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Full-Text Articles in Engineering

Heats Of Transport From The Diffusion Thermoeffect In Binary Liquid Mixtures Of Toluene, Chlorobenzene, And Bromobenzene, Richard L. Rowley, M. D. Hall Sep 1986

Heats Of Transport From The Diffusion Thermoeffect In Binary Liquid Mixtures Of Toluene, Chlorobenzene, And Bromobenzene, Richard L. Rowley, M. D. Hall

Faculty Publications

Measurements of heats of transport in binary liquid mixtures of toluene, chlorobenzene, and bromobenzene utilizing the diffusion thermoeffect, or Dufour effect, are reported at 298 and 308 K. The corresponding heat-mass Onsager doefficients are also reported, from which thermal diffusion ratios have been calculated based on Onsager reciprocity. The resultant binary thermal diffusion ratios have been correlated as a function of composition in an attempt to study the relationship between values in binary and ternary mixtures. It was found that the single independent binary values can be used to estimate the two independent thermal diffusion ratios previously reported in toluene …


Evidence For Amphoteric Behavior Of Ru On Cdte Surfaces, D. N. Bose, S. Basu, K. C. Mandal, D. Mazumdar Feb 1986

Evidence For Amphoteric Behavior Of Ru On Cdte Surfaces, D. N. Bose, S. Basu, K. C. Mandal, D. Mazumdar

Faculty Publications

No abstract provided.


A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White Jan 1986

A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White

Faculty Publications

A mathematical model is presented for a system comprised of a parallel plate electrochemical reactor (PPER) and a continuous, stirred-tank reactor (CSTR) under both total and partial recycle. The model is used to predict the time dependent behavior of the electrowinning of copper from an aqueous, hydrochloric acid solution. The model includes many important aspects of a PPER/CSTR system which have been neglected previously. These aspects are the kinetics of electrode reactions, the electroneutrality condition, three mass transfer processes for ionic species in the electrolyte (diffusion, ionic migration, and convection) and the electrode gap in the PPER, and the inclusion …