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Full-Text Articles in Engineering

Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton Dec 2014

Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton

Faculty Publications

A photoinduced electron paramagnetic resonance (EPR) spectrum in single crystals of Sn2P2S6 (SPS) is assigned to an electron trapped at a sulfur vacancy. These vacancies are unintentionally present in undoped SPS crystals and are expected to play an important role in the photorefractive behavior of the material. Nonparamagnetic sulfur vacancies are formed during the initial growth of the crystal. Subsequent illumination below 100 K with 442 nm laser light easily converts these vacancies to EPR-active defects. The resulting S = 1/2 spectrum shows well-resolved and nearly isotropic hyperfine interactions with two P ions and two Sn ions. Partially resolved interactions …


Space Separatism: Degree Of Differentiation, Luke R. Stover, Alan A. Johnson Nov 2014

Space Separatism: Degree Of Differentiation, Luke R. Stover, Alan A. Johnson

Faculty Publications

Space is so important that the DOD recognizes it as one of five domains in which US forces operate (the other four are land, sea, air, and information). In 2001 Secretary of Defense Donald Rumsfeld designated the Department of the Air Force (DAF) the “Executive Agent for Space for the DOD.” Given the national importance of space activities, the formation of a separate space force has been a topic of persistent discussion in academic and doctrinal circles ever since the United States first entered the space age. Proponents of a separate force argue that because space is an inherently unique …


Machine Learning Nuclear Detonation Features, Daniel T. Schmitt, Gilbert L. Peterson Oct 2014

Machine Learning Nuclear Detonation Features, Daniel T. Schmitt, Gilbert L. Peterson

Faculty Publications

Nuclear explosion yield estimation equations based on a 3D model of the explosion volume will have a lower uncertainty than radius based estimation. To accurately collect data for a volume model of atmospheric explosions requires building a 3D representation from 2D images. The majority of 3D reconstruction algorithms use the SIFT (scale-invariant feature transform) feature detection algorithm which works best on feature-rich objects with continuous angular collections. These assumptions are different from the archive of nuclear explosions that have only 3 points of view. This paper reduces 300 dimensions derived from an image based on Fourier analysis and five edge …


Timing Mark Detection On Nuclear Detonation Video, Daniel T. Schmitt, Gilbert L. Peterson Oct 2014

Timing Mark Detection On Nuclear Detonation Video, Daniel T. Schmitt, Gilbert L. Peterson

Faculty Publications

During the 1950s and 1960s the United States conducted and filmed over 200 atmospheric nuclear tests establishing the foundations of atmospheric nuclear detonation behavior. Each explosion was documented with about 20 videos from three or four points of view. Synthesizing the videos into a 3D video will improve yield estimates and reduce error factors. The videos were captured at a nominal 2500 frames per second, but range from 2300-3100 frames per second during operation. In order to combine them into one 3D video, individual video frames need to be correlated in time with each other. When the videos were captured …


Broadband, Non-Destructive Characterisation Of Pec-Backed Materials Using A Dual-Ridged-Waveguide Probe, Milo W. Hyde Iv, Michael J. Havrilla Jun 2014

Broadband, Non-Destructive Characterisation Of Pec-Backed Materials Using A Dual-Ridged-Waveguide Probe, Milo W. Hyde Iv, Michael J. Havrilla

Faculty Publications

A new probe which utilises a dual-ridged waveguide to provide broadband, non-destructive (ND) material characterisation measurements of a perfect electric conductor (PEC)-backed material is introduced. The new probe possesses a bandwidth similar to existing coaxial probes and is structurally robust like rectangular waveguide probes. The combinations of these two qualities make it especially attractive for ND inspection/evaluation applications in the field. The theoretical development of the dual-ridged-waveguide probe is discussed. A magnetic field integral equation is derived by applying Love’s equivalence theorem and enforcing the continuity of transverse fields at the dual-ridged-waveguide aperture. The magnetic field integral equation is then …


Copper Doping Of Zno Crystals By Transmutation Of 64Zn To 65Cu: An Electron Paramagnetic Resonance And Gamma Spectroscopy Study, Matthew C. Recker, John W. Mcclory, Maurio S. Holston, Eric M. Golden, Nancy C. Giles, Larry E. Halliburton Jun 2014

Copper Doping Of Zno Crystals By Transmutation Of 64Zn To 65Cu: An Electron Paramagnetic Resonance And Gamma Spectroscopy Study, Matthew C. Recker, John W. Mcclory, Maurio S. Holston, Eric M. Golden, Nancy C. Giles, Larry E. Halliburton

Faculty Publications

Transmutation of 64Zn to 65Cu has been observed in a ZnO crystal irradiated with neutrons. The crystal was characterized with electron paramagnetic resonance (EPR) before and after the irradiation and with gamma spectroscopy after the irradiation. Major features in the gamma spectrum of the neutron-irradiated crystal included the primary 1115.5 keV gamma ray from the 65Zn decay and the positron annihilation peak at 511 keV. Their presence confirmed the successful transmutation of 64Zn nuclei to 65Cu. Additional direct evidence for transmutation was obtained from the EPR of Cu2+ ions (where 63Cu and 65 …


Modeling The Thermosphere As A Driven-Dissipative Thermodynamic System, William R. Frey, C. S. Lin, Matthew B. Garvin, Ariel O. Acebal Apr 2014

Modeling The Thermosphere As A Driven-Dissipative Thermodynamic System, William R. Frey, C. S. Lin, Matthew B. Garvin, Ariel O. Acebal

Faculty Publications

Thermospheric density impacts satellite position and lifetime through atmospheric drag. More accurate specification of thermospheric temperature, a key input to current models such as the High Accuracy Satellite Drag Model, can decrease model density errors. This paper improves the model of Burke et al. (2009) to model thermospheric temperatures using the magnetospheric convective electric field as a driver. In better alignment with Air Force satellite tracking operations, we model the arithmetic mean temperature, T 1/2, defined by the Jacchia (1977) model as the mean of the daytime maximum and nighttime minimum exospheric temperatures occurring in opposite hemispheres at a …


Functionalization Of Carbon Nanotube Yarn By Acid Treatment, Heath E. Misak, Ramazan Asmatulu, Mat O'Malley, Emil Jurak, Shankar Mall Apr 2014

Functionalization Of Carbon Nanotube Yarn By Acid Treatment, Heath E. Misak, Ramazan Asmatulu, Mat O'Malley, Emil Jurak, Shankar Mall

Faculty Publications

Carbon nanotube (CNT) yarn was functionalized using sulfuric and nitric acid solutions in 3:1 volumetric ratio. Successful functionalization of CNT yarn with carboxyl and hydroxyl groups (e.g., COOH, COO–, OH, etc.) was confirmed by attenuated total reflectance spectroscopy. X-ray diffraction revealed no significant change to the atomic in-plane alignment in the CNTs; however, the coherent length along the diameter was significantly reduced during functionalization. A morphology change of wavy extensions protruding from the surface was observed after the functionalization treatment. The force required to fracture the yarn remained the same after the functionalization process; however, the linear density was increased …


Triplet Ground State Of The Neutral Oxygen-Vacancy Donor In Rutile Tio2, A. T. Brant, Eric M. Golden, Nancy C. Giles, Shan Yang, M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton Mar 2014

Triplet Ground State Of The Neutral Oxygen-Vacancy Donor In Rutile Tio2, A. T. Brant, Eric M. Golden, Nancy C. Giles, Shan Yang, M. A. R. Sarker, S. Watauchi, M. Nagao, I. Tanaka, D. A. Tryk, A. Manivannan, Larry E. Halliburton

Faculty Publications

Electron paramagnetic resonance (EPR) is used to investigate the triplet (S = 1) ground state of the neutral oxygen vacancy in bulk rutile TiO2 crystals. This shallow donor consists of an oxygen vacancy with two nearest-neighbor, exchange-coupled 3+ ions located along the [001] direction and equidistant from the vacancy. The spins of the two trapped electrons, one at each 3+ ion, align parallel to give the S = 1 state. These neutral oxygen vacancies are formed near 25 K in as-grown oxidized TiO2 crystals by illuminating with sub-band-gap 442 nm laser light. The angular dependence of the EPR …


Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles Mar 2014

Neutral Nitrogen Acceptors In Zno: The 67Zn Hyperfine Interactions, Eric M. Golden, S. M. Evans, Larry E. Halliburton, Nancy C. Giles

Faculty Publications

Electron paramagnetic resonance (EPR) is used to characterize the 67Zn hyperfine interactions associated with neutral nitrogen acceptors in zinc oxide. Data are obtained from an n-type bulk crystal grown by the seeded chemical vapor transport method. Singly ionized nitrogen acceptors (N) initially present in the crystal are converted to their paramagnetic neutral charge state (N0) during exposure at low temperature to 442 or 633 nm laser light. The EPR signals from these N0 acceptors are best observed near 5 K. Nitrogen substitutes for oxygen ions and has four nearest-neighbor cations. The zinc ion …