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Parallel-Plate Electrochemical Reactor Model: A Method For Determining The Time-Dependent Behavior And The Effects Of Axial Diffusion And Axial Migration, T. V. Nguyen, C. W. Walton, Ralph E. White, J. Van Zee
Parallel-Plate Electrochemical Reactor Model: A Method For Determining The Time-Dependent Behavior And The Effects Of Axial Diffusion And Axial Migration, T. V. Nguyen, C. W. Walton, Ralph E. White, J. Van Zee
Faculty Publications
A method is presented for determining the effects of time dependence, axial diffusion, and axial migration in aparallel-plate electrochemical reactor (PPER). The method consists of formulating the governing equations and applying a numerical integration technique to solve a set of time-dependent, nonlinear, coupled, multidimensional equations. This formulation reveals that the steady-state performance of the PPER depends on the cell potential and three dimensionless groups. Predictions of the concentration, potential, and local current distributions in a PPER are presented for the electrowinning of copper from an aqueous, hydrochloric acid solution. These predictions show that axial diffusion and axial migration are significant …