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Full-Text Articles in Engineering
Simple Models For Diaphragm-Type Chlorine/Caustic Cells Ii. Effect Of Acidic Anolyte On Steady-State Caustic Yield, John Van Zee, Ralph E. White
Simple Models For Diaphragm-Type Chlorine/Caustic Cells Ii. Effect Of Acidic Anolyte On Steady-State Caustic Yield, John Van Zee, Ralph E. White
Faculty Publications
A simple steady-state model of a diaphragm-type chlorine/caustic cell in which the diaphragm is divided into two regions by a homogeneous acid-base reaction is presented. The location of the reaction affects significantly the caustic yield and effluent concentration. The model is used to predict the location of this reaction as a function of the operating variables, the physical constants, and three measurable properties of the diaphragm. These measurable properties are the MacMullin number or resistivity ratio of electrolyte-filled diaphragm relative to the electrolyte, the Darcy's law diaphragmpermeability, and the diaphragm thickness. The model is used to predict a maximum in …
A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White
A Mathematical Model For A Parallel Plate Electrochemical Reactor, Cstr, And Associated Recirculation System, T V. Nguyen, C W. Walton, Ralph E. White
Faculty Publications
A mathematical model is presented for a system comprised of a parallel plate electrochemical reactor (PPER) and a continuous, stirred-tank reactor (CSTR) under both total and partial recycle. The model is used to predict the time dependent behavior of the electrowinning of copper from an aqueous, hydrochloric acid solution. The model includes many important aspects of a PPER/CSTR system which have been neglected previously. These aspects are the kinetics of electrode reactions, the electroneutrality condition, three mass transfer processes for ionic species in the electrolyte (diffusion, ionic migration, and convection) and the electrode gap in the PPER, and the inclusion …