion Batteries, Jianchao Chen, Jianyong Liu, Yue Qi, Tao Sun, Xiaodong Li
Unveiling The Roles Of Binder In The Mechanical Integrity Of Electrodes For Lithium-Ion Batteries, Jianchao Chen, Jianyong Liu, Yue Qi, Tao Sun, Xiaodong Li
Faculty Publications
In lithium-ion secondary batteries research, binders have received the least attention, although the electrochemical performance of Li-ion batteries such as specific capacity and cycle life cannot be achieved if the adhesion strengths between electrode particles and between electrode films and current collectors are insufficient to endure charge-discharge cycling. In this paper, the roles of binders in the mechanical integrity of electrodes for lithium-ion batteries were studied by coupled microscratch and digital image correlation (DIC) techniques. A microscratch based composite model was developed to decouple the carbon particle/particle cohesion strength from the electrode-film/copper-current-collector adhesion strength. The dependences of microscratch coefficient of …
A High Energy Density All Solid-State Tungsten-Air Battery, Xuan Zhao, Xue Li, Yunhui Gong, Nansheng Xu, Kevin Gregory Romito, Kevin Huang
A High Energy Density All Solid-State Tungsten-Air Battery, Xuan Zhao, Xue Li, Yunhui Gong, Nansheng Xu, Kevin Gregory Romito, Kevin Huang
Faculty Publications
An all solid-state tungsten–air battery using solid oxide–ion electrolyte is demonstrated as a new chemistry for advanced energy storage. The unique design of separated energy storage from the electrodes allows for free volume expansion–contraction during electrical cycles and new metal–air chemistry to be explored conveniently.
Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. L. Green, J. Suehle, E. M. Vogel, H. Xiong, Jason R. Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner
Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. L. Green, J. Suehle, E. M. Vogel, H. Xiong, Jason R. Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner
Faculty Publications
The authors have fabricated combinatorial Ni–Ti–Pt ternary metal gate thin film libraries on HfO2 using magnetron co-sputtering to investigate flatband voltage shift (ΔVfb) , work function (Φm) , and leakage current density (JL) variations. A more negative ΔVfb is observed close to the Ti-rich corner than at the Ni- and Pt-rich corners, implying smaller Φm near the Ti-rich corners and higher Φm near the Ni- and Pt-rich corners. In addition, measured JL values can be explained consistently with the observed Φm variations. Combinatorial methodologies prove to be useful …
Molecular Dynamics Calculations Of The Electrochemical Properties Of Electrolyte Systems Between Charged Electrodes, Richard L. Rowley, Paul S. Crozier, Douglas Henderson
Molecular Dynamics Calculations Of The Electrochemical Properties Of Electrolyte Systems Between Charged Electrodes, Richard L. Rowley, Paul S. Crozier, Douglas Henderson
Faculty Publications
We investigate the interfacial electrochemical properties of an aqueous electrolyte solution with discrete water molecules in slab geometry between charged atomistic electrodes. Long-range intermolecular Coulombic interactions are calculated using the particle particle particle mesh method with a modification to account for the slab geometry. Density distribution profiles and potential drops across the double layer are given for 0, 0.25, and 1 M aqueous electrolyte solutions each electrode surface charges. Results are compared qualitatively with experimental x-ray scattering findings, other computer simulation results, and traditional electrochemistry theory. The interfacial fluid structure characteristics are generally in good qualitative agreement with the conclusions …
Preparation Of Mesoporous Sno2-Sio2 Composite As Electrodes For Lithium Batteries, Fanglin Chen, Zhong Shi, Meilin Liu
Preparation Of Mesoporous Sno2-Sio2 Composite As Electrodes For Lithium Batteries, Fanglin Chen, Zhong Shi, Meilin Liu
Faculty Publications
Mesoporous SnO2–SiO2 composite stable up to 600 °C with a BET surface area of 350 m2 g-1 and an average pore size of 3.4 nm is successfully prepared, which exhibits promising cycling properties as anodes for lithium batteries
Influence Of Some Design Variables On The Thermal Behavior Of A Lithium‐Ion Cell, Gerardine G. Botte, Bradley A. Johnson, Ralph E. White
Influence Of Some Design Variables On The Thermal Behavior Of A Lithium‐Ion Cell, Gerardine G. Botte, Bradley A. Johnson, Ralph E. White
Faculty Publications
No abstract provided.
Mathematical Modeling Of The Lithium Deposition Overcharge Reaction In Lithium‐Ion Batteries Using Carbon‐Based Negative Electrodes, Pankaj Arora, Marc Doyle, Ralph E. White
Mathematical Modeling Of The Lithium Deposition Overcharge Reaction In Lithium‐Ion Batteries Using Carbon‐Based Negative Electrodes, Pankaj Arora, Marc Doyle, Ralph E. White
Faculty Publications
No abstract provided.
Characterization Of Sol-Gel-Derived Cobalt Oxide Xerogels As Electrochemical Capacitors, Chuan Lin, James A. Ritter, Branko N. Popov
Characterization Of Sol-Gel-Derived Cobalt Oxide Xerogels As Electrochemical Capacitors, Chuan Lin, James A. Ritter, Branko N. Popov
Faculty Publications
Very fine cobalt oxide xerogel powders were prepared using a unique solution chemistry associated with the sol-gel process. The effect of thermal treatment on the surface area, pore volume, crystallinity, particle structure, and corresponding electrochemical properties of the resulting xerogels was investigated and found to have significant effects on all of these properties. The xerogel remained amorphous as Co(OH)2 up to 160°C, and exhibited maxima in both the surface area and pore volume at this temperature. With an increase in the temperature above 200°C, both the surface area and pore volume decreased sharply, because the amorphous Co(OH)2 decomposed …
Determination Of Transport And Electrochemical Kinetic Parameters Of Bare And Copper-Coated Lani4.27Sn0.24 Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White
Determination Of Transport And Electrochemical Kinetic Parameters Of Bare And Copper-Coated Lani4.27Sn0.24 Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White
Faculty Publications
Electrochemical properties of bare and copper-coated LaNi4.27Sn0.24 electrodes were investigated in alkaline solution. The exchange current density, polarization resistance, and equilibrium potential were determined as functions of the state of charge in the electrodes. The symmetry factors for bare and copper-coated electrodes were estimated to be 0.53 and 0.52, respectively. By using a constant current discharge technique, the hydrogen diffusion coefficient in bare and coated LaNi4.27Sn0.24 was estimated to be 6.75 × 10–11 cm2/s.
Application Of Porous Electrode Theory On Metal Hydride Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White
Application Of Porous Electrode Theory On Metal Hydride Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White
Faculty Publications
Porous electrode theory was applied to estimate the exchange current density, the polarization resistance, and symmetry factor for LaNi4.27Sn0.24 hydride electrode in alkaline solution. The exchange current density, polarization resistance, and symmetry factor were determined from polarization curves which were obtained at low overpotentials.
Proton Diffusion In Nickel Hydroxide Films: Measurement Of The Diffusion Coefficient As A Function Of State Of Charge, Sathya Motupally, Christopher C. Streinz, John W. Weidner
Proton Diffusion In Nickel Hydroxide Films: Measurement Of The Diffusion Coefficient As A Function Of State Of Charge, Sathya Motupally, Christopher C. Streinz, John W. Weidner
Faculty Publications
Electrochemical impedance spectroscopy (EIS) was used to measure the solid-state diffusion coefficient of protons in nickel hydroxide films at room temperature as a function of state of charge (SOC). A model for the complex faradaic impedance of the nickel hydroxide active material is presented and used to extract the diffusion coefficient of protons from the EIS data. Impedance data over a range of frequencies can be used to extract a constant diffusion coefficient without the knowledge of the initial mobile proton concentration or the form of the charge-transfer kinetic expression. The proton diffusion coefficient is a strong function of SOC …
Mathematical Modeling Of A Nickel-Cadmium Cell: Proton Diffusion In The Nickel Electrode, Pauline De Vidts, Ralph E. White
Mathematical Modeling Of A Nickel-Cadmium Cell: Proton Diffusion In The Nickel Electrode, Pauline De Vidts, Ralph E. White
Faculty Publications
In this paper we present a mathematical model of a sealed nickel-cadmium cell that includes proton diffusion and ohmic drop through the active material in the nickel electrode. The model is used to calculate sensitivity coefficients for various parameters in the model. These calculations show that the discharge voltage of the cell is affected mostly by the kinetics of the nickel reaction. Toward the end of discharge, proton diffusion also becomes important, because the proton diffusion process affects the active material utilization significantly. During charge, the cell voltage is mainly affected by the kinetics of the nickel reaction until the …
Electrode Kinetics Of Oxygen Reduction In Lithium Carbonate Melt: Use Of Impedance Analysis And Cyclic Voltammetric Techniques To Determine The Effects Of Partial Pressure Of Oxygen, Bhasker B. Davé, Ralph E. White, Supramanian Srinivasan, A. John Appleby
Electrode Kinetics Of Oxygen Reduction In Lithium Carbonate Melt: Use Of Impedance Analysis And Cyclic Voltammetric Techniques To Determine The Effects Of Partial Pressure Of Oxygen, Bhasker B. Davé, Ralph E. White, Supramanian Srinivasan, A. John Appleby
Faculty Publications
The effects of the partial pressure of oxygen and temperature on the oxygen reduction on a submerged gold electrode in a lithium carbonate melt were investigated using cyclic voltammetry and impedance analysis. The values for the mass-transfer parameters, DCO, obtained from cyclic voltammetry and impedance analysis were in good agreement. The reaction orders for oxygen at 800°C were calculated to be about 0.3 for the exchange current density and 0.5 for the product DCO; these values are consistent with the mechanism proposed in the literature for oxygen reduction in Li2CO3 melt.
A Simple Model For A Zinc/Bromine Flow Cell And Associated Storage Tanks, G. D. Simpson, Ralph E. White
A Simple Model For A Zinc/Bromine Flow Cell And Associated Storage Tanks, G. D. Simpson, Ralph E. White
Faculty Publications
A simple model for a parallel plate, zinc/bromine flow cell and associated storage tanks is presented and used to make time-dependent predictions for various quantities in the system. The model is based on a previously published algebraic model of the cell at steady-state and time-dependent, first-order differential equations for the storage tanks. The Butler-Volmer equation is used for the electrochemical reactions, and the homogeneous reaction between bromine and bromide is included. The model predictions indicate that the charging operation of a zinc/bromine battery can be significantly improved by using a storage tank with a larger residence time for the bromine …
Utility Of An Empirical Method Of Modeling Combined Zero Gap/Attached Electrode Membrane Chlor-Alkali Cells, Clifford W. Walton, Ralph E. White
Utility Of An Empirical Method Of Modeling Combined Zero Gap/Attached Electrode Membrane Chlor-Alkali Cells, Clifford W. Walton, Ralph E. White
Faculty Publications
An extensive survey of the Docktor-Ingenieur Dissertationen of Jakob Jörissen and Klaus-R. Menschig, both originally from the Universität Dortmund, is presented in regard to the empirical modeling of membrane chlor-alkali cells and how it can be applied to a combined zero gap/attached porous electrode layer membrane cell. Particular emphasis isplaced on Menschig's work on zero gap (ZG) and attached porous electrode layer (APEL) membrane chlor-alkali cells, the first such research to appear in the open literature. Menschig developed various computer programs to characterize these ZG and APEL membrane chlor-alkali cells. He characterized these cells by using the following parameters: the …
A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White
A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White
Faculty Publications
A mathematical model is presented for a system comprised of a parallel plate electrochemical reactor (PPER) and a continuous, stirred-tank reactor (CSTR) under both total and partial recycle. The model is used to predict the time dependent behavior of the electrowinning of copper from an aqueous, hydrochloric acid solution. The model includes many important aspects of a PPER/CSTR system which have been neglected previously. These aspects are the kinetics of electrode reactions, the electroneutrality condition, three mass transfer processes for ionic species in the electrolyte (diffusion, ionic migration, and convection) and the electrode gap in the PPER, and the inclusion …
High Discharge Rate Characteristics Of Nickel-Cadmium Batteries For Pulse Load Filtering, Gregory M. Gearing, Michael B. Cimino, David H. Fritts, John F. Leonard, Anthony J. Terzuoli Jr.
High Discharge Rate Characteristics Of Nickel-Cadmium Batteries For Pulse Load Filtering, Gregory M. Gearing, Michael B. Cimino, David H. Fritts, John F. Leonard, Anthony J. Terzuoli Jr.
Faculty Publications
Several tests of specially fabricated nickel-cadmium batteries having circular disk type electrodes were considered. These batteries were evaluated as filter elements between a constant current power supply and a five hertz pulsed load demanding approximately twice the power supply current during the load on portion of the cycle. Short tests lasting 10,000 cycles were conducted at up to a 21 C rate and an equivalent energy density of over 40 Joules per pound. In addition, two batteries were subjected to 107 charge/discharge cycles, one at a 6.5 C rate and the other at a 13 C rate. Assuming an …
Extension Of Darby's Model Of A Hydrophylic Gas Fed Porous Electrode, Ralph E. White, M. A. Nicholson, L. G. Kleine, J. Van Zee, R. Darby
Extension Of Darby's Model Of A Hydrophylic Gas Fed Porous Electrode, Ralph E. White, M. A. Nicholson, L. G. Kleine, J. Van Zee, R. Darby
Faculty Publications
A model presented previously by one of the authors (1,2) is reviewed and extended. Aspects of this model which were not previously available in the open literature are considered, and the model is extended to include previously neglected terms in the governing differential equations, fractional reaction orders in the current density-overpotential expression, and mass-transfer coefficients to account for mass-transfer resistance of the reactants to the faces of the porous electrode. The model is used to predict quantities of interest for oxygen reduction in an acidic aqueous solution in a porous carbon electrode.