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A Mathematical Model Of A Zn/Br2 Cell On Charge, M J. Mader, Ralph E. White

Faculty Publications

A mathematical model of a parallel plate electrochemical cell with a separator and a homogeneous bulk reaction is presented. The model is based on the Zn/Br₂ redox couple and can be used as an aid for the design of an efficient rechargeable storage battery. It is shown that four independent variables exist for the system at a fixed temperature: the effective separator thickness, the residence time, the channel width, and the potential driving force. Performance criteria of interest for the Zn/Br₂ battery are defined. Predictions of performance during the charging process are presented. It is shown that the …